Abstract: A formic acid aqueous solution that contains Fe (II) ions is produced by dissolving metal iron in a formic acid aqueous solution. Nitrogen is supplied from a nitrogen supply device to a chemical liquid tank and then discharged from a discharge line to reduce the dissolved oxygen concentration in the aqueous solution. The chemical liquid tank is filled with the formic acid aqueous solution sealed with nitrogen, and transferred from a factory to a nuclear reactor building designated as radiation-controlled areas. Inside the nuclear reactor building, the chemical liquid tank is installed in a film deposition apparatus connected to a reactor water recirculation pipeline. The formic acid aqueous is supplied from the chemical liquid tank to the inside of the reactor water recirculation pipeline, and then a ferrite film is formed on the inner surface of the reactor water recirculation pipeline.

Abstract: Both ends of a circulation pipe of a film formation apparatus are connected to a piping of a BWR plant. A chemical including chromium ions and formic acid is injected into a film formation solution flowing in the circulation pipe heated to a temperature within a range from 60° C. to 100° C. Furthermore, a chemical including iron (II) ions and formic acid, hydrogen peroxide, and hydrazine are injected into the circulation pipe. Due to the injection of these chemicals, a film formation solution of pH 7.0 including iron (II) ions, chromium ions, formic acid, hydrogen peroxide, and hydrazine is generated in the circulation pipe. This film formation solution includes hydrazine of, for example, 1000 ppm. The film formation solution is supplied to the piping, thus, a Fe3—xCrxO4 film (here, 0<X?0.1) is formed on the inner surface of the piping. The above method of forming the ferrite film on a structural member (for example, the piping) can be shortened time required to form the ferrite film.

Abstract: A method of suppressing deposition of radionuclides on components of a nuclear power plant comprises forming a ferrite film by contacting a first chemical including iron (II) ions, a second chemical for oxidizing the iron (II) ions to iron (III) ions, and a third chemical for adjusting the pH of a processing solution containing a mixture of the first and second chemicals to be 5.5 to 9.0 with the metal member surface in a time period from a finishing stage in decontamination step of removing contaminants formed on the surface of metal member composing the nuclear power plant, and suppressing deposition of radionuclides on the metal member by the ferrite film.

Abstract: A natural circulation boiling water reactor provides to a chimney with a plurality of tubes. That is to say, each of the plurality of tubes partitions the coolant flow path above a core. Thus, unlike the conventional natural circulation boiling water reactor providing the flow path partition wall grid in which the plate members are made integral by welding and coolant flow paths are partitioned, the chimney of the natural circulation boiling water reactor can reduce the number of welded portions because the edges of the four corners of each flow path do not need to be welded. The natural circulation boiling water reactor can avoid removal as a single unit, as in the case of the flow path partition wall grid in the conventional natural circulation boiling water reactor, by detaching each tube. The chimney can be easily detached from the reactor pressure vessel.

Abstract: A method of suppressing deposition of radionuclides on components of a nuclear power plant comprises forming a ferrite film by contacting a first chemical including iron (II) ions, a second chemical for oxidizing the iron (II) ions to iron (III) ions, and a third chemical for adjusting the pH of a processing solution containing a mixture of the first and second chemicals to be 5.5 to 9.0 with the metal member surface in a time period from a finishing stage in decontamination step of removing contaminants formed on the surface of metal member composing the nuclear power plant, and suppressing deposition of radionuclides on the metal member by the ferrite film.

Abstract: A bath containing nickel ions and formic acid is injected into a film-forming aqueous solution flowing in a circulation pipe connected to feed water pipe made of carbon steel in a BWR plant. This film-forming aqueous solution is supplied into the feed water pipe through the circulation pipe, and then, a nickel metal film is formed on an inner surface of the feed water pipe. After the nickel metal film is formed, a film-forming aqueous solution containing iron (II) ions, formic acid, nickel ions, hydrogen peroxide, and hydrazine is supplied to the feed water pipe. A nickel ferrite film is formed on the surface of the nickel metal film in the feed water pipe. Then, the nickel ferrite film is come into contact with water containing dissolved-oxygen at 150° C. or above to transform the nickel metal film into a nickel ferrite film. A thick nickel ferrite film is formed on the inner surface of the feed water pipe. Corrosion of the carbon steel member composing the plant can further reduce.

Abstract: A method of suppressing deposition of radionuclides on components of a nuclear power plant comprises forming a ferrite film by contacting a first chemical including iron (II) ions, a second chemical for oxidizing the iron (II) ions to iron (III) ions, and a third chemical for adjusting the pH of a processing solution containing a mixture of the first and second chemicals to be 5.5 to 9.0 with the metal member surface in a time period from a finishing stage in decontamination step of removing contaminants formed on the surface of metal member composing the nuclear power plant, and suppressing deposition of radionuclides on the metal member by the ferrite film.

Abstract: It is an object of the present invention to efficiently suppress radionuclide deposition on a reactor component of nuclear power plant. Radionuclide deposition on the surface of a metallic reactor component of nuclear power plant is suppressed by forming a ferrite film on the component, wherein the film is formed, after decontamination for removing radionuclides contaminants from the component surface is completed and before the plant is started up, by contacting a treatment solution which mixes a first agent containing the iron (II) ions, a second agent for oxidizing the iron (II) ions into the iron (III) ions and a third agent for adjusting pH level of a solution to 5.5 to 9.0 in this order with the reactor component surface.

Abstract: A handling method for a natural circulation boiling water reactor having a chimney having cylindrical chimney shell disposed above a core in a reactor pressure vessel, a plurality of square tubes disposed in the chimney shell, and a grid support plate with grid holes supporting and in communication with a lower end portion of the square tubes so that adjacent square tubes are disposed at an interval which exceeds the width of one square tube between them. The method includes steps shifting predetermined ones of the square tubes to the interval between the square tubes, and performing maintenance and inspection of members around a core via the grid holes which appear at positions from which the predetermined square tubes are taken out due to the shift of the predetermined square tubes.

Abstract: A method for forming a ferrite film onto surface of structural member composing a plant, comprises steps of forming a ferrite film onto the wetted surface of the structural member by making contact with a film forming solution containing iron (II) ions, an oxidant for oxidizing the iron (II) ions, and a pH adjustment agent; measuring the amount of the formed ferrite film; and determining completion of the ferrite film formation based on the measured amount of the formed ferrite film. The method for forming the ferrite film onto the surface of the structural member, can shorten the time required for completing the ferrite film forming operations.

Abstract: A method for suppressing deposit of radionuclide onto structure member composing a nuclear power plant, comprising the steps of: bringing film formation liquid including iron (II) ions and either of zinc (II) ions and nickel (II) ions into contact with a surface of the structure member; and forming either of a ferrite film including the zinc and a ferrite film including the nickel on the surface of the structure member.

Abstract: The present invention is a method for suppressing corrosion of carbon steel members composing a nuclear power plant. That is, the processing solution contains a chemical including iron (II) ions, an oxidizing agent for oxidizing at least one part of the iron (II) ions into iron (III) ion, and a pH adjustment agent for adjusting pH. The pH of the processing solution is adjusted in the range of 5.5 to 9.0 by the pH adjustment agent. The processing solution is introduced into a purifying system pipe having the carbon steel members. The iron (II) ions are adsorbed on an inner surface of the purifying system pipe, namely, a surface of the carbon steel members. The ferrite film is formed on the surface of the carbon steel members by oxidizing the absorbed iron (II) ions. Therefore, corrosion of the carbon steel members is suppressed by the ferrite film.

Abstract: A method of suppressing deposition of radionuclides on components of a nuclear power plant comprises forming a ferrite film by contacting a first chemical including iron (II) ions, a second chemical for oxidizing the iron (II) ions to iron (III) ions, and a third chemical for adjusting the pH of a processing solution containing a mixture of the first and second chemicals to be 5.5 to 9.0 with the metal member surface in a time period from a finishing stage in decontamination step of removing contaminants formed on the surface of metal member composing the nuclear power plant, and suppressing deposition of radionuclides on the metal member by the ferrite film.

Abstract: A method of suppressing deposition of radionuclides on components of a nuclear power plant comprises forming a ferrite film by contacting a first chemical including iron (II) ions, a second chemical for oxidizing the iron (II) ions to iron (III) ions, and a third chemical for adjusting the pH of a processing solution containing a mixture of the first and second chemicals to be 5.5 to 9.0 with the metal member surface in a time period from a finishing stage in decontamination step of removing contaminants formed on the surface of metal member composing the nuclear power plant, and suppressing deposition of radionuclides on the metal member by the ferrite film.

Abstract: A method of suppressing deposition of radionuclides on components of a nuclear power plant comprises forming a ferrite film by contacting a first chemical including iron (II) ions, a second chemical for oxidizing the iron (II) ions to iron (III) ions, and a third chemical for adjusting the pH of a processing solution containing a mixture of the first and second chemicals to be 5.5 to 9.0 with the metal member surface in a time period from a finishing stage in decontamination step of removing contaminants formed on the surface of metal member composing the nuclear power plant, and suppressing deposition of radionuclides on the metal member by the ferrite film.

Abstract: The present invention is a method for suppressing corrosion of carbon steel members composing a nuclear power plant. That is, the processing solution contains a chemical including iron (II) ions, an oxidizing agent for oxidizing at least one part of the iron (II) ions into iron (III) ion, and a pH adjustment agent for adjusting pH. The pH of the processing solution is adjusted in the range of 5.5 to 9.0 by the pH adjustment agent. The processing solution is introduced into a purifying system pipe having the carbon steel members. The iron (II) ions are adsorbed on an inner surface of the purifying system pipe, namely, a surface of the carbon steel members. The ferrite film is formed on the surface of the carbon steel members by oxidizing the absorbed iron (II) ions. Therefore, corrosion of the carbon steel members is suppressed by the ferrite film.

Abstract: A formic acid aqueous solution that contains Fe (II) ions is produced by dissolving metal iron in a formic acid aqueous solution. Nitrogen is supplied from a nitrogen supply device to a chemical liquid tank and then discharged from a discharge line to reduce the dissolved oxygen concentration in the aqueous solution. The chemical liquid tank is filled with the formic acid aqueous solution sealed with nitrogen, and is transferred from a factory to a nuclear reactor building designated as radiation-controlled areas. Inside the nuclear reactor building, the chemical liquid tank is installed in a film deposition apparatus connected to a reactor water recirculation pipeline. The formic acid aqueous is supplied from the chemical liquid tank to the inside of the reactor water recirculation pipeline, and then a ferrite film is formed on the inner surface of the reactor water recirculation pipeline.

Abstract: A handling method for a natural circulation boiling water reactor having a chimney having cylindrical chimney shell disposed above a core in a reactor pressure vessel, a plurality of square tubes disposed in the chimney shell, and a grid support plate with grid holes supporting and in communication with a lower end portion of the square tubes so that adjacent square tubes are disposed at an interval which exceeds the width of one square tube between them. The method includes steps shifting predetermined ones of the square tubes to the interval between the square tubes, and performing maintenance and inspection of members around a core via the grid holes which appear at positions from which the predetermined square tubes are taken out due to the shift of the predetermined square tubes.

Abstract: A formic acid aqueous solution that contains Fe (II) ions is produced by dissolving metal iron in a formic acid aqueous solution. Nitrogen is supplied from a nitrogen supply device to a chemical liquid tank and then discharged from a discharge line to reduce the dissolved oxygen concentration in the aqueous solution. The chemical liquid tank is filled with the formic acid aqueous solution sealed with nitrogen, and transferred from a factory to a nuclear reactor building designated as radiation-controlled areas. Inside the nuclear reactor building the chemical liquid tank is installed in a film deposition apparatus connected to a reactor water recirculation pipeline. The formic acid aqueous is supplied from the chemical liquid tank to the inside of the reactor water recirculation pipeline, and then a ferrite film is formed on the inner surface of the reactor water recirculation pipeline.

Abstract: A method of suppressing deposition of radionuclides on components of a nuclear power plant comprises forming a ferrite film by contacting a first chemical including iron (II) ions, a second chemical for oxidizing the iron (II) ions to iron (III) ions, and a third chemical for adjusting the pH of a processing solution containing a mixture of the first and second chemicals to be 5.5 to 9.0 with the metal member surface in a time period from a finishing stage in decontamination step of removing contaminants formed on the surface of metal member composing the nuclear power plant, and suppressing deposition of radionuclides on the metal member by the ferrite film.