Patents by Inventor Hiroko Kaneko
Hiroko Kaneko has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 5455224Abstract: A method for producing a compound oxide superconducting thin film, comprising forming an oxide thin film on the surface of a substrate of a first metal element having a redox charge by oxidizing the metal, using the oxide thin film thus formed as an electrode for oxidation reaction of a second metal element contained in an electrolyte solution or molten salt to incorporate the second metal element in the oxide thin film, using the compound oxide thin film thus formed as an electrode to obtain a cyclic voltammogram, and electrochemically processing the compound oxide thin film at an electrolytic potential that is determined based on the cyclic voltammogram.Type: GrantFiled: March 24, 1994Date of Patent: October 3, 1995Assignees: Agency of Industrial Science & Technology, Ministry of International Trade & IndustryInventors: Hiroko Kaneko, Keiji Kaneko, Hideo Ihara, Akira Negishi, Shoji Ishibashi
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Patent number: 5380422Abstract: A working micro-electrode with a reference electrode prepared by coating a working micro-electrode with an insulating material except a working electrode portion, forming a silver layer on the coated surface, and then changing a portion of the silver layer into silver chloride which is the reference electrode; a working micro-electrode with a reference electrode and a counter electrode prepared by coating the working micro-electrode with the reference electrode with an insulating material, and then forming the counter electrode on the surface of the insulating material; and methods for preparing these composite micro-electrodes.Heretofore, even if the working electrode is thinly constituted, the merit of the micro-electrode has not been sufficiently utilized, since the reference electrode and the counter electrode have been thick. However, the present invention can solve this problem and can facilitate experiments in which the micro-electrode is necessary.Type: GrantFiled: June 29, 1992Date of Patent: January 10, 1995Assignees: Agency of Industrial Science and Technology, Mitsubishi Pencil Kabushiki KaishaInventors: Akira Negishi, Hiroko Kaneko, Takamasa Kawakubo, Yoshihisa Suda
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Patent number: 5376251Abstract: A carbon micro-sensor electrode is disclosed which is prepared by impregnating, adsorbing or chemically modifying a pure composite carbon wire having many micropores extending to its surface and interior with a reactant such as an enzyme, a metal complex compound, an organic compound or a metabolite; and a method for preparing this carbon micro-sensor electrode is also disclosed.The above-mentioned electrode can be used for a long period of time, since the reactant is received in the many micropores. Furthermore, after used, the electrode may be cut off to expose a new electrode surface, and this new electrode surface may be coated with a material which does not impede an electrode reaction, whereby the reactant can be prevented from flowing out. Thus, the carbon micro-sensor electrode of the present invention can be repeatedly utilized.Type: GrantFiled: November 4, 1993Date of Patent: December 27, 1994Assignees: Agency of Industrial Science and Technology, Mitsubishi Pencil Kabushiki KaishaInventors: Hiroko Kaneko, Masahiro Yamada, Akira Negishi, Takamasa Kawakubo, Yoshihisa Suda
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Patent number: 5344779Abstract: A method for the production of a standard oxide sample for X-ray fluorescence analysis of an impurity element contained in an inorganic compound. The standard oxide sample is produced by accurately weighing a high-purity compound of the type of the main-component element of the inorganic compound, dissolving the weighed compound in an acid, adding an element of the type of the impurity element to be subjected to determination in a prescribed amount to the acid solution, evaporating the resultant solution to dryness, and heating the dry residue of evaporation.Type: GrantFiled: March 22, 1993Date of Patent: September 6, 1994Assignee: Agency of Industrial Science & Technology, Ministry of International Trade & IndustryInventors: Keiji Kaneko, Masayuki Hirabayashi, Hideo Ihara, Hiroko Kaneko
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Patent number: 5318865Abstract: In a redox battery including an electrolytic cell which has a circulating type electrolytic solution and an intermittent circulating type electrolytic solution which has a membrane and which employs an electrolytic solution permeable porous electrode, a solution of vanadium (II/III) dissolved in sulfuric acid is used as an active material on the negative electrode of a redox couple, and an oxidizing substance in a gas (such as oxygen) or in electrolytic solution is used as an active material on the positive electrode of the redox couple. The redox battery of the invention shows high energy density, and has a small size and a high output, thus it can be used for an electric vehicle or as a portable battery.Type: GrantFiled: June 2, 1992Date of Patent: June 7, 1994Assignees: Director-General, Agency of Industrial Science and Technology, Kashima-Kita Electric Power CorporationInventors: Hiroko Kaneko, Akira Negishi, Ken Nozaki, Kanji Sato, Masato Nakajima
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Patent number: 5286711Abstract: A method for producing an oxide superconductor comprises obtaining a cyclic voltammogram using an oxide material containing an element having a redox charge as an electrode, determining an electrolytic potential for the oxide material on the basis of the voltammogram, and electrolyzing the oxide material at the determined potential.Type: GrantFiled: March 23, 1992Date of Patent: February 15, 1994Assignee: Agency of Industrial Science & Technology, Ministry of International Trade & IndustryInventors: Hiroko Kaneko, Keiji Kaneko, Hideo Ihara, Akira Negishi
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Patent number: 5281319Abstract: A carbon micro-sensor electrode is disclosed which is prepared by impregnating, adsorbing or chemically modifying a pure composite carbon wire having many micropores extending to its surface and interior with a reactant such as an enzyme, a metal complex compound, an organic compound or a metabolite; and a method for preparing this carbon micro-sensor electrode is also disclosed.The above-mentioned electrode can be used for a long period of time, since the reactant is received in the many micropores. Furthermore, after used, the electrode may be cut off to expose a new electrode surface, and this new electrode surface may be coated with a material which does not impede an electrode reaction, whereby the reactant can be prevented from flowing out. Thus, the carbon micro-sensor electrode of the present invention can be repeatedly utilized.Type: GrantFiled: June 29, 1992Date of Patent: January 25, 1994Assignee: Agency of Industrial Science and TechnologyInventors: Hiroko Kaneko, Masahiro Yamada, Akira Negishi, Takamasa Kawakubo, Yoshihisa Suda
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Patent number: 5273639Abstract: A method of making a probe electrode includes the steps of kneading a mixture of 75-80% by weight of a carbon material, 10-14% by weight of an organic binder and 7-9% by weight of mineral oil, forming the kneaded mixture into a predetermined shape, heating the shaped mixture in air the temperature of up to 300.degree. C. and raising the temperature in an atmosphere of inert gas up to 1000.degree. C.Type: GrantFiled: June 29, 1992Date of Patent: December 28, 1993Assignees: Agency of Industrial Science & Technology, Ministry of International Trade & IndustryInventors: Hiroko Kaneko, Ken Nozaki, Akira Negishi
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Patent number: 5264712Abstract: A semiconductor integrated circuit comprising first n-channel MISFETs constituting the memory cells of a storage system, second n-channel MISFETs constituting the peripheral circuits of the storage system, and third n-channel MISFETs constituting the output circuit among the peripheral circuits. The respective threshold voltages of the first n-channel MISFETs, the second n-channel MISFETs and the third n-channel MISFETs are decreased in that order when the respective gate lengths of those MISFETs are substantially the same.Type: GrantFiled: May 7, 1992Date of Patent: November 23, 1993Assignee: Hitachi, Ltd.Inventors: Jun Murata, Yoshitaka Tadaki, Hiroko Kaneko, Toshihiro Sekiguchi, Hiroyuki Uchiyama, Hisashi Nakamura, Toshio Maeda, Osamu Kasahara, Hiromichi Enami, Atsushi Ogishima, Masaki Nagao, Michimasa Funabashi, Yasuo Kiguchi, Masayuki Kojima, Atsuyoshi Koike, Hiroyuki Miyazawa, Masato Sadaoka, Kazuya Kadota, Tadashi Chikahara, Kazuo Nojiri, Yutaka Kobayashi
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Patent number: 5250158Abstract: A vanadium electrolytic solution containing highly concentrated and dissolved vanadium is produced by a method wherein a vanadium compound selected from the group consisting of ammonium metavanadate and vanadium pentaoxide is subjected to a reduction operation in the presence of inorganic acids. At this time, by repeating the addition of the concentrated inorganic acids and the vanadium compound, a tetravalent and pentavalent vanadium solution of 3.4 mol/l is obtained.In addition, the resulting vanadium electrolytic solution is electrolyzed, whereby tetravalent vanadium is reduced to be trivalent on the negative electrode and is oxidized into pentavalent vanadium on the positive electrode, and then pentavalent vanadium is reduced into tetravalent vanadium by a reducing agent to form a discharged couple of trivalent and tetravalent vanadium, and an electrolytic solution is obtained which is capable of being charge-discharged.Type: GrantFiled: October 8, 1991Date of Patent: October 5, 1993Assignees: Director-General, Agency of Industrial Science and Technology, Kashima-Kita Electric Power CorporationInventors: Hiroko Kaneko, Akira Negishi, Ken Nozaki, Kenji Sato, Ichiro Nakahara
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Patent number: 5218757Abstract: A tapered carbon microelectrode is produced by extruding an organic material or a composition composed of crystalline carbon fine powder and an organic binder into a thin rod form, carbonizing said rod by calcining to produce a pure carbon thin rod, soaking the resulting thin rod as an anode in an electrolytic solution, gradually pulling up the thin rod while electrochemically oxidizing the tip portion of the thin rod. Then a lead wire is connected with the thick portion of the thin rod followed by coating all the surface except the conically sharp tip portion.The tapered carbon electrode can be used for various electrochemical measurements and scanning tunneling microscope.Type: GrantFiled: June 25, 1991Date of Patent: June 15, 1993Assignees: Agency of Industrial Science and Technology, Mitsubishi Pencil Kabushiki KaishaInventors: Hiroko Kaneko, Masahiro Yamada, Yukifumi Shigematsu, Wataru Mizutani, Akira Negishi, Takamasa Kawakubo, Yoshihisa Suda
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Patent number: 5153685Abstract: A semiconductor integrated circuit device having a switching MISFET, and a capacitor element formed over the semiconductor substrate, such as a DRAM, is disclosed. In a first aspect of the present invention, the impurity concentration of the semiconductor region of the switching MISFET to which the capacitor element is connected is less than the impurity concentration of semiconductor regions of MISFETs of peripheral circuitry. In a second aspect, the Y-select signal line overlaps the lower electrode layer of the capacitor element. In a third aspect, a potential barrier layer, provided at least under the semiconductor region of the switching MISFET to which the capacitor element is connected, is formed by diffusion of an impurity for a channel stopper region. In a fourth aspect, the dielectric film of the capacitor element is co-extensive with the capacitor electrode layer over it.Type: GrantFiled: September 19, 1988Date of Patent: October 6, 1992Assignee: Hitachi, Ltd.Inventors: Jun Murata, Yoshitaka Tadaki, Isamu Asano, Mitsuaki Horiuchi, Jun Sugiura, Hiroko Kaneko, Shinji Shimizu, Atsushi Hiraiwa, Hidetsugu Ogishi, Masakazu Sagawa, Masami Ozawa, Toshihiro Sekiguchi
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Patent number: 4907046Abstract: A solid state device includes a transistor (A) and a capacitor (B). The capacitor is defined by a lower polycrystalline silicon layer or electrode (20), multiple dielectric layers (22), and an upper polycrystalline silicon layer or electrode (30). The dielectric layers are formed by vapor depositing a 3.6-18.6 nm thick layer of silicon nitride on the lower polycrystalline layer. Thicker silicon nitride layers increase the failure rate and decrease the capacitance (FIG. 8). More specifically, the silicon nitride layer is deposited on a thin, about 1 nm, oxidized film or surface (24) of the polycrystalline silicon layer. The silicon nitride layer is oxidized forming a silicon dioxide layer (28) until the silicon nitride layer is only about 3 nm thick. This forms on oxide layer that is 1-8.4 nm thick. If the silicon nitride layer is reduced below 3 nm, the polycrystalline silicon tends to oxidize rapidly reducing capacitance and increasing failure (FIG. 8).Type: GrantFiled: March 15, 1988Date of Patent: March 6, 1990Assignee: Hitachi Ltd.Inventors: Yuzuru Ohji, Osamu Kasahara, Yoshitaka Tadaki, Hiroko Kaneko, Toshiyuki Mine, Kunihiro Yagi
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Patent number: 4814241Abstract: An electrolyte for a Redox flow battery contains from 1 to 4 normal hydrochloric acid and at least 0.5 mole/liter of an active material, and further contains from 0.1 to 4 normalities of an acid comprising an anion which does not inhibit the electrode reactions in addition to the hydrochloric acid. This electrolyte reduces the cell resistivity and improves the solubility of active materials.Type: GrantFiled: March 16, 1987Date of Patent: March 21, 1989Assignees: Director-General, Agency of Industrial Science and Technology, Kawasaki Jukogyo Kabushiki KaishaInventors: Ikuo Nagashima, Jun Fukui, Hiroshi Gotoh, Hiroko Kaneko, Ken Nozaki, Takeo Ozawa
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Patent number: 4732827Abstract: A process for producing an anolyte and a catholyte for redox cells which comprises the steps of heating chromium ore together with carbonaceous substances to produce a pre-reduced chromium product produced a part of iron and chromium in chromium ore, dissolving the pre-reduced chromium product in hydrochloric acid and/or sulfuric acid iron and chromium. Thus, the dissolving step can be simplified, the predetermined concentration can be simply regulated.Type: GrantFiled: July 2, 1986Date of Patent: March 22, 1988Assignees: Japan Metals and Chemical Co., Ltd., Agency of Industrial Science and TechnologyInventors: Hiroko Kaneko, Ken Nozaki, Takeo Ozawa, Koichi Oku, Takashi Shimanuki, Yoshinori Koga
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Patent number: 4701349Abstract: A silicide layer of a refractory metal for reducing resistance and a nitride layer for preventing diffusion of aluminum are formed on the source and drain regions of an MISFET. The silicide layer is formed in self-alignment with the source and drain regions by two annealings effected at a low temperature and at a high temperature, respectively, and has a low resistance. The nitride layer is formed by directly nitriding the silicide layer.Type: GrantFiled: December 9, 1985Date of Patent: October 20, 1987Assignee: Hitachi, Ltd.Inventors: Mitsumasa Koyanagi, Hiroko Kaneko
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Patent number: 4699471Abstract: An electrochromic light transmission control device in which the electrochromic film is operated under control not to reach the color saturation condition, thereby preventing the occurrence of separation of the film and thus ensuring a long-term service life.Type: GrantFiled: June 4, 1985Date of Patent: October 13, 1987Assignee: Ricoh Company, Ltd.Inventors: Kiyoshi Miyake, Hiroko Kaneko
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Patent number: 4521081Abstract: A process for forming an electrochromic film to be used in an electrochromic device is provided. The process includes a step of introducing a mixture of oxygen gas and inert gas at a predetermined mixing ratio into a reactor in which is provided an electrode having thereon a sheet of tungsten as a target and a counter-electrode holding thereon a substrate under a predetermined total pressure condition and a step of applying a predetermined voltage between said electrodes while maintaining the substrate at a predetermined temperature. The present process allows to provide a WO.sub.3 -sputtered film on the substrate. The present invention also provides an electrochromic display device in which the electrochromic film is operated under control not to reach the color saturation condition, thereby preventing the occurrence of separation of the film and thus ensuring a long-term servicelife.Type: GrantFiled: March 25, 1982Date of Patent: June 4, 1985Assignee: Ricoh Company, Ltd.Inventors: Kiyoshi Miyake, Hiroko Kaneko
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Patent number: 4362791Abstract: In a redox battery using a titanium redox system or chromium redox system as an active material for the negative electrode or a manganese redox system as an active material for the positive electrode, the electromotive force of the battery and the stability of electrolyte solutions are enhanced by addition of a chelating agent such as citric acid or a complexing agent such as phosphoric acid to the redox system used therein.Type: GrantFiled: March 23, 1981Date of Patent: December 7, 1982Assignees: Agency of Industrial Science & Technology, Ministry of International Trade & IndustryInventors: Hiroko Kaneko, Ken Nozaki