Patents by Inventor Hiroshi Mera
Hiroshi Mera has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 5196531Abstract: A novel poly(N-cyclic iminoether) compound and a process for production thereof which comprises (a) reacting a polyisocyanate compound with a haloalkyleneamine or (b) reacting a polyamine with an alkyl isocyanate, and then (c) cyclizing the resulting polyurea compound. Several thermosetting compositions containing the novel poly(N-cyclic iminoether) and thermoset resins therefrom are also proposed.Type: GrantFiled: August 18, 1992Date of Patent: March 23, 1993Assignee: Teijin LimitedInventors: Hiroyuki Umetani, Hiroshi Mera, Hiroo Inata, Shunichi Matsumura
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Patent number: 5189094Abstract: A process for producing a thermoset resin, which comprises reacting (A) a poly(cyclic iminoether), (B) an ethylenically unsaturated compound having a functional group reactive with the poly(cyclic iminoether), and (C) an ethylenically unsaturated monomer having no functional group reactive with the poly(cyclic iminoether), in the presence of an acid catalyst and a radical catalyst. Instead of the compound (B), there may be used the compound (D), i.e. a compound having at least two equivalents of at least one group selected from the class consisting of carboxyl, hydroxyl, amino, epoxy and carboxylic anhydride groups in the molecule and being free from an ethylenically unsaturated bond. The present application provides also a thermosetting composition and a thermoset resin.Type: GrantFiled: April 1, 1991Date of Patent: February 23, 1993Assignee: Teijin LimitedInventors: Hiroyuki Umetani, Hiroo Inata, Shunichi Matsumura, Hiroshi Mera
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Patent number: 5068296Abstract: A cross-linked copolymer containing repeating units derived from a mixture comprising the following monomers: ##STR1## and occasionally other repeating units derived from other metathesis polymerizable cyclic compounds such as dicyclopentadiene, a process for producing the copolymer, a process for producing a molded article from the copolymer and a polymerizable composition therefor.Type: GrantFiled: February 25, 1991Date of Patent: November 26, 1991Assignee: Hercules IncorporatedInventors: Shigeyoshi Hara, Zen-ichiro Endo, Hiroshi Mera
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Patent number: 5064919Abstract: A process for producing a molded article by introducing a reactive liquid mixture which comprises a cycloalkene containing dicyclopentadiene, a norbornene-type monomer containing at least one N-substituted 5-membered cyclic imide group and a metathesis polymerization catalyst system and which has moderated metathesis polymerizability into a mold in which the liquid mixture is metathesis polymerized, and a multi-part polymerizable composition for producing the molded article.Type: GrantFiled: November 24, 1989Date of Patent: November 12, 1991Assignee: Hercules IncorporatedInventors: Shigeyoshi Hara, Zen-ichiro Endo, Hiroshi Mera
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Patent number: 5006616Abstract: A cross-linked copolymer containing repeating units derived from a mixture comprising the following monomers: ##STR1## and occasionally other repeating units derived from other metathesis polymerizable cyclic compounds such as dicyclopentadiene, a process for producing the copolymer, a process for producing a molded article from the copolymer and a polymerizable composition therefor.Type: GrantFiled: February 16, 1988Date of Patent: April 9, 1991Assignee: Hercules IncorporatedInventors: Shigeyoshi Hara, Zen-ichiro Endo, Hiroshi Mera
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Patent number: 4994535Abstract: A cross-linked copolymer containing repeating units derived from dicyclopentadiene and metathesis polymerizable halogen-containing cycloalkenes, a process for producing the copolymer, a process for producing a molded article from the copolymer and a polymerizable composition therefor.Type: GrantFiled: January 10, 1990Date of Patent: February 19, 1991Assignee: Hercules IncorporatedInventors: Zen-ichiro Endo, Shigeyoshi Hara, Hiroshi Mera
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Patent number: 4749753Abstract: An intimate mixture comprising (A) a substantially linear aromatic polyazole and (B) a sparingly crystallizable aromatic copolyamide having a glass transition temperature of at least 200.degree. C. and a flow initiation temperature of not more than 500.degree. C. in such proportions represented by A/(A+B)=0.15-0.70 by weight, and a process for producing the intimate mixture, which comprises dissolving the aromatic polyazole (A) and the aromatic copolyamide (B) in a weight ratio represented by A/(A+B)=0.15-0.70 in a common solvent, and forming an intimate mixture of the aromatic polyazole (A) and the aromatic copolyamide (B) from the solution using a coagulating agent.Type: GrantFiled: July 1, 1986Date of Patent: June 7, 1988Assignee: Agency of Industrial Science and TechnologyInventors: Toshio Nishihara, Hiroshi Mera, Zenichiro Endo
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Patent number: 4507467Abstract: High modulus shaped articles such as fibers and films, composed of a wholly aromatic copolyamide, are provided. The wholly aromatic copolyamide is comprised of recurring units of the formulae:--NH--AR.sub.1 --NH--CO--Ar.sub.2 --CO-- (A)and--NH--Ar.sub.3 --CO-- (B)wherein Ar.sub.1, Ar.sub.2 and Ar.sub.3 independently stand for divalent groups selected from ##STR1## in which X's independently stand for a group selected from halogeno, alkyl, aralkyl, aromatic, alkoxy, acetyl and cyano, n is 1 to 3 and Y is selected from ##STR2## in which R' stands for an 1-5C alkyl group, and the copolymerization ratio expressed by the molar ratio of the total of Ar.sub.1, Ar.sub.2 and Ar.sub.3 fails within the square hatched region in a triangular coordinate of FIG. 1, and said copolyamide has an intrinsic viscosity of at least 1.5.Type: GrantFiled: August 29, 1983Date of Patent: March 26, 1985Assignee: Teijin LimitedInventors: Keizo Shimada, Hideharu Sasaki, Hiroshi Mera, Toru Sawaki, Akihiro Aoki
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Patent number: 4413114Abstract: An aromatic copolyamide comprising recurring units (A) of the formula (I), (B) of the formula (II) and (C) of the formula (III): ##STR1## wherein in (I), (II) and (III), Ar.sub.1 is phenylene, naphthylene or biphenylene radicals, each having two valence bonds oriented meta; Ar.sub.2 is phenylene, naphthylene or biphenylene radicals, each having two valence bonds oriented coaxially or in parallel to each other and radicals of the formula (IV): ##STR2## wherein Y.sub.1 and Y.sub.2 are independently ##STR3## and; X.sub.1, X.sub.2, X.sub.3, X.sub.4, X.sub.5 and X.sub.6 respectively are independently --NH-- and --CO-- radicals, connected to each other to form an amide bond (--NHCO-- or --CHNH--), and the molar proportions of said recurring units (A), (B), and (C) fall within a quadrilateral defined by the co-ordinates P, Q, R and S or on a twice-turned line defined by the co-ordinates Q, R, S and P:P (A 50, B 5, C 45)Q (A 5, B 5, C 90)R (A 5, B 40, C 55) andS (A 50, B 15, C 35)on a triangular composition diagram.Type: GrantFiled: March 30, 1982Date of Patent: November 1, 1983Assignee: Teijin LimitedInventors: Keizo Shimada, Hiroshi Mera, Noriaki Sasaki, Akihiro Aoki
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Patent number: 4389521Abstract: An aromatic and/or heterocyclic polyamide-amide type polar solvent composition is prepared by prepolymerizing an aromatic or heterocyclic diamine with an aromatic or heterocyclic or heterocyclic dicarboxylic acid chloride in a smaller molar equivalent than that of the diamine to prepare a prepolymer solution having a solution viscosity of 20 poise or less; by removing a by-product, hydrochloric acid, from the resultant prepolymer solution by neutralizing it with ammonia to such an extent that the pH of a mixture of 10 g of the neutralized mixture with 200 ml of water becomes 3.7 to 8.0; by high polymerizing the prepolymer with an additional amount of aromatic or heterocyclic dicarboxylic acid chloride, and; finally, by converting the entire amount of hydrochloric acid and 10 to 70% NH.sub.Type: GrantFiled: November 19, 1981Date of Patent: June 21, 1983Assignee: Teijin LimitedInventors: Keizo Shimada, Hiroshi Mera, Tsutomu Nakamura, Akihiro Aoki
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Patent number: 4355151Abstract: An aromatic copolyamide comprising recurring units (A) of the formula (I), (B) of the formula (II) and (C) of the formula (III): ##STR1## wherein in (I), (II) and (III) Ar.sub.1 is phenylene, naphthylene or biphenylene radicals, each having two valence bonds oriented meta; Ar.sub.2 is phenylene, naphthylene or biphenylene radicals, each having two valence bonds oriented coaxially or in parallel to each other and radicals of the formula (IV): ##STR2## wherein Y.sub.1 and Y.sub.2 are independently; ##STR3## and; X.sub.1, X.sub.2, X.sub.3, X.sub.4, X.sub.5 and X.sub.6 respectively are independently --NH-- and --CO-- radicals, connected to each other to form an amide bond (--NHCO-- or --CHNH--), and the molar proportions of said recurring units (A), (B) and (C) fall within a quadrilateral defined by the co-ordinates P, Q, R and S or on a twice-turned line defined by the co-ordinates Q,R,S, and P:P (A 50, B 5, C 45)Q (A 5, B 5, C 90)R (A 5, B 40, C 55) andS (A 50, B 15, C 35)on a triangular composition diagram.Type: GrantFiled: February 13, 1980Date of Patent: October 19, 1982Assignee: Teijin LimitedInventors: Keizo Shimada, Hiroshi Mera, Noriaki Sasaki, Akihiro Aoki
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Patent number: 4342715Abstract: A wholly aromatic polyamide shaped article is prepared by a process wherein a solution of a wholly aromatic polyamide is extruded through an orifice and introduced into a first coagulating bath comprising an aqueous coagulating liquid and, then, the coagulated extrudate is introduced into a second coagulating bath comprising an aqueous solution of an inorganic salt.Type: GrantFiled: October 29, 1980Date of Patent: August 3, 1982Assignee: Teijin LimitedInventors: Keizo Shimada, Akihiro Aoki, Hiroshi Mera, Tsutomu Nakamura
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Patent number: 4250073Abstract: An aromatic polyamide composition usable for producing shaped articles, for instance, filaments, comprises the components of an aromatic polyamide resin (P), a polar amide solvent (S) and an auxiliary solvent (H) consisting of a halogenated hydrocarbon, for example, dichloromethane and dichloroethane, the proportions of the components (P), (S) and (H) being on or within a quadrilateral A C D E defined by the co-ordinates:A (P 5.0, S 30.0, H 65.0 )C (P 45.0, S 30.0, H 25.0)D (P 57.0, S 38.0, H 5.0) andF (P 5.0, S 90.0, H 5.0).The composition also contains a solubility enhancing agent consisting of one or more inorganic halide, such as alkali metal halides, alkaline earth metal halides and ammonium halides, in amount of from 5 to 60%, based on the weight of the polyamide resin.Type: GrantFiled: August 14, 1979Date of Patent: February 10, 1981Assignee: Teijin LimitedInventors: Yorikazu Tamura, Akihiro Aoki, Hiroshi Mera, Keizo Shimada
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Patent number: 4172938Abstract: An aromatic polyamide having a high degree of polymerization is produced by polymerizing(A) a mixture of an aromatic diamine of the formula (1):H.sub.2 N--Ar.sub.1 --NH.sub.2 (1)and an aromatic dicarboxylic acid dihalide of the formula (2):XOC--Ar.sub.2 --COX (2)(b) a mixture of the aromatic diamine of the formula (1), the aromatic dicarboxylic acid dihalide of the formula (2) and a hydrogen halide salt of an aromatic amino carboxylic acid halide of the formula (3):XH.multidot.H.sub.2 N--Ar.sub.3 --COX (3)or(C) the hydrogen halide salt of the aromatic amino carboxylic acid halide of the formula (3) alone,Wherein Ar.sub.1, Ar.sub.2 and Ar.sub.Type: GrantFiled: June 13, 1977Date of Patent: October 30, 1979Assignee: Teijin LimitedInventors: Hiroshi Mera, Yasuo Nakagawa, Masahiro Yamaguchi, Mitsuyuki Ohno
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Patent number: 4018735Abstract: An anisotropic aromatic polyamide dope comprising more than 10% by weight of an aromatic polyamide and a solvent for the polyamide, said polyamide consisting essentially of, at least 5 mole% but less than 35 moles%, based on its entire units, of an only partially p-oriented structural unit expressed by the following formula ##STR1## wherein Ar.sup.1 is a divalent aromatic ring whose chain-extending bonds are coaxial or parallel, X is a member selected from the group consisting of O, S and NH, and the NH group bonded to the benzene ring of the above benzoxazole, benzothiazole or benzimidazole ring is meta or para to the carbon atom of said benzene ring.Type: GrantFiled: July 8, 1975Date of Patent: April 19, 1977Assignee: Teijin LimitedInventors: Yasuo Nakagawa, Takashi Noma, Hiroshi Mera