Abstract: A method of operating a phosphoric acid fuel cell is provided, in which the phosphoric acid fuel cell effects power generation at a high output. A power-generating cell is provided with an electrolyte layer comprising a matrix composed of basic polymer impregnated with acidic liquid electrolyte such as phosphoric acid. The phosphoric acid fuel cell has a fuel cell stack comprising a single unit of the power-generating cell or a predetermined number of the power-generating cells electrically connected in series to one another. When the phosphoric acid fuel cell is operated, the supply pressures of the oxygen-containing gas and the hydrogen-containing gas are set so that the pressure on a cathode electrode of the power-generating cell is higher than that of an anode electrode.

Abstract: A proton conducting polymer obtained by blending an organic phosphoric acid compound solution with a meta type polyaniline solution; a solid polymer electrolyte for a fuel cell comprising the proton conducting polymer, which is excellent in proton conductivity, methanol barrier property and dopant stability in an aqueous solution of methanol; and an electrode comprising the proton conducting and fine catalyst particles carried on porous particles.

Abstract: A proton conducting polymer obtained by blending an organic phosphoric acid compound solution with a meta type polyaniline solution; a solid polymer electrolyte for a fuel cell comprising the proton conducting polymer, which is excellent in proton conductivity, methanol barrier property and dopant stability in an aqueous solution of methanol; and an electrode comprising the proton conducting and fine catalyst particles carried on porous particles.

Abstract: An improved metal alloy fuel cell electrocatalyst composition containing platinum, rhodium, molybdenum, and nickel iron or a combination thereof.

Abstract: Sulfonic acid group-containing polyvinyl alcohol having crosslinked structures, which is obtained by heat treating a mixed solution of polyvinyl alcohol, a sulfonating agent and a crosslinking agent, a composite polymer membrane excellent in proton conductivity and methanol barrier property, which is obtained by applying the mixed solution to a water-absorptive or hydrophilic polymer membrane, followed by sulfonation and crosslinking, and an electrode for a fuel cell excellent in catalytic activity, which comprises sulfonic acid group-containing polyvinyl alcohol having crosslinked structures and fine catalyst particles carried on porous particles.

Abstract: A fuel cell has a unit cell whose output is increased. A unit cell of a fuel cell includes a cathode electrode having a gas diffusion layer and an electrode catalyst layer. The electrode catalyst layer is made of carbon black carrying a Pt—Mn-based alloy such as a Pt—Mn alloy on its particle surface. For operating the fuel cell which includes the cathode electrode, it is preferable to make the pressure of an oxygen-containing gas supplied to the cathode electrode higher than the pressure of an hydrogen-containing gas supplied to an anode electrode to make the pressure at the cathode electrode higher than the pressure at the anode electrode.

Abstract: A proton conducting polymer obtained by blending an organic phosphoric acid compound solution with a meta type polyaniline solution; a solid polymer electrolyte for a fuel cell comprising the proton conducting polymer, which is excellent in proton conductivity, methanol barrier property and dopant stability in an aqueous solution of methanol; and an electrode comprising the proton conducting and fine catalyst particles carried on porous particles.

Abstract: A proton conducting polymer obtained by blending an organic phosphoric acid compound solution with a meta type polyaniline solution; a solid polymer electrolyte for a fuel cell comprising the proton conducting polymer, which is excellent in proton conductivity, methanol barrier property and dopant stability in an aqueous solution of methanol; and an electrode comprising the proton conducting and fine catalyst particles carried on porous particles.

Abstract: A proton conducting polymer obtained by blending an organic phosphoric acid compound solution with a meta type polyaniline solution; a solid polymer electrolyte for a fuel cell comprising the proton conducting polymer, which is excellent in proton conductivity, methanol barrier property and dopant stability in an aqueous solution of methanol; and an electrode comprising the proton conducting and fine catalyst particles carried on porous particles.

Abstract: A solid polymer electrolyte membrane excellent in proton conductivity and methanol barrier property, which is composed of a composite membrane obtained by allowing aniline to be adsorbed by a perfluorosulfonic acid polymer membrane, and subjecting the aniline to oxidative polymerization to form a polyaniline-containing polymer membrane.

Abstract: A phosphoric acid fuel cell is efficiently produced. As a matrix, a material is used which can hold therein a impregnating liquid electrolyte and which can release the impregnating liquid electrolyte when the material is pressed. In step S1, the matrix is impregnated with the liquid electrolyte such as phosphoric acid, sulfuric acid, and methanesulfonic acid to provide an electrolyte layer. In step S2, the electrolyte layer is interposed between an anode electrode and a cathode electrode to provide a stack. In step S3, the stack is pressed. By pressing the stack, the electrolyte layer is joined to the anode electrode and the cathode electrode and the liquid electrolyte is diffused from the matrix to electrode catalyst layers of both of the electrodes.

Abstract: A method of operating a phosphoric acid fuel cell is provided, in which the phosphoric acid fuel cell effects power generation at a high output. A power-generating cell is provided with an electrolyte layer comprising a matrix composed of basic polymer impregnated with acidic liquid electrolyte such as phosphoric acid. The phosphoric acid fuel cell has a fuel cell stack comprising a single unit of the power-generating cell or a predetermined number of the power-generating cells electrically connected in series to one another. When the phosphoric acid fuel cell is operated, the supply pressures of the oxygen-containing gas and the hydrogen-containing gas are set so that the pressure on a cathode electrode of the power-generating cell is higher than that of an anode electrode.

Abstract: A novel method for producing a meta type polyaniline, comprising polymerizing aniline in at least one organic solvent selected from N-methyl-2-pyrrolidone, N,N-dimethyl sulfoxide, N,N-dimethylacetamide and N,N-dimethylformamide, in the presence of at least one oxidizing agent selected from ammonium peroxodisulfate, iron(III) chloride, manganese dioxide and hydrogen peroxide, at −20° C. to 50° C.

Abstract: A method of fabricating Cu&agr;(InxGa1−x)&bgr;(SeyS1−y)&ggr; films for solar cells includes forming an electrode on a substrate and supplying the substrate and electrode with Cu, In, Ga, Se, and S to form a Cu&agr;(InxGa1−x)&bgr;(SeyS1−y)&ggr; film. Simultaneously with the supplying of Cu, In, Ga, Se and S, the substrate is supplied with water vapor or a gas that contains a hydroxyl group.

Abstract: This invention provides a solid polymer electrolyte which is low in water absorption, from which no dopant runs out even in pressing, and which is excellent in stability in the presence of water or methanol, proton conductivity and methanol barrier properties, in which an imidazole ring-containing polymer such as a polybenzimidazole compound is doped with an acid in which at least one hydrogen atom of an inorganic acid such as phosphoric acid is substituted by a functional group having a phenyl group by blending the imidazole ring-containing polymer with the acid in a solution using a solvent such as trifluoroacetic acid, preferably at a rate of 1 to 10 molecules of the acid per repeating structure unit of a molecular chain of the imidazole ring-containing polymer, the solid polymer electrolyte.