Abstract: An ozone-photocatalysis reactor, comprising: a shell layer (1); activated carbon layers (2) arranged in the shell layer (1); and at least one photoxidation unit arranged in the shell layer (1) and above the activated carbon layers (2). The photoxidation unit comprises a honeycomb activated carbon layer I (3), a light source layer and a honeycomb activated carbon bed layer II (4) sequentially from bottom to top. A gas inlet (7) and a water inlet (6) are formed in the shell layer below the activated carbon layers (2); a water outlet (9) and a gas outlet (10) are formed in the shell layer (1) above the photoxidation unit; and the activated carbon layers (2), at least one honeycomb activated carbon bed layer I (3) and at least one honeycomb activated carbon bed layer II (4) are loaded with a solid catalyst. The reactor uses ozone oxidation and ozone-photocatalysis sufficiently for sewage treatment, the treatment time is short, and the treatment efficiency is high.

Abstract: The present disclosure provides a recycling method of amphiphilic surface-active pollutants in water, comprising: performing a polymerization reaction by illumination treatment on the amphiphilic surface-active pollutants in water to form a polymerization product; performing self-assembly on the polymerization product for aggregation to form a fluorescent material, and performing separation to obtain a recycled product. Through treatment of the amphiphilic surface-active pollutants by illumination, the present disclosure can realize the recycled utilization of the amphiphilic pollutants in the wastewater by one step of reaction, so that the amphiphilic surface-active pollutants can be converted into usable fluorescent materials, and the biological toxicity is greatly reduced.

Abstract: A system for extracting vanadium from a leaching solution containing vanadium chromium silicon and for preparing vanadium pentoxide, and a method therefor, the system comprising, in sequence: an impurity removal system, an extraction system, a reverse-extraction and vanadium precipitation system, a washing system and a calcining system. The method comprises the following steps: removing silicon in a leaching solution by using a silicon removal agent, extracting most of the vanadium to an organic phase by using centrifugal extraction, reverse-extracting the vanadium of a vanadium-rich organic phase by using a mixed solution containing a basic solution and an ammonium salt, and precipitating ammonium metavanadate to obtain an ammonium metavanadate solid, washing and drying, and then calcining at a certain temperature to obtain a low chromium, low silicon, low aluminum and high-purity vanadium pentoxide product.

Abstract: The present disclosure relates to a treatment method of wastewater containing heterocyclic organics comprising the following steps: (1) adding a persulfate to the wastewater containing heterocyclic organics in a reaction vessel; (2) heating the reaction vessel to a reaction temperature in an inert atmosphere, then introducing an oxygen-containing gas until a reaction pressure is reached for reaction, and after the reaction is completed, cooling and filtering the reaction resultant to obtain a filtrate as a treated effluent and a filter residue; no catalyst is added to the reaction system. The treatment method provided by the present disclosure not only can significantly reduce the treatment temperature of the conventional wet oxidation, but also can control the amount of generated spherical polymer and the removal efficiency of organic pollutants by control of reaction conditions. Wastewater purification and organics recovery and reuse are achieved at the same time.

Abstract: The present disclosure provides a fluorescent nanomaterial and a preparation method and applications thereof, and the preparation method comprises: subjecting amphiphilic molecules in a solvent system to an illumination treatment and/or a heat treatment to obtain fluorescent nanomaterials. The preparation of fluorescent nanomaterials provided by the present disclosure is simple in process, simple and easily available in raw materials and requires neither additional addition of a strong acid, a strong alkali, a passivating agent and the like, nor high temperature and high pressure in the preparation process. The whole process is environmentally friendly and pollution-free and the products can be used in various fields.

Abstract: Embodiments of the present disclosure disclose a quick intra code-rate predicting method in the field of video coding, which may skip an entropy coding procedure during an RDO process by modeling residual information of a prediction block and predicting the number of coding bits of the prediction block based on an information entropy theory under a corresponding model. The code-rate predicting method comprises: making statistics on prediction block distribution information and modeling to obtain a combined model, predicting the number of coding bits of a prediction mode based on the model, and correcting the predicted number of coding bits for predicting the code-rate of each prediction mode during the RDO process, so as to replace a high time complexity in an actual entropy coding procedure, thereby effectively reducing the coding time with less video quality loss. The present disclosure is applicable to Iframe code-rate prediction for in video coding.

Abstract: The present disclosure relates to a method for photocatalytic ozonation reaction, in which the silicon carbide material is used. By using the silicon carbide material for photocatalytic ozonation reaction, the present disclosure overcomes the problem of low photocatalytic efficiency of silicon carbide, utilizes photogenerated electrons therefrom with strong reducibility to reduce ozone molecules to efficiently produce hydroxyl radicals, so as to improve the oxidation capacity in the process. Whether visible light or ultraviolet light is coupled with ozone, the group has strong catalytic activity, moreover, the silicon carbide has low cost and good stability, which prolongs the life of catalyst for photocatalytic ozonation or device.

Abstract: The present invention provides carbon quantum dots, preparation method and uses thereof. The preparation method of the carbon quantum dots comprises the following steps: (1) preparing a dispersion of carbon based material; (2) mixing a solution of halogenated quinone with the dispersion of carbon based material and preparing a dispersion of carbon based-halogenated quinone composite material by halogenated quinone grafting method; (3) adding a solution of H2O2 to the dispersion of carbon based-halogenated quinone composite material and carrying out reaction thereof, obtaining reaction products; (4) carrying out solid-liquid separation to the reaction products, with the resulting filtrate continuing to react, thus obtaining a dispersion of carbon quantum dots. This method adopts metal-free catalytic oxidation, the process of which is safe, convenient and low-cost, and is performed under a mild reaction condition without adding additional substances which are difficult to be separated.

Abstract: An ozone-photocatalysis reactor, comprising: a shell layer (1); activated carbon layers (2) arranged in the shell layer (1); and at least one photoxidation unit arranged in the shell layer (1) and above the activated carbon layers (2). The photoxidation unit comprises a honeycomb activated carbon layer I (3), a light source layer and a honeycomb activated carbon bed layer II (4) sequentially from bottom to top. A gas inlet (7) and a water inlet (6) are formed in the shell layer below the activated carbon layers (2); a water outlet (9) and a gas outlet (10) are formed in the shell layer (1) above the photoxidation unit; and the activated carbon layers (2), at least one honeycomb activated carbon bed layer I (3) and at least one honeycomb activated carbon bed layer II (4) are loaded with a solid catalyst. The reactor uses ozone oxidation and ozone-photocatalysis sufficiently for sewage treatment, the treatment time is short, and the treatment efficiency is high.

Abstract: The present invention provides a method and a reactor for removing organic matters by immobilized-enzymatic electrode coupled electro-coagulation. In the method, in a single electrochemical system, an enzyme-modified electrode is combined with electro-coagulation to synergistically remove organic matters from water. Certain electrochemical parameters are controlled such that a polymerization reaction is performed between hydrogen peroxide generated by a cathode reaction and organic matters catalyzed by the immobilized-enzymatic electrode. After the polymerization reaction, the organic product enters an anode chamber through a pump. The organic product is precipitated and removed by performing a reaction between the organic product and different hydrolysis products from the electro-coagulation through a coagulating/flocculating effect of compression of a double electric layer, adsorption and electric neutralization as well as precipitation capture.

Abstract: The present invention provides carbon quantum dots, preparation method and uses thereof. The preparation method of the carbon quantum dots comprises the following steps: (1) preparing a dispersion of carbon based material; (2) mixing a solution of halogenated quinone with the dispersion of carbon based material and preparing a dispersion of carbon based-halogenated quinone composite material by halogenated quinone grafting method; (3) adding a solution of H2O2 to the dispersion of carbon based-halogenated quinone composite material and carrying out reaction thereof, obtaining reaction products; (4) carrying out solid-liquid separation to the reaction products, with the resulting filtrate continuing to react, thus obtaining a dispersion of carbon quantum dots. This method adopts metal-free catalytic oxidation, the process of which is safe, convenient and low-cost, and is performed under a mild reaction condition without adding additional substances which are difficult to be separated.

Abstract: The present invention provides a heterogeneous metal-free Fenton catalyst, a method for preparing the same and use thereof. The catalyst is a carbon-based material surface-bonded with halogenated quinones, wherein the carbon-based material has synergistic action with halogenated quinones. The catalyst is prepared by grafting halogenated quinones onto the carbon-based material, or feeding chlorine during the carbonation process of the carbon-based material for oxidization. The production of hydroxyl radicals by using the catalyst has a low cost and a safe, simple and convenient process. The conditions for producing hydroxyl radicals are mild, without any secondary pollution. Moreover, the radical production has a high, continuous and stable yield, and the hydroxyl radicals can be effectively produced by using no chemicals which are harmful to human bodies, without any side product and any additional substances which are difficult to separate.

Abstract: The present invention relates to a synthetic method of graphitic carbon nitride material. The method involves a homogenous mixing of carbon nitride precursor and ammonium salt, and calcining the mixture to obtain a porous graphitic carbon nitride material. Wherein, the ammonium salt is any one or a combination of at least two which could release gaseous NH3 during thermolysis. The present invention uses thermolabile ammonium salt as a pore former; the thermolysis of ammonium salt could release soft gas bubbles during the calcination; the later burst of bubbles leads to the formation of nanoporous structure. The proposed method is template-free and environmentally-friendly, and the resultant material exhibits high photocatalytic activity in the field of gas and water decontamination.

Abstract: The present invention provides a method and a reactor for removing organic matters by immobilized-enzymatic electrode coupled electro-coagulation. In the method, in a single electrochemical system, an enzyme-modified electrode is combined with electro-coagulation to synergistically remove organic matters from water. Certain electrochemical parameters are controlled such that a polymerization reaction is performed between hydrogen peroxide generated by a cathode reaction and organic matters catalyzed by the immobilized-enzymatic electrode. After the polymerization reaction, the organic product enters an anode chamber through a pump. The organic product is precipitated and removed by performing a reaction between the organic product and different hydrolysis products from the electro-coagulation through a coagulating/flocculating effect of compression of a double electric layer, adsorption and electric neutralization as well as precipitation capture.