Patents by Inventor Horst Zinke
Horst Zinke has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Publication number: 20020151444Abstract: There are disclosed compounds of formula I 1Type: ApplicationFiled: March 28, 2002Publication date: October 17, 2002Inventors: Horst Zinke, Rolf Schumacher
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Patent number: 6380139Abstract: There are disclosed compounds of formula I wherein R1 and R2 are each independently of the other C3-C18alkyl, C5-C12cycloalkyl, C5-C6cycloalkylmethyl, C9-C10bicycloalkylmethyl, C9-C10tricycloalkylmethyl, phenyl, C7-C24alkylphenyl or, taken together, are R3 is C2-C18alkylene which is interrupted by —O—, —S—, or —NR4—, or is a group of formula R4 is hydrogen, C1-C18alkyl, phenyl-C1-C4alkyl, phenyl or C1-C6alkyl-substituted phenyl, R5 is hydrogen or methyl. These compounds are particularly suitable for use as additives for lubricant compositions, hydraulic fluids and machining fluids.Type: GrantFiled: May 26, 1995Date of Patent: April 30, 2002Assignee: Ciba Specialty Chemicals CorporationInventors: Horst Zinke, Rolf Schumacher
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Patent number: 6013703Abstract: A stabilizer combination, principally for PVC, is described which essentially comprisesA) at least one zinc compound of the formula IZn(R.sup.1 R.sup.2) (I)andB) at least one metal compound of the formula IIMe.sup.n+ (R.sup.3.sub.a R.sup.4.sub.b R.sup.5.sub.c) (II)in which Me is Al, Mg, Na or K,a, b and c are 0, 1, 2 or 3,n=a+b+c and can be from 1 to 3, and at least one radical R.sup.1 to R.sup.5 independently of one another are C.sub.1 -C.sub.22 carboxylates, C.sub.2 -C.sub.21 alkenyl-CO.sub.2 --, phenyl-CO.sub.2 --, naphthyl-CO.sub.2 --, C.sub.5 -C.sub.12 cycloalkyl-CO.sub.2 --, C.sub.7 -C.sub.18 alkylphenyl-CO.sub.2 --, C.sub.7 -C.sub.18 alkylphenyl-O--, C.sub.7 -C.sub.9 phenylalkyl-CO.sub.2 --, C.sub.1 -C.sub.21 -alkyl-O--, R.sup.8 --O--CO--[CH.sub.2 ].sub.p --S-- or a radical of the formula R.sup.6 --CO--CH.dbd.CR.sup.7 --O.sup..crclbar.Type: GrantFiled: March 19, 1997Date of Patent: January 11, 2000Assignee: Witco Vinyl Additives GmbHInventors: Karl Josef Kuhn, Wolfgang Wehner, Horst Zinke
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Patent number: 5969015Abstract: Compositions, comprising (i) a halogen-containing polymeric material, and(ii) at least one phosphite of formula I ##STR1## wherein n is a number from 1 to 6,R is a divalent linking group of formulae as defined herein as well as of novel compounds of formula I and their use as stabilisers.Type: GrantFiled: September 10, 1997Date of Patent: October 19, 1999Assignee: Witco Vinyl Additives GmbHInventors: Horst Zinke, Karl Josef Kuhn, Wolfgang Wehner
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Patent number: 5804622Abstract: A stabilizer combination, principally for PVC, is described, comprising A at least one zinc carboxylate B at least one compound of the formula ##STR1## in which R.sub.1 to R.sub.6 are as defined in claim 1.Type: GrantFiled: March 17, 1997Date of Patent: September 8, 1998Assignee: Ciba Specialty Chemicals CorporationInventors: Horst Zinke, Wolfgang Wehner, Karl Josef Kuhn, Valerio Borzatta, Gerhard Rytz
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Patent number: 5670563Abstract: The invention relates to compositions comprisinga) a chlorine-containing polymerb) at least one organotin compound andc) at least one phosphorus compound of formula(R.sub.7 S).sub.3 P.dbd.X.sub.nwherein the meaning of the individual substituents is as defined in the disclosure.Type: GrantFiled: July 17, 1995Date of Patent: September 23, 1997Assignee: Ciba-Specialty Chemicals CorporationInventors: Horst Zinke, Johannes Kaufhold
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Patent number: 5516827Abstract: Compositions comprising a chlorine-containing polymer and a stabilizer mixture comprising:a) at least one tin alcoholate or tin carboxylate of the formula[(R.sub.2).sub.2 Sn(OR')].sub.2 O (Ia);[(R.sub.2)Sn(OR').sub.2 ].sub.2 O (Ib);(R.sub.2)Sn(OR')O (Ic);[-(R.sub.2)Sn(OR')O--].sub.m (Id);[-(R.sub.1 CO.sub.2 Sn(R.sub.2).sub.2 ].sub.2 O (IIa);or[-(R.sub.2).sub.2 Sn--O.sub.2 C--R.sub.3 --CO.sub.2 --{(R.sub.2).sub.2 SnO{(R.sub.2).sub.2 SnO}.sub.i -].sub.n (IIb);b) at least one organic zinc carboxylate, zinc phenoxide or a tin chloride of the formula[(R.sub.1 CO.sub.2).sub.x (R.sub.2).sub.y CL.sub.z Sn].sub.n O.sub.n-1 (III)andc) at least one thiophosphate or thiophosphite of the formula(R.sub.6 S).sub.3 P.dbd.X.sub.b (IV)where the individual radicals are as defined in claim 1.Type: GrantFiled: January 24, 1995Date of Patent: May 14, 1996Assignee: Ciba-Geigy CorporationInventors: Johannes Kaufhold, Horst Zinke
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Patent number: 5401845Abstract: Compounds of the formula I ##STR1## in which x is 1, 2 or 3, and, if x=1, R.sup.1 is C.sub.1 -C.sub.30 alkyl, C.sub.1 -C.sub.18 alkyl substituted by halogen, --COOR.sup.2, --CN, --NR.sup.3 R.sup.4 or by --CONR.sup.3 R.sup.4, C.sub.2 -C.sub.18 alkyl which is interrupted by --NR.sup.5 --, --O-- or --S--, C.sub.3 -C.sub.18 alkenyl, C.sub.5 -C.sub.12 cycloalkyl, phenyl-C.sub.1 -C.sub.4 alkyl, phenyl which is unsubstituted or substituted by C.sub.1 -C.sub.12 alkyl, halogen, phenyl-C.sub.1 -C.sub.4 alkyl and/or C.sub.1 -C.sub.4 alkoxy, or R.sub.1 is naphthyl, a radical of the formula ##STR2## R.sub.2, R.sub.3, R.sub.4 and R.sub.5, independently of one another, are hydrogen, C.sub.1 -C.sub.18 alkyl, C.sub.5 -C.sub.12 cycloalkyl or phenyl-C.sub.1 -C.sub.4 alkyl, R.sup.6 is hydrogen, methyl, allyl or benzyl, R.sup.7 is hydrogen or --OR.sup.9, R.sup.8 is hydrogen or methyl, R.sup.9 is hydrogen or C.sub.1 -C.sub.30 alkyl, R.sup.10 and R.sup.11, independently of one another, are hydrogen or C.sub.1 -C.sub.Type: GrantFiled: March 11, 1994Date of Patent: March 28, 1995Assignee: Ciba-Geigy CorporationInventors: Rita Pitteloud, Peter Hofmann, Rudolf Maul, Volker Schenk, Eduard Troxler, Horst Zinke
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Patent number: 5362419Abstract: There are disclosed compounds of formula I ##STR1## R.sub.1 and R.sub.2 are each independently of the other C.sub.3 -C.sub.18 alkyl, C.sub.5 -C.sub.12 cycloalkyl, C.sub.5 -C.sub.6 cycloalkylmethyl, C.sub.9 -C.sub.10 bicycloalkylmethyl, C.sub.9 -C.sub.10 tricycloalkylmethyl, phenyl, C.sub.7 -C.sub.6 alkylphenyl or, taken together, are ##STR2## R.sub.3 is hydrogen or methyl, A is ##STR3## R.sub.4 is hydrogen or C.sub.1 -C.sub.6 alkyl, and R.sub.5 is a 5- or 6-membered saturated heterocyclic ring,R.sub.6 is hydrogen or methyl,n is an integer from 1 to 11 and m is an integer from 0 to 4.These compounds are particularly suitable for use as additives for lubricant compositions, hydraulic fluids and machining fluids.Type: GrantFiled: May 27, 1993Date of Patent: November 8, 1994Assignee: Ciba-Geigy CorporationInventors: Horst Zinke, Rolf Schumacher
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Patent number: 5360563Abstract: There are disclosed compounds of formulae I and Ia ##STR1## wherein R.sub.1 and R.sub.2 are each independently of the other C.sub.1 -C.sub.13 alkyl which may be interrupted by oxygen, C.sub.5 -C.sub.6 cycloalkyl or, together with the linking N-atom, are a group of formula ##STR2## R is hydrogen or methyl, R.sub.3 is hydrogen or C.sub.1 -C.sub.13 alkyl, andR.sub.4 and R.sub.5 are each independently of the other hydrogen, C.sub.1 -C.sub.18 alkyl which may be interrupted by oxygen, C.sub.5 -C.sub.6 cycloalkyl or, together with the linking N-atom, are a group of formula ##STR3## withe proviso that R.sub.3, R.sub.4 and R.sub.5 are not simultaneously hydrogen and HNR.sub.1 R.sub.2 are not identical with NR.sub.3 R.sub.4 R.sub.5.The compounds are suitable for use as lubricant additives.Type: GrantFiled: May 27, 1993Date of Patent: November 1, 1994Assignee: Ciba-Geigy CorporationInventors: Horst Zinke, Rolf Schumacher
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Patent number: 5322871Abstract: Compounds of the formula I ##STR1## in which x is 1, 2 or 3, and, if x=1, R.sup.1 is C.sub.1 -C.sub.30 alkyl, C.sub.1 -C.sub.18 alkyl substituted by halogen, --COOR.sup.2, --CN, --NR.sup.3 R.sup.4 or by --CONR.sup.3 R.sup.4, C.sub.2 -C.sub.18 alkyl which is interrupted by --NR.sup.5 --, --O-- or --S--, C.sub.3 -C.sub.18 alkenyl, C.sub.5 -C.sub.12 cycloalkyl, phenyl-C.sub.1 -C.sub.4 alkyl, phenyl which is unsubstituted or substituted by C.sub.1 -C.sub.12 alkyl, halogen, phenyl-C.sub.1 -C.sub.4 alkyl and/or C.sub.1 -C.sub.4 alkoxy, or R.sub.1 is naphthyl, a radical of the formula ##STR2## R.sub.2, R.sub.3, R.sub.4 and R.sub.5, independently of one another, are hydrogen, C.sub.1 -C.sub.18 alkyl, C.sub.5 -C.sub.12 cycloalkyl or phenyl-C.sub.1 -C.sub.4 alkyl, R.sup.6 is hydrogen, methyl, allyl or benzyl, R.sup.7 is hydrogen or --OR.sup.9, R.sup.8 is hydrogen or methyl, R.sup.9 is hydrogen or C.sub.1 -C.sub.30 alkyl, R.sup.10 and R.sup.11, independently of one another, are hydrogen or C.sub.1 -C.sub.Type: GrantFiled: April 20, 1993Date of Patent: June 21, 1994Assignee: Ciba-Geigy CorporationInventors: Rita Pitteloud, Peter Hofmann, Rudolf Maul, Volker Schenk, Eduard Troxler, Horst Zinke
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Patent number: 5308902Abstract: Biphosphites of formula I ##STR1## wherein m is 0, 1 or 2,n is 1 to 4 or 6,R.sub.1 is hydrogen or C.sub.1 -C.sub.4 alkyl and, if m=2, the radicals R.sub.1 are identical or different, and A is the radical of an at least n-hydric alcohol or phenol, which radical is attached to the P atom or atoms through the alcoholic or phenolic O atom or atoms, obtainable by reacting a compound of formula II ##STR2## wherein m is 0, 1 or 2, R.sub.1 is hydrogen or C.sub.1 -C.sub.4 alkyl and, if m=2, the radicals R.sub.1 are identical or different and R.sub.2 ' is phenyl, C.sub.1 -C.sub.12 alkylphenyl or C.sub.1 -C.sub.4 alkyl, with a polyether polyol or polyether/ester polyol, the hydroxy functions of said polyether polyol or polyether/ester polyol being partially or completely esterified with the ##STR3## are suitable for use as stabilizers, especially processing stabilizers, for organic polymers, preferably PVC resins, high density polyethylene and propylene.Type: GrantFiled: May 14, 1992Date of Patent: May 3, 1994Assignee: Ciba-Geigy CorporationInventors: Holger Andreas, Alfred Renner, Horst Zinke
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Patent number: 5167844Abstract: Formulation containing A) a lubricant and a mixture of B) for example, at least one of the compounds O,O-bis-2-ethylhexylsodium dithiophosphate, O,O-bis-2-ethylhexylsodium thionophosphate, O,O-bis-2-methylpropylsodium dithiophosphate, O,O-bis-nonylphenylsodium dithiophosphate or S-[O,O-bis-2-ethylhexylthiophosphoryl]-potassium thioglycolate, C) at least one compound from the series of the aromatic amines, for example the diphenylamines or phenothiazines, and D) at least one compound from the series of the cyclic sterically hindered amines, the acyclic sterically hindered amines and the phenols of the formula ##STR1## wherein R.sup.4, R.sup.5 and A are, for example, alkyl radicals. Such lubricant formulations have a high degree of stability towards oxidative degradation.Type: GrantFiled: October 31, 1990Date of Patent: December 1, 1992Assignee: Ciba-Geigy CorporationInventors: Rolf Schumacher, Horst Zinke
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Patent number: 4917809Abstract: A composition comprising(a) one or more lubricants or hydraulic based on mineral oil or synthetic oils and(b) 0.05 to 5% by weight, relative to the total weight of the lubricant composition or hydraulic oil composition, of a mixture of(1) at least one compound of the formula I or II ##STR1## in which Y, Z, R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5, R.sup.6 and R.sup.7 as well as a are as defined in patent claim 1 and(2) at least one compound of the formulae III or IV ##STR2## in which X, X.sup.1, X.sup.2, R.sup.11, R.sup.12, m, n, n*, k, b and M are as defined in patent claim 1.Type: GrantFiled: November 2, 1987Date of Patent: April 17, 1990Assignee: Ciba-Geigy CorporationInventors: Horst Zinke, Rolf Schumacher
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Patent number: 4639482Abstract: Compositions for the stabilization of polyvinylchloride comprising blends or tri- and tetrathiophosphoric acid esters and at least one polyvinylchloride stabilizer of the type Me(II)-carboxylate and/or Me(II)-phenolate as well as the polyvinylchloride stabilized therewith.Type: GrantFiled: March 21, 1983Date of Patent: January 27, 1987Assignee: Ciba-Geigy CorporationInventors: Horst Muller, Horst Zinke, Wolfgang Wehner
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Patent number: 4544492Abstract: Lubricant compositions containing (a) a mineral and/or synthetic base oil and (b) at least one compound of the formula I ##STR1## wherein a is 0 or 1, b is 1 to 6, R is H or alkoxycarbonyl, R.sup.1 and R.sup.2 are independently alkyl, cycloalkyl, aryl, aralkyl or are together substituted alkylene and X is hydroxyl, alkoxy, aryloxy, amino, substituted amino or the residue of a polyol, are described.Type: GrantFiled: May 1, 1984Date of Patent: October 1, 1985Assignee: Ciba-Geigy CorporationInventors: Horst Zinke, Rolf Schumacher
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Patent number: 4492661Abstract: A process for producing triarylphosphites of the formula (RO).sub.3 P, in which R represents aryl or aryl substituted by one or more straight-chain or branched-chain alkyl, cycloalkyl, aryl or aralkyl groups, by reaction of phosphorus trihalides with hydroxy-substituted aromatic compounds of the formula ROH in the presence of 0.005 to 10 mol %, relative to the hydroxy-substituted aromatic compound, of a catalyst, optionally in the presence of a solvent, in which process the catalyst used is a compound from the group comprising amines or ammonium salts, amides of carboxylic and thiocarboxylic acids and also of oxygen acids of phosphorus, non-aromatic nitrogen-containing heterocycles and salts thereof, guanidines, amidines and azomethines and also salts thereof, sulfones, sulfoxides and sulfonium salts, primary, secondary and tertiary phosphines and salts thereof, phosphine oxides, phosphine sulfides or esters of phosphoric acids.Type: GrantFiled: July 5, 1983Date of Patent: January 8, 1985Assignee: Ciba-Geigy CorporationInventors: Rudolf Maul, Eberhard Otto, Horst Zinke
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Patent number: 4440696Abstract: A process for producing triarylphosphites of the formula (RO).sub.3 P, in which R represents aryl or aryl substituted by one or more straight-chain or branched-chain alkyl, cycloalkyl, aryl or aralkyl groups, by reaction of phosphorous trihalides with hydroxy-substituted aromatic compounds of the formula ROH in the presence of 0.005 to 10 mol %, relative to the hydroxy-substituted aromatic compound, of a catalyst, optionally in the presence of a solvent, in which process the catalyst used is a compound from the group comprising amines or ammonium salts, amides of carboxylic and thiocarboxylic acids and also of oxygen acids of phosphorus, non-aromatic nitrogen-containing heterocycles and salts thereof, guanidines, amidines and azomethines and also salts thereof, sulfones, sulfoxides and sulfonium salts, primary, secondary and tertiary phosphines and salts thereof, phosphine oxides, phosphine sulfides or esters of phosphoric acids.Type: GrantFiled: October 1, 1981Date of Patent: April 3, 1984Assignee: Ciba-Geigy CorporationInventors: Rudolf Maul, Eberhard Otto, Horst Zinke
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Patent number: 4424173Abstract: A process for producing thiophosphorous acid-O,O-diesters from corresponding phosphorous acid diester chlorides and hydrogen sulfide, in which process the acid acceptor used is ammonia. The thiophosphorous acid diesters obtained are suitable as intermediates for producing lubricant additives, fungicides or pharmaceutical products.Type: GrantFiled: March 31, 1982Date of Patent: January 3, 1984Assignee: Ciba-Geigy CorporationInventor: Horst Zinke
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Patent number: 4376054Abstract: 1,3,2-Dioxaphospholanes of the formula ##STR1## are suitable as high-pressure additives in natural and/or synthetic lubricating oils.Type: GrantFiled: October 15, 1981Date of Patent: March 8, 1983Assignee: Ciba-Geigy CorporationInventor: Horst Zinke