Patent number: 7955524
Abstract: A phosphor can be excited by UV, purple or blue light LED, its preparation method, and light emitting devices incorporating the same. The phosphor contains rare earth, silicon, alkaline-earth metal, halogen, and oxygen, as well as aluminum or gallium. Its General formula of is aLn2O3.MO.bM?2O3.fSiO2.cAXe:dR, wherein Ln is at least one metal element selected from a group consisting of Sc, Y, La, Pr, Nd, Gd, Ho, Yb and Sm; M is at least one metal element selected from a group consisting of Ca, Sr and Ba; M? is at least one metal element selected from Al and Ga; A is at least one metal element selected from a group consisting of Li, Na, K, Mg, Ca, Sr and Ba; X is at least one element selected from F and Cl; R is at least one metal element selected from a group consisting of Ce, Eu, Tb and Mn; 0.01?a?2, 0.35?b?4, 0.01?c?1, 0.01?d?0.3, 0.01?f?3, 0.6?e?2.4. The phosphor has broad emitting range, high efficiency, better uniformity and stability.
Type:
Grant
Filed:
September 19, 2008
Date of Patent:
June 7, 2011
Assignees:
General Research Institute for Nonferrous Metals, Beijing, Grirem Advanced Materials Co., Ltd.
Inventors:
Weidong Zhuang, Yunsheng Hu, Zhen Long, Xiaowei Huang, Hongwei Li, Shusheng Zhang, Huagiang He
Publication number: 20090128006
Abstract: A silicon-containing phosphor for LED and its preparation method, and the devices incorporating the same. The phosphor in the present invention can be represented as AO.aSiO2.bAX2:mEu2+,nR3+, wherein A is at least one metal element selected from a group consisting of Sr, Ba, Ca, Mg, and Zn; X is at least one halogen element selected from a group consisting of F, Cl, Br, and I; R is at least one element selected from a group consisting of Bi, Y, La, Ce, Pr, Gd, Tb, and Dy; 0.1<a<2, 0.005<b<0.08, 0.005<m<0.5, 0.005<n<0.5, and m+n<1. The phosphor has excellent luminescent performance and good stability, wide excitation band, and adjustable emission wavelength. White or color LED can be obtained by combining the phosphor of the present invention with UV, purple or blue light LED chip.
Type:
Application
Filed:
January 26, 2009
Publication date:
May 21, 2009
Applicants:
GENERAL RESEARCH INSTITUTE FOR NONFERROUS METALS, GRIREM ADVANCED MATERIALS CO. LTD.
Inventors:
Weidong ZHUANG, Yunsheng Hu, Ying Fang, Xiaowei Huang, Huagiang He
Publication number: 20090050918
Abstract: A phosphor can be excited by UV, purple or blue light LED, its preparation method, and light emitting devices incorporating the same. The phosphor contains rare earth, silicon, alkaline-earth metal, halogen, and oxygen, as well as aluminum or gallium. Its General formula of is aLn2O3.MO.bM?2O3.fSiO2.cAXe: dR, wherein Ln is at least one metal element selected from a group consisting of Sc, Y, La, Pr, Nd, Gd, Ho, Yb and Sm; M is at least one metal element selected from a group consisting of Ca, Sr and Ba; M? is at least one metal element selected from Al and Ga; A is at least one metal element selected from a group consisting of Li, Na, K, Mg, Ca, Sr and Ba; X is at least one element selected from F and Cl; R is at least one metal element selected from a group consisting of Ce, Eu, Tb and Mn; 0.01?a?2, 0.35?b?4, 0.01?c?1, 0.01?d?0.3, 0.01?f?3, 0.6?e?2.4. The phosphor has broad emitting range, high efficiency, better uniformity and stability.
Type:
Application
Filed:
September 19, 2008
Publication date:
February 26, 2009
Applicants:
GENERAL RESEARCH INSTITUTE FOR NONFERROUS METALS, BEIJING, GRIREM ADVANCED MATERIALS CO., LTD
Inventors:
Weidong Zhuang, Yunsheng Hu, Zhen Long, Xiaowei Huang, Hongwei Li, Shusheng Zhang, Huagiang He