Abstract: The present disclosure discloses a preparation method of a energetic metal coordination compound with 5-methyltetrazole, belonging to the technical field of energetic metal coordination compounds. The method comprises: dissolving methyltetrazole in distilled water, and adding a nitrate therein, to obtain a mixture; stirring the mixture for 30 min, then putting the mixture into a teflon-lined reactor, and reacting at a constant temperature of 120±1° C. for 72 h, to obtain a crude reaction product; cooling the crude reaction product to 80° C., thermally insulating for 12 h, and hereafter cooling to room temperature at a rate of 3° C./h, to obtain a target product. The coordination compound has a good explosion heat, high thermal stability, and low mechanical sensitivity. The present disclosure could obtain a product with a high yield by a green and environment-friendly method.

Abstract: The present disclosure discloses a preparation method of a energetic metal coordination compound with 5-methyltetrazole, belonging to the technical field of energetic metal coordination compounds. The method comprises: dissolving methyltetrazole in distilled water, and adding a nitrate therein, to obtain a mixture; stirring the mixture for 30 min, then putting the mixture into a teflon-lined reactor, and reacting at a constant temperature of 120±1° C. for 72 h, to obtain a crude reaction product; cooling the crude reaction product to 80° C., thermally insulating for 12 h, and hereafter cooling to room temperature at a rate of 3° C./h, to obtain a target product. The coordination compound has a good explosion heat, high thermal stability, and low mechanical sensitivity. The present disclosure could obtain a product with a high yield by a green and environment-friendly method.