Abstract: The invention relates to an unsaturated polyester resin comprising fumaric acid and optional end-capping with an ethylenically unsaturated moiety, which is useful for the preparation of engineered stone. The unsaturated polyester resin can be further processed to obtain a formable composition which can be cured to finally yield engineered stone as composite material. The thus obtained engineered stone shows a high resistance to UV- and sunlight as well as to weathering. The invention also relates to a method for the preparation of engineered stone as well as to the use of the unsaturated polyester resin for the preparation of engineered stone.

Abstract: The invention pertains to low profile additives (“LPA”) comprising branched polymers having a weight average molecular weight (Mw) of at least about 20,000 grams/mole and a number average molecular weight (Mn) of at least about 3,000 grams/mole and methods for making the LPAs. The invention further concerns compositions comprising LPAs synthesized from one or more difunctional monomers and one or more branching agents. Also, disclosed are thermosettable resinous compositions and molded articles comprising the LPAs.

Abstract: The invention pertains to low profile additives (“LPA”) comprising branched polymers having a weight average molecular weight (Mw) of at least about 20,000 grams/mole and a number average molecular weight (Mn) of at least about 3,000 grams/mole and methods for making the LPAs. The invention further concerns compositions comprising LPAs synthesized from one or more Bifunctional monomers and one or more branching agents. Also, disclosed are thermosettable resinous compositions and molded articles comprising the LPAs.

Abstract: The invention pertains to low profile additives (“LPA”) comprising branched polymers having a weight average molecular weight (Mw) of at least about 20,000 grams/mole and a number average molecular weight (Mn) of at least about 3,000 grams/mole and methods for making the LPAs. The invention further concerns compositions comprising LPAs synthesized from one or more difunctional monomers and one or more branching agents. Also, disclosed are thermosettable resinous compositions and molded articles comprising the LPAs.

Abstract: A coating composition which is capable of crosslinking at ambient and elevated temperatures which includes a polymerized monomer having the formula ##STR1## wherein R is hydrogen or an alkyl group containing 1-5 carbon atoms, R.sub.1 and R.sub.2 are hydrogen or a methyl group; --X-- is a bond, --O-- or --NH--; Ar is unsubstituted arylene; n is 0-10 and m is 1 or 2; wherein when X is O or NH, n is at least 1. A process for preparing the composition suspensions is also presented. The coating composition is useful in coatings, inks, overprint, varnish and surface treatment applications.

Abstract: A novel compound having the formula: ##STR1## wherein R is hydrogen or an alkyl group containing 1-5 carbon atoms, R.sub.1 and R.sub.2 are hydrogen or a methyl group, X is nonexistent, O or --NH--, Ar is unsubstituted arylene, n is 0-10 and m is 1 or 2, wherein when X is O or --NH--, n is at least 1.The compound of this invention is useful as a monomer which can be polymerized and/or copolymerized by both free radical and cationic polymerization.Polymers and copolymers produced in this invention can be crosslinked and are useful in coatings, inks, overprint, varnish and surface treatment applications.

Abstract: A novel thermosettable composition-of-matter is disclosed. One embodiment of the composition-of-matter includes a polymeric thermosettable ingredient having at least three acetoacetoxy-type functional pendant moieties as well as at least three acid-functional pendant moieties. Another embodiment of the composition-of-matter includes at least two polymeric thermosettable ingredients, one of which includes at least three acid-functional pendant moieties and the other of which includes at least three acetoacetoxy-type functional pendant moieties. The novel composition is characterized in that the acid-functional and acetoacetoxy-type functional pendant moieties crosslinkably-react together, when subjected to elevated-temperature conditions for a predetermined period of time, thereby producing a crosslinked polymeric network. The novel thermosettable composition-of-matter can be used "as is" if either of the polymeric thermosettable components is a "fluid" (i.e., is able to flow) at room temperature.

Abstract: These improved compositions include a polymethylalkylsiloxane hair conditioning These improved compositions include a polymethyMcarrier medium such as a hair shampoo, hair conditioner or aerosol spray composition. The polymethylalkylsiloxane is from 0.1% to about 10% by weight of the total composition and is of the general formula: R.sub.2 (CH.sub.3)Si(OSi(CH.sub.3).sub.2).sub.x (OSiR'CH.sub.3).sub.y OSi(CH.sub.3)R.sub.2, wherein each R is selected from the group consisting or methyl, ethyl and phenyl groups, R' is an alkyl group of from 8 to about 60 carbon atoms where the total number or R' groups present has an average of at least 12 carbon atoms, the values of x and y are such that the ratio of x:y is in the range of from 97:3 to 55:45, the sum of x+y is greater than or equal to about 60 and less than or equal to about 1,333 and the polymethylalkylsiloxane has a melting transition, as measured by a differential scanning calorimeter, between about -25.degree. C. to +27.degree. C.

Abstract: A novel thermosettable composition-of-matter is disclosed. One embodiment of the composition-of-matter includes a polymeric thermosettable ingredient having at least three acetoacetoxy-type functional pendant moieties as well as at least three acid-functional pendant moieties. Another embodiment of the composition-of-matter includes at least two polymeric thermosettable ingredients, one of which includes at least three acid-functional pendant moieties and the other of which includes at least three acetoacetoxy-type functional pendant moieties. The novel composition is characterized in that the acid-functional and acetoacetoxy-type functional pendant moieties crosslinkably-react together, when subjected to elevated-temperature conditions for a predetermined period of time, thereby producing a crosslinked polymeric network. The novel thermosettable composition-of-matter can be used "as is" if either of the polymeric thermosettable components is a "fluid" (i.e., is able to flow) at room temperature.

Abstract: This invention relates to compatible blends of liquid crystal main chain polymer and liquid crystal side polymers having the same or similar mesogenic groups.

Abstract: Disclosed are emulsion polish compositions comprising a copolymeric siloxane selected from the group consisting of a poly(dimethyl)-co-poly(methylalkyl) siloxane polymer, a poly(dimethyl)-co-poly(methyl, oxygen-containing) siloxane polymer, and combinations thereof. The poly(dimethyl)-co-poly(methylalkyl) siloxane copolymer has the formula ##STR1## wherein "A" is an alkyl radical having 10-20 carbon atoms, and wherein "w" is 70-91 mole percent and "x" is 9-30 mole percent. The poly(dimethyl)-co-poly(methyl, oxygen-containing) siloxane copolymer has the formula ##STR2## wherein "B" is (CH.sub.2).sub.i (L)(CH.sub.2 CH.sub.2 O).sub.n R, wherein "i" is an integer from 3 to 10 inclusive, wherein "L" is either --O-- or --COO--, wherein "n" is either zero or an integer from 1 to 3 inclusive, wherein "R" is --H, --CH.sub.3, or --C.sub.2 H.sub.5, and wherein "y" is 62-92 mole percent and "z" is 8-38 mole percent.

Abstract: This invention relates to compatible blends of liquid crystal main chain polymers and liquid crystal side chain polymers having the same or similar mesogenic groups.

Abstract: Linear, melt processable, crosslinkable, thermotropic wholly aromatic ("liquid crystal") polyesters are prepared by polymerizing difunctional stilbene or tolan derivatives as comonomers with non-ethylenically and non-acetylenically unsaturated aromatic diols, dicarboxylic acids, hydroxy acids or reactive derivatives thereof. Shaped structures made from these polyesters are crosslinked using electron-poor monomers, such as maleic anhydride.

Abstract: This invention provides 2-aminobenzothiazole-6-carbonyl chloride hydrochloride, which can be condensed under polymerization conditions to form a novel benzothiazole-polyamide polymer consisting of a recurring monomeric unit corresponding to the formula: ##STR1##

Abstract: A novel polyester is provided which is capable of forming an anisotropic melt and which, subsequent to being formed into shaped articles, is capable of crosslinking to render the article highly heat stable. The polyester preferably consists of approximately 1 to 40 mole percent of 3-allyl-4-oxybenzoyl and/or 3-methylallyl-4-oxybenzoyl moieties copolymerized with oxyaroyl moieties and/or dioxaryl and dicarboxyaryl moieties. The process comprises heating a monomer mixture of allylically substituted hydroxybenzoic acid and aromatic hydroxy acids and/or aromatic diols and diacids to prepare the polyester; melt processing the polyester to form a solid shaped article; and heating to substantially crosslink the allylic groups while substantially retaining the configuration of the solid shaped article.

Abstract: This invention provides 2-aminobenzothiazole-6-carbonyl chloride hydrochloride, which can be condensed under polymerization conditions to form a novel benzothiazole-polyamide polymer consisting of a recurring monomeric unit corresponding to the formula: ##STR1##