Abstract: We provide systems for ionic liquid catalyzed hydrocarbon conversion that comprise a modular reactor comprising a plurality of mixer modules. The mixer modules may be arranged in series. One or more feed modules are disposed between the mixer modules. Such systems may be used for ionic liquid catalyzed alkylation reactions. Processes for ionic liquid catalyzed hydrocarbon conversion are also disclosed.

Abstract: A process is provided for preparing a spent noble metal fixed-bed catalyst for precious metals recovery, comprising: a) adding the catalyst to a caustic solution to wash the spent catalyst and to make a wash slurry having an alkaline pH, wherein the spent catalyst has been in contact with chloroaluminate ionic liquid catalyst, and wherein the spent catalyst comprises from 5 to 35 wt % chloride; and b) filtering the wash slurry and collecting: i) a filter cake having from at least 70 wt % of the chloride in the spent catalyst removed and having the noble metals retained, and ii) a wash filtrate. Also provided is a filter cake comprising a washed consolidated cake having 40 to 75 wt % solids, a cake moisture content from 25 to less than 60 wt %, 0.1 to 1.5 wt % total noble metals, and a residual chloride content of from zero to less than 4 wt %.

Abstract: Systems and apparatus for ionic liquid catalyzed hydrocarbon conversion, such as alkylation, using vaporization to remove reaction heat from an ionic liquid reactor and to provide mixing therein, wherein hydrocarbon vapors are withdrawn from the ionic liquid reactor and the withdrawn hydrocarbon vapor is recovered by a hydrocarbon vapor recovery unit in fluid communication with the ionic liquid reactor for recycling condensed hydrocarbons to the ionic liquid reactor. Processes for ionic liquid catalyzed alkylation are also disclosed.

Abstract: Processes for shutting down a regeneration reactor and for removing spent solid from the regeneration reactor may comprise shutting off a feed comprising an ionic liquid to the regeneration reactor, cooling the regeneration reactor, removing at least a portion of the ionic liquid from the regeneration reactor, purging the regeneration reactor with N2 gas, introducing water into the regeneration reactor to form an acidic liquid in the regeneration reactor, and dumping the acidic liquid and the spent solid from the regeneration reactor. The acidic liquid may be neutralized with a basic liquid to provide a neutralized liquid. The spent solid may be separated from the neutralized liquid. In an embodiment, noble metal(s) may be recovered from the spent solid.

Abstract: We provide an apparatus for performing a hydrocarbon conversion or for handling of an output of the hydrocarbon conversion, comprising: a bare metal alloy, wherein the bare metal alloy comprises: from 15.1 to 49 wt % nickel, from 2.3 to 10 wt % molybdenum, from 0.00 to 2.95 wt % copper, from 5 to 25 wt % chromium, and from 20 to 59 wt % iron; wherein the bare metal alloy exhibits a corrosion rate less than 0.07 mm/year when performing the hydrocarbon conversion or handling the output of the hydrocarbon conversion; and wherein the hydrocarbon conversion is performed using an acidic ionic liquid. We also provide a process for using the apparatus.

Abstract: Provided herein are processes for ethylene oligomerization in the presence of an ionic liquid catalyst and a co-catalyst to produce a hydrocarbon product comprising C10-C55 oligomers.

Abstract: A process is provided for preparing a spent noble metal fixed-bed catalyst for precious metals recovery, comprising: a) adding the catalyst to a caustic solution to wash the spent catalyst and to make a wash slurry having an alkaline pH, wherein the spent catalyst has been in contact with chloroaluminate ionic liquid catalyst, and wherein the spent catalyst comprises from 5 to 35 wt % chloride; and b) filtering the wash slurry and collecting: i) a filter cake having from at least 70 wt % of the chloride in the spent catalyst removed and having the noble metals retained, and ii) a wash filtrate. Also provided is a filter cake comprising a washed consolidated cake having 40 to 75 wt % solids, a cake moisture content from 25 to less than 60 wt %, 0.1 to 1.5 wt % total noble metals, and a residual chloride content of from zero to less than 4 wt %.

Abstract: Systems and apparatus for ionic liquid catalyzed hydrocarbon conversion, such as alkylation, using vaporization to remove reaction heat from an ionic liquid reactor and to provide mixing therein, wherein hydrocarbon vapors are withdrawn from the ionic liquid reactor and the withdrawn hydrocarbon vapor is recovered by a hydrocarbon vapor recovery unit in fluid communication with the ionic liquid reactor for recycling condensed hydrocarbons to the ionic liquid reactor. Processes for ionic liquid catalyzed alkylation are also disclosed.

Abstract: Systems and apparatus for ionic liquid catalyzed hydrocarbon conversion, such as alkylation, using vaporization to remove reaction heat from an ionic liquid reactor and to provide mixing therein, wherein hydrocarbon vapors are withdrawn from the ionic liquid reactor and the withdrawn hydrocarbon vapor is recovered by a hydrocarbon vapor recovery unit in fluid communication with the ionic liquid reactor for recycling condensed hydrocarbons to the ionic liquid reactor. Processes for ionic liquid catalyzed alkylation are also disclosed.

Abstract: Systems for ionic liquid catalyzed hydrocarbon conversion comprise a reactor vessel, a mixing device in fluid communication with the reactor vessel, and at least one circulation loop in fluid communication with the reactor vessel and the mixing device. The mixing device may comprise an upper venturi, at least one feed injection component, and a lower venturi. Such systems may be used for ionic liquid catalyzed alkylation reactions. Processes for ionic liquid catalyzed hydrocarbon conversion are also disclosed.

Abstract: This application provides a metallurgical extraction technique, comprising: a) re-pulping a feed filter cake to make a filter cake slurry; b) grinding the filter cake slurry; c) leaching the ground filter cake slurry in a hot alkaline cyanide solution to provide dissolved platinum group metals; d) liquid-solid separating of the dissolved platinum group metals; and e) recovering the dissolved platinum group metals by cementing the dissolved platinum group metals with a precipitating metal comprising an aluminum or a zinc; wherein the feed filter cake has the platinum group metals at a total amount from 0.1 to 1.5 wt % and a halide anion content from zero to less than 4 wt %. This application provides a process for platinum group metal recovery, comprising: converting a catalyst which was in contact with a water reactive ionic liquid catalyst into a non-water reactive filter cake and extracting the platinum group metals.

Abstract: A process is provided for preparing a spent noble metal fixed-bed catalyst for precious metals recovery, comprising: a) adding the catalyst to a caustic solution to wash the spent catalyst and to make a wash slurry having an alkaline pH, wherein the spent catalyst has been in contact with chloroaluminate ionic liquid catalyst, and wherein the spent catalyst comprises from 5 to 35 wt % chloride; and b) filtering the wash slurry and collecting: i) a filter cake having from at least 70 wt % of the chloride in the spent catalyst removed and having the noble metals retained, and ii) a wash filtrate. Also provided is a filter cake comprising a washed consolidated cake having 40 to 75 wt % solids, a cake moisture content from 25 to less than 60 wt %, 0.1 to 1.5 wt % total noble metals, and a residual chloride content of from zero to less than 4 wt %.

Abstract: We provide processes, and process units for practicing the processes, comprising a. regenerating a used catalyst comprising an ionic liquid catalyst and a chloride, from an alkylation reactor, in a hydrogenation reactor to produce a regenerated catalyst effluent; b. separating at least a portion of the regenerated catalyst effluent into a gas fraction comprising a hydrogen gas and into a light hydrocarbon fraction comprising a hydrogen chloride; c. recycling at least a part of the gas fraction comprising the hydrogen gas to the hydrogenation reactor; and d. recovering at least an amount of the light hydrocarbon fraction comprising the hydrogen chloride and recycling the at least the amount of the light hydrocarbon fraction to the alkylation reactor. The alkylation process units comprise a hydrogenation reactor, a fractionation unit, and connections for transmitting the gas fraction to the hydrogenation reactor and for transmitting the light hydrocarbon fraction to the alkylation reactor.

Abstract: We provide alkylation process units, one comprising: a) a hydrogenation reactor that produces a regenerated catalyst effluent; b) a fractionation unit that separates the effluent into gas and light hydrocarbon; c) a connection between the fractionation unit for transmitting the gas to the hydrogenation reactor; and d) a connection between the fractionation unit and an alkylation reactor to transmit the light hydrocarbon to the alkylation reactor.

Abstract: We provide an apparatus for performing a hydrocarbon conversion or for handling of an output of the hydrocarbon conversion, comprising: a bare metal alloy, wherein the bare metal alloy comprises: from 15.1 to 49 wt % nickel, from 2.3 to 10 wt % molybdenum, from 0.00 to 2.95 wt % copper, and 20 to 59 wt % iron; wherein the bare metal alloy exhibits a corrosion rate less than 0.07 mm/year when performing the hydrocarbon conversion or handling the output of the hydrocarbon conversion; and wherein the hydrocarbon conversion is performed using an acidic ionic liquid. We also provide a process for using the apparatus.

Abstract: We provide an alkylation process, comprising: separating and recycling a hydrogen gas and a hydrogen chloride from an offgas of a hydrogenation reactor; wherein the hydrogen gas is recycled to the hydrogenation reactor; and wherein the hydrogen chloride is recycled to an alkylation reactor. We also provide an alkylation process unit for performing this process.

Abstract: The present invention is directed to a hydroprocessing catalyst containing at least one catalyst support, one or more metals, optionally one or more molecular sieves, optionally one or more promoters, wherein deposition of at least one of the metals is achieved in the presence of a modifying agent.

Abstract: We provide an alkylation process, comprising: separating and recycling a hydrogen gas and a hydrogen chloride from an offgas of a hydrogenation reactor; wherein the hydrogen gas is recycled to the hydrogenation reactor; and wherein the hydrogen chloride is recycled to an alkylation reactor. We also provide an alkylation process unit for performing this process.

Abstract: Systems and apparatus for ionic liquid catalyzed hydrocarbon conversion may comprise a modular reactor comprising a plurality of mixer modules. The mixer modules may be arranged in series. One or more feed modules may be disposed between the mixer modules. Such systems may be used for ionic liquid catalyzed alkylation reactions. Processes for ionic liquid catalyzed hydrocarbon conversion are also disclosed.

Abstract: Systems for ionic liquid catalyzed hydrocarbon conversion comprise a reactor vessel, a mixing device in fluid communication with the reactor vessel, and at least one circulation loop in fluid communication with the reactor vessel and the mixing device. The mixing device may comprise an upper venturi, at least one feed injection component, and a lower venturi. Such systems may be used for ionic liquid catalyzed alkylation reactions. Processes for ionic liquid catalyzed hydrocarbon conversion are also disclosed.