Patents by Inventor Hyo Shu

Hyo Shu has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Publication number: 20120214095
    Abstract: An image forming apparatus including an image forming device forming a toner image on a recording material, and a fixing device including an endless fixing belt feeding the recording material at a speed of 400 to 1,700 mm/sec while heating to fix the toner image thereon. The fixing belt has a rubber layer located on a substrate and having thickness of 400 ?m to 700 ?m, and a fluorine-containing resin layer located on the rubber layer and having thickness of 2 ?m to 20 ?m. The toner includes a release agent including a microcrystalline wax and/or a synthetic ester wax, and a binder resin including a crystalline polyester and an amorphous polyester. The ratio (W/R) of the height (W) of the third falling peak of the crystalline polyester to the height (R) of the maximum rising peak of the amorphous polyester in the FT-IR spectrum of the toner is 0.045 to 0.850.
    Type: Application
    Filed: February 9, 2012
    Publication date: August 23, 2012
    Applicant: RICOH COMPANY, LTD.
    Inventors: Hyo Shu, Hiroki Ishii, Wakana Itoh
  • Publication number: 20120058425
    Abstract: A toner including a release promoter and a binder resin containing crystalline polyester resin and non-crystalline polyester resin, wherein W/R is 0.045 to 0.850 where W denotes height of third bottom peak in infrared absorption spectrum of crystalline polyester resin and R denotes height of maximum top peak in infrared absorption spectrum of non-crystalline polyester resin, each of the infrared absorption spectra being measured by infrared spectroscopic method (KBr method) using Fourier transform infrared spectrometer, wherein the toner is used as toner contained with carrier in premix agent which is developer containing them previously mixed together before shipment, and wherein the premix agent is used in an image forming apparatus containing latent image bearing member, developing device for developing latent image on the latent image bearing member with developer containing toner and carrier, and agent supplying unit configured to supply the premix agent to the developing device.
    Type: Application
    Filed: September 7, 2011
    Publication date: March 8, 2012
    Inventor: Hyo Shu
  • Publication number: 20120014714
    Abstract: An image forming apparatus including a latent electrostatic image bearing member, a latent electrostatic image forming unit, a developing unit, a transfer unit and a fixing unit, wherein the fixing unit includes rotatable heating member heating the recording medium having the unfixed visible image, rotatable pressing member coming into contact with the rotatable heating member to form a nip portion, and an air separation member separating the recording medium from the rotatable heating member by air, the toner including toner base particles each including binder resin and releasing agent, the binder resin including crystalline polyester resin and non-crystalline resin, and ratio of W/R being 0.045 to 0.85, where W denotes peak height in spectrum of the crystalline polyester resin, R denotes peak height in spectrum of the non-crystalline resin, and each of the spectra is measured by total transmission method (KBr method) using Fourier transform infrared (FT-IR) spectrometer.
    Type: Application
    Filed: June 24, 2011
    Publication date: January 19, 2012
    Inventor: Hyo SHU
  • Publication number: 20110268474
    Abstract: A toner including toner particles including a binder resin containing at least one polyester resin comprising an inorganic tin (II) compound and an external additive including a particulate inorganic material having a volume average particle diameter greater than 70 nm and less than 300 nm. The binder resin preferably includes a polyester resin having a weight average molecular weight of from 5,000 to 50,000 and another resin having a weight average molecular weight of from 200,000 to 400,000. A developer including the toner; and a developing device, an image forming apparatus and a process cartridge, which form toner images using the toner are also provided.
    Type: Application
    Filed: July 6, 2011
    Publication date: November 3, 2011
    Inventors: Hyo SHU, Mitsuo Aoki, Minoru Masuda, Kumi Hasegawa
  • Patent number: 8034523
    Abstract: A full color toner containing a binder resin, a release agent and a colorant is provided, wherein the binder resin contains a polyester resin containing a hybrid resin containing one or more vinyl group polymer units and one or more polyester units, and wherein the content A of the hybrid resin and the content B of the release agent satisfy the following relationship: B/2?A?3B.
    Type: Grant
    Filed: August 3, 2005
    Date of Patent: October 11, 2011
    Assignee: Ricoh Company, Ltd.
    Inventors: Kumi Hasegawa, Mitsuo Aoki, Minoru Masuda, Hyo Shu
  • Publication number: 20110223532
    Abstract: A toner, comprising a colorant, a crystalline polyester resin, and an amorphous polyester resin, in which the crystalline polyester resin satisfies the following relations: 60?(T2-cp)<80 (T2-cs2)?(T2-cp)<10 (T2-cp)?(T2-cs1)<10 wherein (T2-cp) (° C.) represents an endothermic peak temperature, (T2-cs1) (° C.) represents a first endothermic shoulder temperature, and (T2-cs2) (° C.) represents a second endothermic shoulder temperature, each determined from a second heating in a differential scanning calorimetry.
    Type: Application
    Filed: February 11, 2011
    Publication date: September 15, 2011
    Inventors: Tsuyoshi SUGIMOTO, Fumihiro Sasaki, Hiroshi Yamashita, Satoshi Ogawa, Junichi Awamura, Hyo Shu, Tomomi Suzuki, Teruki Kusahara, Ryota Inoue, Daisuke Inoue
  • Patent number: 8012659
    Abstract: An image forming apparatus including a fixing device to fix a toner image on a recording medium including a heat roller and an oil applicator to apply a silicone oil to the heat roller, having a system speed of from 500 to 1700 mm/sec, and using a toner including a binder resin including a crystalline polyester resin and an amorphous polyester resin; a fatty acid amide compound; and a colorant, wherein a ratio (W/R) of a height (W) of a peak at a wavenumber of 1638 cm?1, specific to the fatty acid amide compound, to a height (R) of a peak at a wavenumber of 829 cm?1, specific to the amorphous polyester resin, is from 0.010 to 0.040 in an absorption spectrum obtained by an ATR method (total reflectance method) using a Fourier transform infrared (FT-IR) spectrophotometer.
    Type: Grant
    Filed: December 14, 2007
    Date of Patent: September 6, 2011
    Assignee: Ricoh Company Limited
    Inventors: Hyo Shu, Minoru Masuda, Yasuaki Iwamoto, Yasutada Shitara
  • Patent number: 8007976
    Abstract: A toner is provided that comprises a colorant and a binder resin, wherein the binder resin comprises a polyester resin that is prepared by a polycondensation reaction in the presence of at least a titanium-containing catalyst expressed by General Formula (II) or (II), the toner has a volume average particle diameter of 2.0 ?m to 10.0 ?m and a ratio Dv/Dn within a range of 1.00 to 1.
    Type: Grant
    Filed: November 1, 2006
    Date of Patent: August 30, 2011
    Assignee: Ricoh Company. Ltd.
    Inventors: Hideki Sugiura, Hiroyuki Fushimi, Osamu Uchinokura, Takahiro Honda, Masami Tomita, Hyo Shu, Ken Umehara
  • Patent number: 7985518
    Abstract: An image forming apparatus of the present invention includes a latent electrostatic image bearing member, a latent electrostatic image forming unit configured to form a latent electrostatic image on the latent electrostatic image bearing member, at least three developing units each configured to develop the latent electrostatic image using a toner to form a visible image, a transferring unit configured to transfer the visible image on a recording medium, and an image fixing unit configured to the transferred image on the recording medium, in which the developing units respectively include any one of a yellow toner, a magenta toner, and a cyan toner, the magenta toner includes C.I. pigment red 269, and the yellow toner includes C.I pigment yellow 180 or C.I pigment yellow 155.
    Type: Grant
    Filed: November 3, 2008
    Date of Patent: July 26, 2011
    Assignee: Ricoh Company, Ltd.
    Inventors: Hyo Shu, Mitsuo Aoki, Minoru Masuda, Kumi Hasegawa
  • Publication number: 20110165508
    Abstract: A toner containing at least a binder resin, releasing agent, and colorant, wherein the binder resin contains polyester resin (A), polyester resin (B), and polyester resin (C), which is prepared by condensation-polymerizing (i) an alcohol component containing an alkylene oxide adduct of bisphenol compound and (ii) a carboxylic acid component; at least one of the polyester resin (A) and polyester resin (B) is a polyester resin prepared by condensation-polymerizing (i) the alcohol component substantially composed of only aliphatic alcohol and containing 1,2-propanediol in an amount of 65 mole % or more of a divalent alcohol component and (ii) the carboxylic acid component; and a softening point Tm(A) of the polyester resin (A) is 10 C or more higher than Tm(B) of the polyester resin (B), and the absolute difference between Tm(C) of the polyester resin (C) and the Tm(B) is 5° C. or less.
    Type: Application
    Filed: September 2, 2009
    Publication date: July 7, 2011
    Inventors: Shinya Nakayama, Hisashi Nakajima, Saori Yamada, Mitsuo Aoki, Hyo Shu, Hiroyuki Kishida
  • Publication number: 20110129773
    Abstract: A toner including a binder resin comprising a modified polyester having an ester bond and a chemical bond other than the ester bond, and a crystalline polyester; and a release agent comprising a microcrystalline wax comprising a hydrocarbon having 20 to 80 carbon atoms which comprises 55 to 70% by weight of a linear hydrocarbon. The microcrystalline wax has an acid value of from 0.1 to 20 mgKOH/g and a melting point of from 65 to 90° C. The melting point is a temperature at which a local maximum endothermic peak is observed in a differential thermal curve measured by differential scanning calorimetry (DSC). The release agent is dispersed in the toner with a dispersion diameter of from 0.06 to 1.50 ?m.
    Type: Application
    Filed: November 3, 2010
    Publication date: June 2, 2011
    Inventors: Hyo SHU, Fumihiro Sasaki, Hiroshi Yamashita, Masaki Watanabe, Junichi Awamura, Tsuyoshi Sugimoto, Teruki Kusahara, Satoshi Ogawa, Ryota Inoue, Daisuke Inoue
  • Publication number: 20110091245
    Abstract: An image forming method including electrostatic image forming step, developing step, transferring step, fixing step and oil application step for applying an oil to a fixing member, wherein the toner includes a binder resin, a colorant and a wax, and the relationship (A2/A1)×100<200 is satisfied, wherein A1 represents the area of the oil dropped on a pellet of the toner measured 30 seconds after dropping the oil, and A2 represents the area of the dropped oil measured 24 hours after dropping the oil. Alternatively, the relationships (X1?X2)<0.5 atomic percent, X1>1.0 atomic percent, and X2>1.0 atomic percent, are satisfied, wherein X1 and X2 represent amounts of Si atoms of the silicone oil measured by subjecting the toner image to X-ray photoelectron spectroscopy at times 5 minutes and 24 hours, respectively, after fixing the toner image.
    Type: Application
    Filed: December 28, 2010
    Publication date: April 21, 2011
    Inventors: Yasutada SHITARA, Minoru Masuda, Yasuaki Iwamoto, Hyo Shu
  • Patent number: 7901861
    Abstract: An image forming method including electrostatic image forming step, developing step, transferring step, fixing step and oil application step for applying an oil to a fixing member, wherein the toner includes a binder resin, a colorant and a wax, and the relationship (A2/A1)×100<200 is satisfied, wherein A1 represents the area of the oil dropped on a pellet of the toner measured 30 seconds after dropping the oil, and A2 represents the area of the dropped oil measured 24 hours after dropping the oil. Alternatively, the relationships (X1?X2)<0.5 atomic percent, X1>1.0 atomic percent, and X2>1.0 atomic percent, are satisfied, wherein X1 and X2 represent amounts of Si atoms of the silicone oil measured by subjecting the toner image to X-ray photoelectron spectroscopy at times 5 minutes and 24 hours, respectively, after fixing the toner image.
    Type: Grant
    Filed: December 4, 2007
    Date of Patent: March 8, 2011
    Assignee: Ricoh Company Limited
    Inventors: Yasutada Shitara, Minoru Masuda, Yasuaki Iwamoto, Hyo Shu
  • Publication number: 20110033794
    Abstract: A toner containing a binder, a colorant, and a wax having a molecular chain consisting of C—H bond and C—C bond, wherein the mass reduction of the wax at 165° C. is 10% by mass or less, and the total amount of the wax in the toner measured by a DSC method is 1% by mass to 8% by mass, wherein a ratio, Sbet/SF, of a BET specific surface area (Sbet) of the toner to an average circularity (SF) of the toner is 1.0 m2/g or more to less than 3.6 m2/g, wherein the toner is obtained through a process which contains at least emulsifying or dispersing a toner material liquid in an aqueous medium containing a surfactant, and wherein the toner material liquid is a liquid containing toner-forming materials which contains at least the binder, the colorant and the wax.
    Type: Application
    Filed: August 2, 2010
    Publication date: February 10, 2011
    Inventors: Naohiro WATANABE, Naohito SHIMOTA, Yasuaki IWAMOTO, Masana SHIBA, Satoshi KOJIMA, Masaki WATANABE, Tsuneyasu NAGATOMO, Hyo SHU
  • Publication number: 20110002719
    Abstract: An image forming method producing images at a speed of from 500 to 1,700 mm/sec, including charging an image bearer; irradiating the charged image bearer to form an electrostatic latent image thereon; developing the electrostatic latent image with a developer comprising a toner, to form a toner image on the image bearer; transferring the toner image onto a recording medium; cleaning the toner remaining on the image bearer after the transferring step; and fixing the toner image on the recording medium, wherein the binder resin includes a crystalline polyester resin and an amorphous resin, wherein a peak ratio (W/R) of a specific peak height (W) of the crystalline polyester resin to a specific peak height (R) of the amorphous resin is from 0.050 to 0.
    Type: Application
    Filed: September 13, 2010
    Publication date: January 6, 2011
    Inventors: Hyo Shu, Masami Tomita, Ken Umehara
  • Publication number: 20100136471
    Abstract: A toner, wherein a binder resin contains a polyester resin (A) produced by polycondensing an alcohol component with a carboxylic acid component which contains a rosin compound in an amount of 5% by mass or more of the total amount by mass of the alcohol component and the carboxylic acid component, and a polyester resin (B) produced by polycondensing an alcohol component containing an alkylene oxide adduct of bisphenol A represented by General Formula (1) given below with a carboxylic acid component, and wherein the toner contains abietic acid in an amount of 0.01% by mass to 1% by mass: where R1 and R2 each represent C2-C4 alkylene; R3 and R4 are each any one of a hydrogen atom, C1-C6 straight-chain alkyl, and C1-C6 branched-chain alkyl; and x and y each represent a positive integer and the sum of x and y is 1 to 16.
    Type: Application
    Filed: November 24, 2009
    Publication date: June 3, 2010
    Inventors: Saori YAMADA, Shinya Nakayama, Hisashi Nakajima, Mitsuo Aoki, Hyo Shu, Hiroyuki Kishida
  • Publication number: 20100067958
    Abstract: An image forming method including forming an electrostatic latent image on a photoreceptor; developing the latent image with a developer including a toner using a center-feed developing device to form a toner image; transferring the toner image onto a receiving material; and fixing the toner image using a fixing member coated with silicone oil. The toner includes at least a binder resin; a colorant; and a quaternary ammonium salt having a specific formula, wherein when the toner is dispersed in ethanol using ultrasonic waves, the dispersion has a turbidity of from 0.4 to 1.0 when the turbidity is determined using a haze meter. An image forming apparatus including a photoreceptor; a center-feed developing device using a developer including the toner; a transferring device; a fixing device using a fixing member coated with silicone oil; and a cleaner for the photoreceptor.
    Type: Application
    Filed: August 24, 2009
    Publication date: March 18, 2010
    Inventors: Hiroyuki KISHIDA, Masahide INOUE, Hyo SHU, Yasutada SHITARA
  • Publication number: 20100068644
    Abstract: The present invention provides a toner which contains at least a binder resin, and a colorant, wherein the binder resin contains a polyester resin (A) obtained by polycondensation of an alcohol component with a carboxylic acid component containing one of a purified rosin and a modified rosin, and a polyester resin (B) obtained by polycondensation of a carboxylic acid with an alcohol component containing a specific alkylene oxide adduct of bisphenol A, and wherein when the carboxylic acid component containing a purified rosin is used in the carboxylic acid component for the polyester resin (A), a mass ratio [(B)/(A)] of the polyester resin (B) to the polyester resin (A) is 2/8 to 6/4.
    Type: Application
    Filed: September 10, 2009
    Publication date: March 18, 2010
    Inventors: Hisashi Nakajima, Shinya Nakayama, Saori Yamada, Mitsuo Aoki, Hiroyuki Kishida, Hyo Shu, Yasutada Shitara, Masahide Inoue
  • Publication number: 20090155706
    Abstract: An image forming apparatus including a fixing device to fix a toner image on a recording medium including a heat roller and an oil applicator to apply a silicone oil to the heat roller, having a system speed of from 500 to 1700 mm/sec, and using a toner including a binder resin including a crystalline polyester resin and an amorphous polyester resin; a fatty acid amide compound; and a colorant, wherein a ratio (W/R) of a height (W) of a peak at a wavenumber of 1638 cm?1, specific to the fatty acid amide compound, to a height (R) of a peak at a wavenumber of 829 cm?1, specific to the amorphous polyester resin, is from 0.010 to 0.040 in an absorption spectrum obtained by an ATR method (total reflectance method) using a Fourier transform infrared (FT-IR) spectrophotometer.
    Type: Application
    Filed: December 14, 2007
    Publication date: June 18, 2009
    Inventors: Hyo Shu, Minoru Masuda, Yasuaki Iwamoto, Yasutada Shitara
  • Publication number: 20090142677
    Abstract: An image forming method including electrostatic image forming step, developing step, transferring step, fixing step and oil application step for applying an oil to a fixing member, wherein the toner includes a binder resin, a colorant and a wax, and the relationship (A2/A1)×100<200 is satisfied, wherein A1 represents the area of the oil dropped on a pellet of the toner measured 30 seconds after dropping the oil, and A2 represents the area of the dropped oil measured 24 hours after dropping the oil. Alternatively, the relationships (X1?X2)<0.5 atomic percent, X1>1.0 atomic percent, and X2>1.0 atomic percent, are satisfied, wherein X1 and X2 represent amounts of Si atoms of the silicone oil measured by subjecting the toner image to X-ray photoelectron spectroscopy at times 5 minutes and 24 hours, respectively, after fixing the toner image.
    Type: Application
    Filed: December 4, 2007
    Publication date: June 4, 2009
    Inventors: Yasutada SHITARA, Minoru MASUDA, Yasuaki IWAMOTO, Hyo SHU