Abstract: The present invention relates to a sulfide-based solid electrolyte for an all-solid lithium secondary battery, and to a method for preparing the sulfide-based solid electrolyte. The present invention has an effect of providing a sulfide-based solid electrolyte that has excellent stability with respect to lithium metal and has excellent ion conductivity, while having high crystallinity. The present invention has an effect of providing a method for preparing a sulfide-based solid electrolyte that has excellent stability with respect to lithium metal and has excellent ion conductivity, while having high crystallinity even when heat-treated at a low temperature.

Abstract: A crystallized glass with negative coefficient of thermal expansion includes 38 wt % to 64 wt % of silica (SiO2); 30 wt % to 40 wt % of alumina (Al2O3); and 5 wt % to 12 wt % of lithium oxide (Li2O) as a basic component, and further includes more than one component selected from the group consisting of 0.5 wt % to 15 wt % of zirconia (ZrO2), 0.5 wt % to 6.5 wt % of titanium dioxide (TiO2), 0.5 wt % to 4 wt % of phosphorus pentoxide (P2O5), 2 wt % to 5 wt % of magnesium oxide (MgO), and 0 wt % to 5 wt % of magnesium fluoride (MgF2) in addition to the basic components. The crystallized glass may have a high negative coefficient of thermal expansion so that it has an advantage that it can be used as a thermal expansion compensation material according to the temperatures of all kinds of glasses and similar products thereof.

Abstract: A crystallized glass with negative coefficient of thermal expansion includes 38 wt % to 64 wt % of silica (SiO2); 30 wt % to 40 wt % of alumina (Al2O3); and 5 wt % to 12 wt % of lithium oxide (Li2O) as a basic component, and further includes more than one component selected from the group consisting of 0.5 wt % to 15 wt % of zirconia (ZrO2), 0.5 wt % to 6.5 wt % of titanium dioxide (TiO2), 0.5 wt % to 4 wt % of phosphorus pentoxide (P2O5), 2 wt % to 5 wt % of magnesium oxide (MgO), and 0 wt % to 5 wt % of magnesium fluoride (MgF2) in addition to the basic components. The crystallized glass may have a high negative coefficient of thermal expansion so that it has an advantage that it can be used as a thermal expansion compensation material according to the temperatures of all kinds of glasses and similar products thereof.

Abstract: Nitrogen trifluoride is produced with a high yield by the method comprising forming a fast stream of micro droplets of a fused ammonium fluoride salt by rapidly ejecting the fused ammonium fluoride salt into a reactor through a nozzle while circulating the fused ammonium fluoride salt in the reactor from a lower portion to an upper portion; and contacting micro droplets of the fused ammonium fluoride salt with fluorine gas sucked in the reactor through a suction pipe for fluorine by a negative pressure formed around the nozzle due to an ejection of the fused ammonium fluoride salt, whereby excessive generation and regional accumulation of the heat of reaction are prevented, reducing the reaction temperature by 10˜30° C. compared with those of the existing methods, and a side reaction occurs only to a slight extent according to the lowered reaction temperature.

Abstract: Nitrogen trifluoride is produced with a high yield by the method comprising forming a fast stream of micro droplets of a fused ammonium fluoride salt by rapidly ejecting the fused ammonium fluoride salt into a reactor through a nozzle while circulating the fused ammonium fluoride salt in the reactor from a lower portion to an upper portion; and contacting micro droplets of the fused ammonium fluoride salt with fluorine gas sucked in the reactor through a suction pipe for fluorine by a negative pressure formed around the nozzle due to an ejection of the fused ammonium fluoride salt, whereby excessive generation and regional accumulation of the heat of reaction are prevented, reducing the reaction temperature by 10˜30° C. compared with those of the existing methods, and a side reaction occurs only to a slight extent according to the lowered reaction temperature.