Publication number: 20120273091
Abstract: A method of providing sulfidation corrosion resistance and corrosion induced fouling resistance to a heat transfer component surface includes providing a silicon containing steel composition including an alloy and a Si-partitioned non-metallic film formed on a surface of the alloy. The alloy is formed from the composition ?, ?, and t, in which ? is a metal selected from the group consisting of Fe, Ni, Co, and mixtures thereof, ? is Si, and t is at least one alloying element selected from the group consisting of Cr, Al, Mn, Ti, Zr, Hf, V, Nb, Ta, Mo, W, Sc, La, Y, Ce, Ru, Rh, Ir, Pd, Pt, Cu, Ag, Au, Ga, Ge, As, In, Sn, Sb, Pb, B, C, N, P, O, S and mixtures thereof. The Si-partitioned non-metallic film comprises at least one of sulfide, oxysulfide and mixtures thereof.
Type:
Application
Filed:
May 15, 2012
Publication date:
November 1, 2012
Applicant:
EXXONMOBIL RESEARCH AND ENGINEERING COMPANY
Inventors:
ChangMin Chun, Mark A. Greaney, Thomas Bruno, Ian A. Cody, Trikur A. Ramanarayanan, LeRoy R. Clavenna
Patent number: 8211548
Abstract: A heat transfer component that is resistant to both corrosion and fouling is disclosed having a heat exchange surface formed from a silicon containing steel composition including an alloy and a non-metallic film formed on a surface of the alloy. The alloy is formed from the composition ?, ?, and ?, in which ? is a metal selected from the group consisting of Fe, Ni, Co, and mixtures thereof, ? is Si, and ? is at least one alloying element selected from the group consisting of Cr, Al, Mn, Ti, Zr, Hf, V, Nb, Ta, Mo, W, Sc, La, Y, Ce, Ru, Rh, Ir, Pd, Pt, Cu, Ag, Au, Ga, Ge, As, In, Sn, Sb, Pb, B, C, N, P, O, S and mixtures thereof. The non-metallic film comprises sulfide, oxide, carbide, nitride, oxysulfide, oxycarbide, oxynitride and mixtures thereof. The surface roughness of the heat transfer component is less than 40 micro inches.
Type:
Grant
Filed:
December 20, 2006
Date of Patent:
July 3, 2012
Assignee:
ExxonMobil Research & Engineering Co.
Inventors:
ChangMin Chun, Mark A. Greaney, Thomas Bruno, Ian A. Cody, Trikur A. Ramanarayanan, LeRoy R. Clavenna