Abstract: A method for ceramming a glass article to a glass-ceramic includes placing a glass article into a heating apparatus, and heating the glass article to a first hold temperature at a first predetermined heating rate. The glass article is held at the first hold temperature for a first predetermined duration. The viscosity of the glass article is maintained within log viscosity ±1.0 poise during the first predetermined duration. The glass article is then heated from the first hold temperature to a second hold temperature at a second predetermined heating rate. The glass article is held at the second hold temperature for a second duration. A density of the glass article is monitored from the heating of the glass article from the first hold temperature through the second duration, and the second duration is ended when an absolute value of a density rate of change of the glass article is less than or equal to 0.10 (g/cm3)/min.

Abstract: A glass or glass-ceramic carrier substrate, the substrate having undergone at least one complete cycle of a semiconductor fabrication process and having also undergone a reclamation process following the end of the semiconductor fabrication process; the glass or glass-ceramic carrier substrate comprising at least one of the following properties: (i) a coefficient of thermal expansion of less than 13 ppm/° C.; (ii) a Young's Modulus of 70 GPa to 150 GPa; (iii) an IR transmission of greater than 80% at a wavelength of 1064 nm; (iv) a UV transmission of greater than 20% at a wavelength of 255 nm to 360 nm; (v) a thickness tolerance within the same range as the thickness tolerance of the carrier substrate before undergoing at least one complete cycle of the semiconductor fabrication process; (vi) a total thickness variation of less than 2.5 ?m; (vii) a failure strength of greater than 80 MPa using a 4-point-bending test; (viii) a pre-shape of 50 ?m to 300 ?m.

Abstract: A glass article includes: from 60 mol % to 80 mol % SiO2; from 5 mol % a to 25 mol % Al2O3; from 0.25 mol % to 10 mol % MgO; from 0.25 mol % to 10 mol % Na2O; from 0 mol % to 2 mol % Li2O; from 0 mol % to 9 mol % La2O3; and from 0 mol % to 9 mol % Y2O3. La2O3+Y2O3 is from 2 mol % to 9 mol %. (La2O3+Y2O3)/(R2O+RO) is from 0.1 to 2, R2O being the sum of Na2O, Li2O, and K2O, and RO being the sum of MgO, CaO, SrO, and BaO.

Abstract: Methods of producing a glass article include melting a first glass composition and feeding a second glass composition into the melter. Both glass compositions include the same combination of components but at least one component has a concentration that is different in each. At least three glass articles may be drawn from the melter, including: a first glass article formed from the first glass composition; at least one intermediate glass article composed of neither the first nor the second glass composition; and a final glass article not composed of the first glass composition. The concentration of the at least one component in the intermediate glass article may be between the concentration in the first and second glass compositions. The first glass article and final glass article may have differing values for certain properties, and the intermediate glass article may have an intermediate set of values for the same properties.

Abstract: Methods of producing a glass article include melting a first glass composition and feeding a second glass composition into the melter. Both glass compositions include the same combination of components but at least one component has a concentration that is different in each. At least three glass articles may be drawn from the melter, including: a first glass article formed from the first glass composition; at least one intermediate glass article composed of neither the first nor the second glass composition; and a final glass article not composed of the first glass composition. The concentration of the at least one component in the intermediate glass article may be between the concentration in the first and second glass compositions. The first glass article and final glass article may have differing values for certain properties, and the intermediate glass article may have an intermediate set of values for the same properties.

Abstract: Methods of producing a glass article include melting a first glass composition and feeding a second glass composition into the melter. Both glass compositions include the same combination of components but at least one component has a concentration that is different in each. At least three glass articles may be drawn from the melter, including: a first glass article formed from the first glass composition; at least one intermediate glass article composed of neither the first nor the second glass composition; and a final glass article not composed of the first glass composition. The concentration of the at least one component in the intermediate glass article may be between the concentration in the first and second glass compositions. The first glass article and final glass article may have differing values for certain properties, and the intermediate glass article may have an intermediate set of values for the same properties.

Abstract: Lithium-containing polycrystalline ceramic sheets include grains having an average grain size of less than 5 ?m, a relative density greater than 90%, and a thickness of up to 200 ?m. In aspects, the lithium-containing polycrystalline ceramic sheets include an outer edge of the sheet that has no height variations greater than 1 mm from baseline in a perimeter trace. In aspects, the lithium-containing polycrystalline ceramic sheets include microstructural features of an outer edge of the sheet are no greater than about ? the thickness of the sheet. In aspects, the lithium-containing polycrystalline ceramic sheets include an outer edge of the sheet that is enriched in lithium relative to a bulk of the sheet.

Abstract: The disclosure relates to ceramic lithium ion electrolyte membranes and processes for forming them. The ceramic lithium electrolyte membrane may comprise at least one ablative edge. Exemplary processes for forming the ceramic lithium ion electrolyte membranes comprise fabricating a lithium ion electrolyte sheet and cutting at least one edge of the fabricated electrolyte sheet with an ablative laser.

Abstract: Embodiments of the present disclosure pertain to crystallizable glasses and glass-ceramics that exhibit a black color and are opaque. In one or more embodiments, the crystallizable glasses and glass-ceramics include a precursor glass composition that exhibits a liquidus viscosity of greater than about 20 kPa*s. The glass-ceramics exhibit less than about 20 wt % of one or more crystalline phases, which can include a plurality of crystallites in the Fe2O3—TiO2—MgO system and an area fraction of less than about 15%. Exemplary compositions used in the crystallizable glasses and glass-ceramics include, in mol %, SiO2 in the range from about 50 to about 76, Al2O3 in the range from about 4 to about 25, P2O5+B2O3 in the range from about 0 to about 14, R2O in the range from about 2 to about 20, one or more nucleating agents in the range from about 0 to about 5, and RO in the range from about 0 to about 20.

Abstract: A glass-ceramic article that includes an article having a glass-ceramic composition, the composition including: SiO2 from about 45% to about 65%, Al2O3 from about 14% to about 28%, TiO2 from about 2% to about 4%, ZrO2 from about 3% to about 4.5%, MgO from about 4.5% to about 12%, and ZnO from about 0.1 to about 4% (by weight of oxide). The article can include a coefficient of thermal expansion (CTE) of about 20×10?7 K?1 to about 160×10?7 K?1, as measured over a temperature range from 25° C. to 300° C.

Abstract: A glass glass-ceramic composite comprises a substrate comprising an alkali-containing glass bulk, the bulk comprising Al2O3 and SiO2 and alkali, and a glass-ceramic surface layer, the surface layer comprising an alkali-depleted glass ceramic comprising Al2O3 and SiO2 with at least 5% crystalline phase by volume, wherein the alkali-depleted glass ceramic surface layer comprises a mol % Al2O3 of at least 51%. A method of preparing the composite is also disclosed.

Abstract: Embodiments of a glass substrate including an alkali-containing bulk and an alkali-depleted surface layer, including a substantially homogenous composition with at least 51 mol % Al2O3 are disclosed. In some embodiments, the alkali-depleted surface layer includes about 0.5 atomic % alkali or less. The alkali-depleted surface layer can be substantially free of hydrogen and/or crystallites. Methods for forming a glass substrate with a modified surface layer are also provided.

Abstract: A porous silicon composition, a porous alloy composition, or a porous silicon containing cermet composition, as defined herein. A method of making: the porous silicon composition; the porous alloy composition, or the porous silicon containing cermet composition, as defined herein. Also disclosed is an electrode, and an energy storage device incorporating the electrode and at least one of the disclosed compositions, as defined herein.

Abstract: A process for making a glass-ceramic article includes annealing an as-formed glass article formed from a glass-ceramic composition at a first temperature for a duration sufficient to nucleate a plurality of nuclei within a vitreous matrix of the as-formed glass article and forming a post-nucleation glass article. The process also includes annealing the post-nucleation glass article at a second temperature for a duration sufficient to grow crystalline grains within the vitreous matrix of the post-nucleation glass article and forming a glass-ceramic article. The first temperature is less than a glass transition temperature for the glass-ceramic composition and the second temperature is greater than the glass transition temperature for the glass-ceramic composition.

Abstract: A glass or glass-ceramic carrier substrate, the substrate having undergone at least one complete cycle of a semiconductor fabrication process and having also undergone a reclamation process following the end of the semiconductor fabrication process; the glass or glass-ceramic carrier substrate comprising at least one of the following properties: (i) a coefficient of thermal expansion of less than 13 ppm/° C.; (ii) a Young's Modulus of 70 GPa to 150 GPa; (iii) an IR transmission of greater than 80% at a wavelength of 1064 nm; (iv) a UV transmission of greater than 20% at a wavelength of 255 nm to 360 nm; (v) a thickness tolerance within the same range as the thickness tolerance of the carrier substrate before undergoing at least one complete cycle of the semiconductor fabrication process; (vi) a total thickness variation of less than 2.5 ?m; (vii) a failure strength of greater than 80 MPa using a 4-point-bending test; (viii) a pre-shape of 50 ?m to 300 ?m.

Abstract: The disclosure relates to ceramic lithium ion electrolyte membranes and processes for forming them. The ceramic lithium electrolyte membrane may comprise at least one ablative edge. Exemplary processes for forming the ceramic lithium ion electrolyte membranes comprise fabricating a lithium ion electrolyte sheet and cutting at least one edge of the fabricated electrolyte sheet with an ablative laser.

Abstract: The disclosure relates to ceramic lithium ion electrolyte membranes and processes for forming them. The ceramic lithium electrolyte membrane may comprise at least one ablative edge. Exemplary processes for forming the ceramic lithium ion electrolyte membranes comprise fabricating a lithium ion electrolyte sheet and cutting at least one edge of the fabricated electrolyte sheet with an ablative laser.

Abstract: A glass-ceramic article that includes an article having a glass-ceramic composition, the composition including: SiO0 from about 45% to about 65%, Al2O3 from about 14% to about 28%, TiO2 from about 2% to about 4%, ZrO2 from about 3% to about 4.5%, MgO from about 4.5% to about 12%, and ZnO from about 0.1 to about 4% (by weight of oxide). The article can include a coefficient of thermal expansion (CTE) of about 20×10?7K?1 to about 160×10?7K?1, as measured over a temperature range from 25° C. to 300° C.

Abstract: Embodiments of the present disclosure pertain to crystallizable glasses and glass-ceramics that exhibit a black color and are opaque. In one or more embodiments, the crystallizable glasses and glass-ceramics include a precursor glass composition that exhibits a liquidus viscosity of greater than about 20 kPa*s. The glass-ceramics exhibit less than about 20 wt % of one or more crystalline phases, which can include a plurality of crystallites in the Fe2O3—TiO2—MgO system and an area fraction of less than about 15%. Exemplary compositions used in the crystallizable glasses and glass-ceramics include, in mol %, SiO2 in the range from about 50 to about 76, Al2O3 in the range from about 4 to about 25, P2O5+B2O3 in the range from about 0 to about 14, R2O in the range from about 2 to about 20, one or more nucleating agents in the range from about 0 to about 5, and RO in the range from about 0 to about 20.

Abstract: A porous silicon composition, a porous alloy composition, or a porous silicon containing cermet composition, as defined herein. A method of making: the porous silicon composition; the porous alloy composition, or the porous silicon containing cermet composition, as defined herein. Also disclosed is an electrode, and an energy storage device incorporating the electrode and at least one of the disclosed compositions, as defined herein.