Abstract: The invention relates to a permselective membrane (1) for removal of water from water-containing gas mixtures, said permselective membrane (1) being a carbon membrane of a material whose structure is graphite similar and formed by at least one sequence of layers of the material, the layers being arranged in planes, adjacent layers having an average distance between the layers of less than 0.45 nm (4.5 ?), and the sequence of layers being turbostratically disordered. The invention further relates to processes for preparing membrane (1) and to uses of membrane (1) for exchanging water between two gas streams and also for removing water from chemical equilibrium reactions. Assemblies comprising membrane (1) on porous ceramic carriers (2) and apparatuses for separating water from a water-containing gas mixture are also described.

Abstract: The invention relates to a permselective membrane (1) for removal of water from water-containing gas mixtures, said permselective membrane (1) being a carbon membrane of a material whose structure is graphite similar and formed by at least one sequence of layers of the material, the layers being arranged in planes, adjacent layers having an average distance between the layers of less than 0.45 nm (4.5 ?), and the sequence of layers being turbostratically disordered. The invention further relates to processes for preparing membrane (1) and to uses of membrane (1) for exchanging water between two gas streams and also for removing water from chemical equilibrium reactions. Assemblies comprising membrane (1) on porous ceramic carriers (2) and apparatuses for separating water from a water-containing gas mixture are also described.

Abstract: The use of solutions of organic polymers for production of carbon membranes suitable for gas separation, and a process for producing carbon membranes suitable for gas separation, comprising the steps of a) coating a porous substrate with solutions of organic polymers, b) drying the polyester coating on the porous substrate by removing the solvent, and c) pyrolyzing the polyester coating on the porous substrate to form the carbon membrane suitable for gas separation, it being possible to conduct any of steps a) to c) or the sequence of steps a) to c) more than once.

Abstract: A method for producing membranes which contain at least one solid layer on one side of a porous substrate by treating the side of the support, which is to be coated, with a synthetic solution that forms the solid layer. The inventive method is characterized in that the space located behind the side of the porous support, which is not to be coated, is filled with an inert fluid during the production of the solid layer on the porous support, “behind” being from the perspective of the support. The pressure and/or the temperature of the fluid is/are selected such that the synthetic solution is essentially prevented from entering in contact with the side of the porous support, which is not to be coated.

Abstract: A process for the production of a composite membrane, one or more microporous separation layers comprising a zeolite of the MFI type being produced by hydrothermal synthesis on a porous substrate, wherein one or more additives from the group consisting of linear (C1-C4)-alcohols, ammonia, primary, secondary and tertiary amines having in each case (C1-C4)-alkyl radicals, (C1-C4)-aminoalcohols and (C3-C4)-ketones are added to the synthesis solution for the hydrothermal synthesis.

Abstract: A separation module which contains at least one bundle of ceramic capillaries (9), in which, for controlling the material transport and the flow in the separation module, a certain distance is established between the capillaries (9) by joining. The separation module can be used in a variety of ways in the separation of substances by filtration, also in combination with further measures of chemical process engineering.

Abstract: Composite membranes comprising at least one porous substrate layer and at least one microporous separation layer, comprising at least one zeolite of the MFI type, are described, the separation layer being produced by a hydrothermal synthesis in which the molar ratio of silicon to aluminum is greater than 120 and the separation layer contains less than 10% by weight of aluminum in elemental or chemically bound form in a zone of at least 100 nm adjacent to the separation layer.

Abstract: A process for the production of a composite membrane, one or more microporous separation layers comprising a zeolite of the MFI type being produced by hydrothermal synthesis on a porous substrate, wherein one or more additives from the group consisting of linear (C1-C4)-alcohols, ammonia, primary, secondary and tertiary amines having in each case (C1-C4)-alkyl radicals, (C1-C4)-aminoalcohols and (C3-C4)-ketones are added to the synthesis solution for the hydrothermal synthesis.

Abstract: The invention relates to a catalytically active membrane pore flow reactor, to the membrane used and to processes using this reactor.

Abstract: A process for the production of membranes which contain at least one solid layer on one side of a porous substrate by treating, with a synthesis solution forming the solid layer, that side of the substrate which is to be coated is described, wherein, in the production of the solid layer on the porous substrate, the space which, viewed from the substrate, is behind that side of the porous substrate which is not to be coated is filled with an inert fluid, the pressure and/or the temperature of the fluid being chosen so that contact of the synthesis solution with that side of the porous substrate which is not to be coated is substantially prevented.

Abstract: Composite membranes comprising at least one porous substrate layer and at least one microporous separation layer, comprising at least one zeolite of the MFI type, are described, the separation layer being produced by a hydrothermal synthesis in which the molar ratio of silicon to aluminum is greater than 120 and the separation layer contains less than 10% by weight of aluminum in elemental or chemically bound form in a zone of at least 100 nm adjacent to the separation layer.

Abstract: Ceramic nanofiltration membrane for use with organic solvents is produced by impregnating a mesoporous ceramic membrane with a hydrophobing agent.

Abstract: The invention relates to a fuel cell having a moderate operating temperature which comprises a cathode, an anode and an electrolyte, where at least the cathode comprises a material having the composition (Sr1-xCax)1-yAyMn1-zBzO3-? and A is at least one element from the group consisting of Ba, Pb, Na, K, Y and the lanthanide group, B is at least one element from the group consisting of Mg, Al, Ga, In, Sn and sub-group elements from the 4th, 5th or 6th period, and x adopts values of from 0.2 to 0.8, y adopts values of from 0 to 0.4, z adopts values of from 0 to <1, and ? adopts values which arise taking into account the electroneutrality principle.

Abstract: Reactor membranes for used in oxidation reactions of hydrocarbons involving oxygen comprising a selective oxidation catalyst on a mixed conducting, oxide ion selective ceramic membrane of the composition (Sr1-xCax)1-yAyMn1-zBzO3-&dgr;, where A is Ba, Pb, Na, K, Y, an element of the lanthanide group or a combination thereof, B is Mg, Al, Ga, In, Sn, an element of the 3d or 4d period or a combination thereof, x is from 0.2 to 0.8, y is from 0 to 0.4, z is from 0 to 0.6, and &dgr; is a number, dependent on x, y and z, that renders the composition charge neutral.

Abstract: A separation module which contains at least one bundle of ceramic capillaries (9), in which, for controlling the material transport and the flow in the separation module, a certain distance is established between the capillaries (9) by joining. The separation module can be used in a variety of ways in the separation of substances by filtration, also in combination with further measures of chemical process engineering.

Abstract: The invention relates to a fuel cell having a moderate operating temperature which comprises a cathode, an anode and an electrolyte, where at least the cathode comprises a material having the composition (Sr1-xCax)1-yAyMn1-zBzO3-&dgr; and

Abstract: This process serves to form a long-time-vacuum-tight, high-strength, and corrosion-resistant joint, by means of a joining material, between a first body and a second body each made of sintered, polycrystalline alumina ceramic with a purity greater than 92 wt. % or of sapphire. The joining material is interposed in the form of a paste, a foil, or a slip between the first body and the second body. The joining material has been made from 1) an agglomerate-free, highly disperse, high-purity .alpha.-alumina powder with particles of as high a degree of calcination as possible and of a size not exceeding 100 nm (=10.sup.-7 m), 2) an anorganic oxidic powder of an auxiliary sintering agent with particles of approximately the same size as the particle size of the .alpha.-alumina powder, 3) an organic vehicle which is dissolved or suspended in an organic or aqueous solvant and in which the particles of the respective powder are distributed as evenly as possible.