Abstract: Composition for use as catalyst in hydrosilylations, comprising at least one platinum compound selected from the group consisting of Pt[(Me2SiCH?CH2)2O]2 and Pt2[(Me2SiCH?CH2)2O]3 and at least one rhodium compound selected from the group consisting of Rh(acac)(CO)2, Rh2(CO)4Cl2, [Rh(cod)Cl]2, Rh(acac)(cod), RhH(CO)(PPh3)3, Rh(CO)(PPh3)(acac), RhCl(CO)(PPh3)2, and Rh-2-ethylhexanoate at a molar ratio of Pt/Rh in the range of 0.1 to 100.

Abstract: Process for the production of high purity iridium(III) chloride hydrate, comprising the steps of: (1) providing at least one material selected from the group consisting of solid H2[IrCl6] hydrate, aqueous, at least 1 wt. % H2[IrCl6] solution, and solid IrCl4 hydrate; (2) adding, to the at least one material provided in step (1), at least one monohydroxy compound selected from the group consisting of monohydroxy compounds that are miscible with water at any ratio, primary monoalcohols comprising 4 to 6 carbon atoms, and secondary monoalcohols comprising 4 to 6 carbon atoms at a molar ratio of Ir(IV):monohydroxy compound=1:0.6 to 1000, and allowing to react for 0.2 to 48 hours in a temperature range from 20 to 120° C., followed by removing volatile components from the reaction mixture thus formed.

Abstract: Composition for use as catalyst in hydrosilylations, comprising at least one platinum compound selected from the group consisting of Pt[(Me2SiCH?CH2)2O]2 and Pt2[(Me2SiCH?CH2)2O]3 and at least one rhodium compound selected from the group consisting of Rh(acac)(CO)2, Rh2(CO)4Cl2, [Rh(cod)Cl]2, Rh(acac)(cod), RhH(CO)(PPh3)3, Rh(CO)(PPh3)(acac), RhCl(CO)(PPh3)2, and Rh-2-ethylhexanoate at a molar ratio of Pt/Rh in the range of 0.1 to 100.

Abstract: Process for the production of high purity iridium(III) chloride hydrate, comprising the steps of: (1) providing at least one material selected from the group consisting of solid H2[IrCl6] hydrate, aqueous, at least 1 wt. % H2[IrCl6] solution, and solid IrCl4 hydrate; (2) adding, to the at least one material provided in step (1), at least one monohydroxy compound selected from the group consisting of monohydroxy compounds that are miscible with water at any ratio, primary monoalcohols comprising 4 to 6 carbon atoms, and secondary monoalcohols comprising 4 to 6 carbon atoms at a molar ratio of Ir(IV):monohydroxy compound =1:0.6 to 1000, and allowing to react for 0.2 to 48 hours in a temperature range from 20 to 120° C., followed by removing volatile components from the reaction mixture thus formed.

Abstract: The production of noble metal oxalate complexes from noble metal precursors and oxalic acid and/or oxalic acid salts is an exothermic reaction, in which heat and CO2 are produced, is described. The temperature can increase above the decomposition point of the noble metal oxalate complexes in the course of the reaction, which simultaneously releases more CO2. For safety reasons, when the reaction is carried out on a large scale, it is therefore necessary to take into consideration that the product must not be decomposed by heat that is produced during the reaction. Therefore, according to the invention, a method for the production of noble metal oxalate complexes is provided, in which the product noble metal oxalate complexes are added to the reaction mixture as an auto-catalyst.

Abstract: The production of noble metal oxalate complexes from noble metal precursors and oxalic acid and/or oxalic acid salts is an exothermic reaction, in which heat and CO2 are produced, is described. The temperature can increase above the decomposition point of the noble metal oxalate complexes in the course of the reaction, which simultaneously releases more CO2. For safety reasons, when the reaction is carried out on a large scale, it is therefore necessary to take into consideration that the product must not be decomposed by heat that is produced during the reaction. Therefore, according to the invention, a method for the production of noble metal oxalate complexes is provided, in which the product noble metal oxalate complexes are added to the reaction mixture as an auto-catalyst.