Patents by Inventor Jacques Garapon

Jacques Garapon has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 5981763
    Abstract: Bifunctional compounds are characterized in that they have the following general formula: ##STR1## where n is zero or a whole number in the range 1 to 4, limits included, X is a substituent where the X groups are identical or different when n is a number from 2 to 4, and R is a divalent group.Use of these compounds as functionalising agents for a polyolefin by grafting the compound onto the paraffinic chain, or as compatibilising agents for incompatible polymers.
    Type: Grant
    Filed: December 11, 1997
    Date of Patent: November 9, 1999
    Assignee: Institut Francais du Petrole
    Inventors: Jacques Garapon, Jacques Vallet
  • Patent number: 5472624
    Abstract: Anti-wear and high pressure lubricating compositions with a major proportion of lubricating oil and a minor proportion of at least one amine phosphate containing a terminal imide ring result from the reaction, under conditions for the formation of an amine salt, of at least one phosphate having the general formula (I): ##STR1## in which n is equal to 1 or 2, R.sup.1 is a divalent hydrocarbon group with 1 to 32 carbon atoms, R.sup.6 represents a hydrogen atom or a monovalent hydrocarbon group containing usually from 1 to 200 carbon atoms, with at least one amine.
    Type: Grant
    Filed: October 6, 1994
    Date of Patent: December 5, 1995
    Assignee: Institut Francais du Petrole
    Inventors: Jacques Denis, Jacques Garapon, Maurice Born, Francoise Dixmier
  • Patent number: 5449386
    Abstract: Amine phosphate having a terminal imide cycle resulting from the reaction, under formation conditions for an amine salt, of at least one phosphate complying with the general formula (I): ##STR1## in which n is equal to 1 or 2, R.sup.1 is a divalent hydrocarbon group having 1 to 32 carbon atoms, R.sup.6 stands for a hydrogen atom or a hydrocarbon group normally having 1 to 200 carbon atoms, with at least one amine. Preparation process in accordance with standard methods and use of these compounds as additives in fuels for engines, if appropriate in formulations containing a second constituent consisting of at least one product chosen from among the germination additives of paraffins, whereby said formulations can also contain at least one paraffin crystal growth inhibiting product.
    Type: Grant
    Filed: October 12, 1993
    Date of Patent: September 12, 1995
    Assignees: Institut Francais du Petrole, Elf Antar France
    Inventors: Jacques Denis, Jacques Garapon, Alain Forestiere, Gerard Leleu, Despina Vassilakis, Robert Leger
  • Patent number: 5425788
    Abstract: An additive composition for fuels comprising at least one constituent (A) and at least one constituent (B), the said constituent (A) comprising at least one multinitrogen-containing compound of general formula (I): ##STR1## where R.sup.1 and R.sup.2, which are the same or different each represent a hydrocarbon group or a group of formula R.sup.5 --(--O--R.sup.6 --).sub.a --(--O--R.sup.7 --).sub.b --, R.sup.3 is a hydrocarbon group or a group of formula R.sup.8 --(--X--R.sup.9 --).sub.c --(--X--R.sup.1 O--).sub.d --(--X--R.sup.1 1--).sub.e -- in which X is selected from the groups --O-- and --NR.sup.1 2--, R.sup.5, R.sup.6, R.sup.7, R.sup.8, R.sup.9, R.sup.1 0 and R.sup.1 1 each represent a hydrocarbon group, a, d and e are each zero or a whole number, b and c are each a whole number, R.sup.4 and R.sup.1 2 each represent a hydrogen atom or a hydrocarbon group and n is a number from 0 to 20 and the said constituent (B) comprises at least one polyglycol which is soluble in the fuel in question.
    Type: Grant
    Filed: November 4, 1993
    Date of Patent: June 20, 1995
    Assignees: Institut Francais du Petrole, Elf Antar France
    Inventors: Jacques Garapon, Alain Forestiere, Philippe Mulard, Yvan Labruyere
  • Patent number: 5234476
    Abstract: Polynitrogen compound having two terminal cycles of the imide type, its preparation by conventional organic chemistry methods and its use as an additive for engine fuel. This compound complies with the general formula (I): ##STR1## in which R.sup.1, R.sup.2, R.sup.3, and R.sup.4 are as set forth in the specification.
    Type: Grant
    Filed: July 30, 1992
    Date of Patent: August 10, 1993
    Assignees: Institut Francais du Petrole, Elf France
    Inventors: Jacques Garapon, Roger Bregent, Remi Touet, Philippe Mulard, Pierre Schmelzle
  • Patent number: 5112937
    Abstract: Disclosed are polymers of average molecular weight ranging from 400 to 20,000 comprising thiosubstituted groups per molecule and resulting from the reaction, in the presence of an addition catalyst, of at least one compound with a thiol function, having 1 to 60 carbon atoms per molecule, with an unsaturated polyester resulting from the condensation of an aliphatic epoxide with an unsaturated aliphatic dicarboxylic compound comprising at least one ethylenic unsaturation in the alpha position of one of the carboxyl groups. Also disclosed are middle distillate compositions having a distillation range from 150.degree. to 450.degree. C. and comprising a minor proportion, preferably from 0.001 to 2% by weight, of at least one of the polymers defined hereinabove.
    Type: Grant
    Filed: May 10, 1991
    Date of Patent: May 12, 1992
    Assignees: Institut Francais du Petrole, Elf France
    Inventors: Jacques Garapon, Remi Touet, Bernard Damin, Beatrice Debled
  • Patent number: 5106515
    Abstract: Disclosed is a polymer of average molecular weight ranging from 400 to 20,000 comprising amino substituted groups in its molecule and resulting from the reaction of at least one compound with a primary amine function having 1 to 60 carbon atoms with an unsaturated polyester resulting from the condensation of an unsaturated aliphatic dicarboxylic compound, comprising at least one ethylenic unsaturation in the alpha position of one of the carboxyl groups, with at least one epoxidated compound having 4 to 62 carbon atoms chosen from ethers and esters of epoxyalcohols and esters of epoxyacids.Also disclosed is a middle distillate composition having a distillation range from 150.degree. to 450.degree. C. and comprising a minor proportion, preferably from 0.001 to 2% in weight, of at least one of the polymers defined hereinabove.
    Type: Grant
    Filed: November 27, 1990
    Date of Patent: April 21, 1992
    Assignees: Institut Francais du Petrole, Elf France
    Inventors: Jacques Denis, Jacques Garapon, Bernard Damin, Robert Leger
  • Patent number: 5104842
    Abstract: The object of the invention is a catalytic composition comprising titanium and phosphorus and resulting from the contacting of at least one titanate with at least one quaternary "onium" salt of an acid selected from the group consisting of phosphoric acid and the phosphonic acids of formula R.sup.7 H.sub.2 PO.sub.3 in which R.sup.7 is a hydrocarbon group having 1 to 38 atoms of carbon and the "onium" remainder is a remainder of formula (R.sup.8 R.sup.9 R.sup.10 R.sup.11 M).sup.+ in which M is an element from the group VA of the periodic table of elements, preferably nitrogen or phosphorous, and R.sup.8, R.sup.9, R.sup.10 and R.sup.11, identical or different, represent each an atom of hydrogen or a hydrocarbon group having 1 to 38 atoms of carbon.This catalytic composition is utilizable for producing asters and polyesters from epoxides and carboxylic acid anhydrides.
    Type: Grant
    Filed: October 16, 1990
    Date of Patent: April 14, 1992
    Assignees: Institut Francais du Petrol, L'Air Liquide Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges Claude, Elf France
    Inventors: Jacques Garapon, Isabelle Muller, Remi Touet, Catherine Huet, Bernard Damin
  • Patent number: 5037945
    Abstract: Disclosed are polymers of average molecular weight ranging from 400 to 20,000 comprising thiosubstituted groups per molecule and resulting from the reaction, in the presence of an addition catalyst, of at least one compound with a thiol function, having 1 to 60 carbon atoms per molecule, with an unsaturated polyester resulting from the condensation of an aliphatic epoxide with an unsaturated aliphatic dicarboxylic compound comprising at least one ethylenic unsaturation in the alpha position of one of the carboxyl groups. Also disclosed are middle distillate compositions having a distillation range from 150.degree. to 450.degree. C. and comprising a minor proportion, preferably from 0.001 to 2% by weight, of at least one of the polymers defined hereinabove.
    Type: Grant
    Filed: February 6, 1989
    Date of Patent: August 6, 1991
    Assignees: Institut Francais du Petrole, Elf France
    Inventors: Jacques Garapon, Remi Touet, Bernard Damin, Beatrice Debled
  • Patent number: 5030711
    Abstract: The invention relates to a process for condensing at least one epoxide on at least one cyclic anhydride of a dicarboxylic acid in the presence of a catalyst consisting of at least one titanium nitrogenous complex of the formula (I) Ti(OR.sup.1).sub.m (OR.sup.2 ).sub.n (OR.sup.2 ).sub.p Lg in which R.sup.1, R.sup.2 and R.sup.3 each independently represents one hydrocarbon group, L represents the remainder of a nitrogenous compound, the sum of m+n+p+q is 4, q is an integer from 1 to 4 and m, n and p are independently each 0 or 1. The process allows for obtaining a perfectly alternating polyester.
    Type: Grant
    Filed: March 12, 1990
    Date of Patent: July 9, 1991
    Assignees: Institut Francais du Petrole, L'Air Liquide Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges Claude, ELF France
    Inventors: Valerie Bagrel, Jacques Garapon, Remi Touet, Catherine Huet, Bernard Damin
  • Patent number: 5019643
    Abstract: A process for condensing at least one aliphatic epoxide having at least 8 atoms of carbon in its molecule on at least one cyclic anhydride of a dicarboxylic acid in the presence of a catalyst consisting of at least one titanium complex of general formula (I) Ti(OR).sub.2 (L).sub.2 in which each R group independently represents one hydrocarbon group with 1 to 10 atoms of carbon and each L group represents a ligand of the diketonic beta type or of the keto-ester beta.
    Type: Grant
    Filed: March 12, 1990
    Date of Patent: May 28, 1991
    Assignees: Institut Francais du Petrole, L'Air Liquide Societe Anonyme pour L'Etude et L'Exploitation des Procedes Georges Claude, ELF France
    Inventors: Valerie Bagrel, Jacques Garapon, Remi Touet, Catherine Huet, Bernard Damin
  • Patent number: 5001202
    Abstract: Polymer of average molecular weight ranging from 400 to 20 000 comprising amino substituted groups in its molecule and resulting from the reaction of at least one compound with a primary amine function having 1 to 60 carbon atoms with an unsaturated polyester resulting from the condensation of an unsaturated aliphatic dicarboxylic compound, comprising at least one ethylenic unsaturation in the alpha position of one of the carboxyl groups, with at least one epoxidated compound having 4 to 62 carbon atoms chosen from ethers and esters of epoxyalcohols and esters of epoxyacids.Middle distillate composition having a distillation range from 150.degree. to 450.degree. C. and comprising a minor proportion, preferably from 0.001 to 2% in weight, of at least one of the polymers defined hereinabove.
    Type: Grant
    Filed: February 3, 1989
    Date of Patent: March 19, 1991
    Assignees: Institut Francais du Petrole, Elf France
    Inventors: Jacques Denis, Jacques Garapon, Bernard Damin, Robert Leger
  • Patent number: 4997910
    Abstract: The invention relates to a process for condensing at least one epoxide on at least one cyclic anhydride of a dicarboxylic acid in the presence of a catalyst consisting of at least one titanium peroxidic complex of the peroxo type of the A form ##STR1## Said process allows to obtain a perfectly alternate polyester.
    Type: Grant
    Filed: December 7, 1989
    Date of Patent: March 5, 1991
    Assignees: Institut Francais du Petrole, L'Air Liquide Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges Claude, Elf France
    Inventors: Jacques Garapon, Remi Touet, Catherine Huet, Bernard Damin
  • Patent number: 4731095
    Abstract: Copolymers with nitrogen groups are used as additives to lower the cloud point and improve the filterability limit temperature and the pour point of middle distillates such as gas oils. They are obtained by reacting a compound having a primary amine group with a copolymer comprising 15 to 40% of recurrent units form a linear .alpha.-olefin, 20 to 70% of recurrent units form and .alpha.,.beta.-unsaturated dicarboxylic compound and 15 to 45% of recurrent units form an alkyl ester of unsaturated monocarboxylic acid.
    Type: Grant
    Filed: September 16, 1985
    Date of Patent: March 15, 1988
    Assignees: Institut Francais du Petrole, Elf France
    Inventors: Jacques Garapon, Bernard Sillion, Bernard Damin, Robert Leger
  • Patent number: 4433157
    Abstract: A process for manufacturing an alkenyl dicarboxylic acid, anhydride comprises reacting at least one halogenated polyolefin with at least one unsaturated dicarboxylic acid anhydride in substantially stoichiometrical proportion, in the presence of a minor proportion of at least one organic compound containing at least one double bond bearing at least one electron attracting substituent.
    Type: Grant
    Filed: May 11, 1982
    Date of Patent: February 21, 1984
    Assignee: Institut Francais du Petrole
    Inventors: Jerome Weill, Jacques Garapon, Bernard Sillion