Abstract: A catalyst for use in the production of vinyl acetate which comprises (1) a catalyst support, (2) palladium, (3) an acid, (4) at least one acetic acid catalyst promoter and (5) at least one vinyl acetate promoter and/or co-promoter. A process for the production of vinyl acetate from ethylene and an oxygen-containing gas using the catalyst.

Abstract: A catalyst for use in the production of vinyl acetate which comprises (1) a catalyst support, (2) palladium, (3) an acid, (4) at least one acetic acid catalyst promoter and (5) at least one vinyl acetate promoter and/or co-promoter. A process for the production of vinyl acetate from ethylene and an oxygen-containing gas using the catalyst.

Abstract: In a process for the production of vinyl acetate by reacting ethylene, acetic acid and an oxygen-containing gas in a reactor to produce a process stream which is removed from the reactor as an outlet stream, the process is improved by maintaining the oxygen concentration of the outlet stream at or near its flammability limit.

Abstract: Process for the production of vinyl acetate in which ethylene, acid and oxygen-containing gas are combined at elevated temperature in the presence of a catalyst material to produce (i) a product mixture comprising vinyl acetate, (ii) a liquid by-product comprising acetic acid and (iii) a gaseous by-product comprising carbon dioxide. The liquid by-product is separated from the product mixture and treated to reduce the water content therein before being recycled to the reactor such that the water entering the reactor comprises less than 6 wt %, (preferably less than 4 wt %, more preferably less than 3 wt %) of the total of acetic acid and water entering the reactor.

Abstract: An improved defrost controller is provided for a space cooling system of the type having an evaporator in heat exchange relationship with a space to be cooled, a condenser external to the space, a compressor for circulating heat transfer fluid between the evaporator and condenser, an expansion valve located between an outlet from the condenser and an inlet to the evaporator, and a defroster operatively associated with the evaporator. The expansion valve is positionable in a plurality of positions between a fully open position and a fully closed position to maintain a desired level of superheat across the evaporator. The defrost controller monitors the expansion valve position and activates the defroster in response to the expansion valve being in a more closed position than a predetermined defrost target position.

Abstract: A process for the production of vinyl acetate which comprises contacting ethylene, acetic acid and an oxygen-containing gas with a supported palladium catalyst prepared by a process comprising the steps of (a) impregnating a catalyst support with a palladium compound, (b) converting the palladium compound to substantially metallic palladium, and (c) sintering the supported palladium at a temperature of greater than 500.degree. C.

Abstract: An improved defrost controller is provided for a space cooling system of the type having an evaporator in heat exchange relationship with a space to be cooled, a condenser external to the space, a compressor for circulating heat transfer fluid between the evaporator and condenser, an expansion valve located between an outlet from the condenser and an inlet to the evaporator, and a defroster operatively associated with the evaporator. The expansion valve is positionable in a plurality of positions between a fully open position and a fully closed position to maintain a desired level of superheat across the evaporator. The defrost controller monitors the expansion valve position and activates the defroster in response to the expansion valve being in a more closed position than a predetermined defrost target position.

Abstract: A supervisory channel is provided on a digital transmission system by frequency modulation of the data signal transmitted along a transmission link which includes repeaters. The frequency modulation can be carried out using an elastic store. Each repeater includes means for demodulating the frequency modulation so that each repeater can be addressed and interrogated. Each repeater can also phase modulate the data signals on the return link to a terminal station so that signals indicative of an interrogated condition can be transmitted to the terminal station.