Abstract: A printing apparatus including a manifold shaped as a rectangular parallelepiped having three pairs of parallel faces and including (i) a body thereof defining a plurality of fluidic channels, (ii) a bottom portion thereof defining a slot configured to accommodate insertion of a printing element; and (iii) at least one face defining a plurality of fluidic connections in fluidic communication with the fluidic channels. A method for manufacturing a printing apparatus includes the steps of a) manufacturing a manifold by manufacturing a parallelepiped and defining a slot therein configured to hold a printing element; b) machining features into the manifold for mechanical mounting, electronic connection, and fluid connection; and (c) assembling the manifold with the printing element and a gasket to form the printing apparatus.

Abstract: A material system and method for bonding refractory powders in a three dimensional printer. A first particulate component including a refractory material is mixed with a first reactive component to form a particulate mixture. A flat layer of the particulate mixture is dispensed onto a build surface. A liquid binder, which may include a furan monomer and a surfactant, is dispensed by an ink-jet printhead onto the particulate mixture. The particulate mixture may contain a furan-soluble polymer that imposes a capillary attraction for the liquid binder, keeping it situated in the immediate vicinity of where the binder is dispensed. Additionally it provides a sufficient catalytic power to co-polymerize with the furan monomer and form a solid structure. This enables a 3D printer to build strong, accurate parts with high packing density, and to reuse the feed material many times in the printer.

Abstract: A powder for three-dimensional printing including a mixture of soluble adhesive; cement filler including magnesium oxide, and acid additive; and nonreactive ceramic filler. A kit includes a substantially nonaqueous liquid jetting fluid, and a solid powder mixture including soluble adhesive, magnesium oxide, an acid additive, and a nonreactive ceramic filler. A nonaqueous liquid jetting fluid includes up to 50 wt % cosolvents, and an acidic additive. A method for forming a three dimensional article includes providing a layer of a powder mixture including a soluble adhesive, magnesium oxide, an acid additive, and a nonreactive ceramic filler; and applying a substantially nonaqueous liquid jetting fluid including less than 50% water by weight to the powder mixture layer.

Abstract: A material system and method for bonding refractory powders in a three dimensional printer. A first particulate component including a refractory material is mixed with a first reactive component to form a particulate mixture. A flat layer of the particulate mixture is dispensed onto a build surface. A liquid binder, which may include a furan monomer and a surfactant, is dispensed by an ink-jet printhead onto the particulate mixture. The particulate mixture may contain a furan-soluble polymer that imposes a capillary attraction for the liquid binder, keeping it situated in the immediate vicinity of where the binder is dispensed. Additionally it provides a sufficient catalytic power to co-polymerize with the furan monomer and form a solid structure. This enables a 3D printer to build strong, accurate parts with high packing density, and to reuse the feed material many times in the printer.

Abstract: Apparatus and methods for fabricating a solid article by three-dimensional printing. A bed of loose solid powder is formed, a fluid dispenser moved parallel to the bed, and a liquid dispensed from the fluid dispenser onto at least a portion of a surface of the powder to form a first printed layer having a first pattern printed thereon. The fluid dispenser includes a printhead inclined at an angle selected from a range of 2 to 20 degrees from vertical with respect to the bed. An apparatus includes a stage, a spreading mechanism to spread layers of loose powder on the stage, and a fluid dispenser disposed above the stage and configured to dispense droplets of fluid that travel in free flight to the stage, the fluid dispenser including a printhead tilted at an angle from 2 to 20 degrees relative to a line perpendicular to the stage surface.

Abstract: A 3D printing apparatus including a manifold configured to receive a printing element; and a gasket disposed at a lower portion of the manifold. The manifold and gasket enclose the printing element, and the gasket defines a liquid-tight seal isolating the printing element from ambient. In another embodiment, a 3D printing apparatus includes a printing element; a manifold configured to receive the printing element; and a gasket disposed proximate the printing element, with the manifold and gasket together enclosing the printing element, and the gasket defining a liquid-tight seal that isolates the printing element from ambient. A service apparatus for washing a printing element, the apparatus including a parking element having at least one surface, and a frame defining a plurality of channels for introducing and draining a liquid solution when a printing element is parked against the surface of the parking element. Methods for capping, washing, preserving, and storing printing elements.

Abstract: A printing apparatus including a manifold shaped as a rectangular parallelepiped having three pairs of parallel faces and including (i) a body thereof defining a plurality of fluidic channels, (ii) a bottom portion thereof defining a slot configured to accommodate insertion of a printing element; and (iii) at least one face defining a plurality of fluidic connections in fluidic communication with the fluidic channels. A method for manufacturing a printing apparatus includes the steps of a) manufacturing a manifold by manufacturing a parallelepiped and defining a slot therein configured to hold a printing element; b) machining features into the manifold for mechanical mounting, electronic connection, and fluid connection; and (c) assembling the manifold with the printing element and a gasket to form the printing apparatus.

Abstract: A powder for three-dimensional printing including a mixture of soluble adhesive; cement filler including magnesium oxide, and acid additive; and nonreactive ceramic filler. A kit includes a substantially nonaqueous liquid jetting fluid, and a solid powder mixture including soluble adhesive, magnesium oxide, an acid additive, and a nonreactive ceramic filler. A nonaqueous liquid jetting fluid includes up to 50 wt % cosolvents, and an acidic additive. A method for forming a three dimensional article includes providing a layer of a powder mixture including a soluble adhesive, magnesium oxide, an acid additive, and a nonreactive ceramic filler; and applying a substantially nonaqueous liquid jetting fluid including less than 50% water by weight to the powder mixture layer.

Abstract: Apparatus and methods for fabricating a solid article by three-dimensional printing. A bed of loose solid powder is formed, a fluid dispenser moved parallel to the bed, and a liquid dispensed from the fluid dispenser onto at least a portion of a surface of the powder to form a first printed layer having a first pattern printed thereon. The fluid dispenser includes a printhead inclined at an angle selected from a range of 2 to 20 degrees from vertical with respect to the bed. An apparatus includes a stage, a spreading mechanism to spread layers of loose powder on the stage, and a fluid dispenser disposed above the stage and configured to dispense droplets of fluid that travel in free flight to the stage, the fluid dispenser including a printhead tilted at an angle from 2 to 20 degrees relative to a line perpendicular to the stage surface.

Abstract: Semiconductor photovoltaic cells have surfaces that are textured for processing and photovoltaic reasons. The absorbing regions may have parallel grooves that reduce loss of solar energy that would otherwise be lost by reflection. One form of texturing has parallel grooves and ridges. The cell also includes regions of metallization for collecting the generated electrical carriers and conducting them away, which may be channels. The topography is considered during production, using a process that takes advantage of the topography to govern what locations upon will receive a specific processing, and which locations will not receive such a processing. Liquids are treated directly into zones of the cell. They migrate throughout a zone and act upon the locations contacted. They do not migrate to other zones, due to impediments to fluid flow that are features of the surface texture, such as edges, walls and ridges.

Abstract: Semiconductor bodies, such as for solid state electronics and photovoltaic cells, have surfaces that are textured for processing, charge carrying and photovoltaic reasons. Absorbing regions may have grooves that reduce loss of solar energy by reflection. Semiconductor bodies also include metallizations for conducting electrical carriers, which may be channels. Production processes take advantage of the topography to govern which locations will receive a specific processing, and which locations will not. Liquids are treated directly into zones. They migrate throughout a zone and act upon the locations contacted. They do not migrate to other zones, due to impediments to flow, such as edges, walls and ridges. Liquid may also be deposited and migrate within a zone, to block or mask a subsequent activity, such as etching.

Abstract: Semiconductor photovoltaic cells have surfaces that are textured for processing and photovoltaic reasons. The absorbing regions may have grooves that reduce loss of solar energy that would otherwise be lost by reflection. One form of texturing has grooves and ridges. The cell also includes metallizations for collecting generated electrical carriers and conducting them away, which may be channels. The topography is considered during production, using a process that takes advantage of the topography to govern what locations will receive a specific processing, and which locations will not. Liquids are treated directly into zones. They migrate throughout a zone and act upon the locations contacted. They do not migrate to other zones, due to impediments to flow, such as edges, walls and ridges. Liquid may also be deposited and migrate within a zone, to block or mask a subsequent activity, such as etching.

Abstract: Semiconductor photovoltaic cells have surfaces that are textured for processing and photovoltaic reasons. The absorbing regions may have grooves that reduce loss of solar energy that would otherwise be lost by reflection. One form of texturing has grooves and ridges. The cell also includes metallizations for collecting generated electrical carriers and conducting them away, which may be channels. The topography is considered during production, using a process that takes advantage of the topography to govern what locations will receive a specific processing, and which locations will not. Liquids are treated directly into zones. They migrate throughout a zone and act upon the locations contacted. They do not migrate to other zones, due to impediments to flow, such as edges, walls and ridges. Liquid may also be deposited and migrate within a zone, to block or mask a subsequent activity, such as etching.

Abstract: Semiconductor photovoltaic cells have surfaces that are textured for processing and photovoltaic reasons. The absorbing regions may have parallel grooves that reduce loss of solar energy that would otherwise be lost by reflection. One form of texturing has parallel grooves and ridges. The cell also includes regions of metallization for collecting the generated electrical carriers and conducting them away, which may be channels. The topography is considered during production, using a process that takes advantage of the topography to govern what locations upon will receive a specific processing, and which locations will not receive such a processing. Liquids are treated directly into zones of the cell. They migrate throughout a zone and act upon the locations contacted. They do not migrate to other zones, due to impediments to fluid flow that are features of the surface texture, such as edges, walls and ridges.

Abstract: Mixture for use in a three-dimensional printer to make molds suitable for producing ferrous coatings. The mixture includes cement, sand and accelerator. Grain sizes of the cement, sand and accelerator are selected to assure that the three-dimensional printer generates coherent layers.

Abstract: A materials system and methods are provided to enable the formation of articles by three dimensional printing. The materials system includes particulate mixtures having a whitening agent and a solid particulate additive comprising an acid, the latter adapted for modifying a cure rate of an infiltrant. The materials system also includes aqueous fluids including optical brightening agents.

Abstract: Materials that contain liquid are deposited into grooves upon a surface of a work piece, such as a silicon wafer to form a solar cell. Liquid can be dispensed into work piece paths, such as grooves under pressure through a dispensing tube. The tube mechanically tracks in the groove. The tube may be small and rest at the groove bottom, with the sidewalls providing restraint. Or it may be larger and ride on the top edges of the groove. A tracking feature, such as a protrusion, Non-circular cross-sections, molded-on protrusions and lobes also enhance tracking. The tube may be forced against the groove by spring or magnetic loading. Alignment guides, such as lead-in features may guide the tube into the groove. Restoring features along the path may restore a wayward tube. Many tubes may be used. Many work pieces can be treated in a line or on a drum.

Abstract: Mixture for use in a three-dimensional printer to make molds suitable for producing ferrous coatings. The mixture includes cement, sand and accelerator. Grain sizes of the cement, sand and accelerator are selected to assure that the three-dimensional printer generates coherent layers.

Abstract: Semiconductor photovoltaic cells have surfaces that are textured for processing and photovoltaic reasons. The absorbing regions may have parallel grooves that reduce loss of solar energy that would otherwise be lost by reflection. One form of texturing has parallel grooves and ridges. The cell also includes regions of metallization for collecting the generated electrical carriers and conducting them away, which may be channels. The topography is considered during production, using a process that takes advantage of the topography to govern what locations upon will receive a specific processing, and which locations will not receive such a processing. Liquids are treated directly into zones of the cell. They migrate throughout a zone and act upon the locations contacted. They do not migrate to other zones, due to impediments to fluid flow that are features of the surface texture, such as edges, walls and ridges.

Abstract: The present invention is directed to three-dimensional printing material systems and method, and an article made therefrom. The method of the present invention includes building cross-sectional portions of a three-dimensional article, and assembling the individual cross-sectional areas in a layer-wise fashion to form a final article. The individual cross-sectional areas are built by using an ink-jet printhead to deliver a fluid to a particulate material that includes particulate material.