Abstract: A target track (20) of an anode (14) of an x-ray tube becomes heated adjacent a focal spot (18) to temperatures on the order of 1100.degree.-1400.degree. C. To protect the anode, a body portion (34) is coated (46) with a thermal energy emissive oxide layer (48). In order to prevent carbon from the body portion from migrating out to the oxide layer and forming carbon monoxide gas, a carbide forming barrier layer (36) is formed (38,40) between the body and the oxide coating. The barrier layer is a dense, substantially pore-free coating of a metal that has a free energy of carbide formation of at least 100 KJ/mole at 1200.degree. C. Preferably, the barrier layer material is zirconium, although hafnium, titanium, vanadium, uranium, tantalum, niobium, chromium, and their alloys also provide acceptable barriers to carbon atom migration.