Abstract: The present invention discloses a reactivity-based self-stratifying coating composition. The coating composition can include a polyol, silsesquioxane, a polyester polyol, and a crosslinker that form a mixture within a solvent. The polyol can be selected from a fluorinated polyether, a fluoroethylene-alkyl vinyl ether and/or a combination thereof. The silsesquioxane can be an epoxy functional silsesquioxane having a formula of (R)6(C6H11O2)2(SiO1.5)8 where R can be selected from hydrogen, methyl, ethyl, propyl, butyl, pentyl, hexyl, cyclopentyl, cyclohexyl, benzyl, phenyl, and isomers thereof. In some instances, the epoxy functional silsesquioxane can be a di-epoxy silsesquioxane.

Abstract: A coating composition may include a polyol, a silsesquioxane, a polyurethane dendrimer, a crosslinker, and a pigment in contact with a dispersing agent. A process for preparing a coating composition is further disclosed including the step of contacting a polyol, a silsesquioxane, a polyurethane dendrimer, and a crosslinker to form a coating mixture dispersed within a solvent. The process further includes adding a pigment in contact with a dispersing agent to the coating mixture, and forming a self-stratifying coating having at least one layer, wherein the pigment resides substantially within one of the at least one layer.

Abstract: The present invention discloses a reactivity-based self-stratifying coating composition. The coating composition can include a polyol, silsesquioxane, a polyester polyol, and a crosslinker that form a mixture within a solvent. The polyol can be selected from a fluorinated polyether, a fluoroethylene-alkyl vinyl ether and/or a combination thereof. The silsesquioxane can be an epoxy functional silsesquioxane having a formula of (R)6(C6H11O2)2(SiO1.5)8 where R can be selected from hydrogen, methyl, ethyl, propyl, butyl, pentyl, hexyl, cyclopentyl, cyclohexyl, benzyl, phenyl, and isomers thereof. In some instances, the epoxy functional silsesquioxane can be a di-epoxy silsesquioxane.

Abstract: A process for preparing a coating composition includes contacting a polyol, a silsesquioxane, a polyurethane dendrimer, and a crosslinker, wherein the polyol, the silsesquioxane, the polyurethane dendrimer, and the crosslinker are dispersed within a solvent and forming a self-stratifying coating. Further, a coating composition includes a polyol, a silsesquioxane, a polyurethane dendrimer and a crosslinker forming a mixture dispersed within a solvent.

Abstract: A coating composition may include a polyol, a silsesquioxane, a polyurethane dendrimer, a crosslinker, and a pigment in contact with a dispersing agent. A process for preparing a coating composition is further disclosed including the step of contacting a polyol, a silsesquioxane, a polyurethane dendrimer, and a crosslinker to form a coating mixture dispersed within a solvent. The process further includes adding a pigment in contact with a dispersing agent to the coating mixture, and forming a self-stratifying coating having at least one layer, wherein the pigment resides substantially within one of the at least one layer.

Abstract: A process for preparing a coating composition includes contacting a polyol, a silsesquioxane, a polyurethane dendrimer, and a crosslinker, wherein the polyol, the silsesquioxane, the polyurethane dendrimer, and the crosslinker are dispersed within a solvent and forming a self-stratifying coating. Further, a coating composition includes a polyol, a silsesquioxane, a polyurethane dendrimer and a crosslinker forming a mixture dispersed within a solvent.

Abstract: A silane-capped polyurethane block copolymer comprising at least one polyester block and at least one polyacrylate block is disclosed. The copolymer can be used in coatings, and is particularly useful as a primer coating, especially as a primer for non-porous surfaces to which adhesives will be applied.

Abstract: A one-component, moisture-curable polyurethane-based adhesive composition useful for affixing glass panels directly to electrocoat painted metal substrates or over a primer comprises a polyurethane base polymer containing an electrocoat adhesion promoter. The sealant composition has fast cure times at ambient temperatures and forms a strong bond directly to electrocoat painted metal substrates without the need for a sealant primer.

Abstract: A polyurethane resin polymer that is terminated on each end with a silane group, and has appended thereto at least one additional silane group.

Abstract: A primerless, one-component, moisture-curable polyurethane-based adhesive composition useful for affixing glass panels directly to electrocoat painted metal substrates comprises a polyurethane base polymer containing an electrocoat adhesion promoter. The sealant composition has fast cure times at ambient temperatures and forms a strong bond directly to electrocoat painted metal substrates without the need for a sealant primer.

Abstract: One-component, moisture-curable sealant compositions having fast cure times comprise a mixture of a silane-capped polyurethane polymer, an aminosilane cross-linking agent, and a silyl-substituted guanidine accelerator.

Abstract: One-component, moisture-curable sealant compositions having fast cure times comprise a mixture of a silane-capped polyurethane polymer, an aminosilane cross-linking agent, and a silyl-substituted guanidine accelerator.

Abstract: One-component, moisture-curable sealant compositions having fast cure times comprise a mixture of a silane-capped polyurethane polymer, an aminosilane cross-linking agent, and a silyl-substituted piperazinyl accelerator.

Abstract: One-component, moisture-curable sealant compositions having fast cure times comprise a mixture of a silane-capped polyurethane polymer, an aminosilane cross-linking agent, and a titanium ester accelerator.

Abstract: Novel polyurea/polyurethane two-component adhesive compositions are disclosed which comprise the reaction product of (a) a blend of an amine terminated polybutadiene and a polyhydroxybutadiene with (b) an aliphatic or aromatic di- or polyisocyanate and optionally chain extenders, tackifiers, coupling agents fillers and curingly effective amounts of catalyst.