Abstract: In one aspect of the instant disclosure, a setter plate assembly to sinter green titanium dioxide forms, such as aluminum smelting cathodes made by multiple forming methods is produced. The assembly is itself formed from sintered titanium diboride. The open area of the assembly and vents allow off-gassing during settering to producing a sintered product with reduced contamination. The setter plate assembly is made principally from titanium diboride, which is chemically compatible with green titanium dioxide forms.