Patents by Inventor Jean-Bernard Egraz

Jean-Bernard Egraz has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 5905110
    Abstract: Copolymer dispersants for use in an aqueous emulsion containing fillers pigments or both where the copolymer has the formula (I)--(A).sub.a --(B).sub.b --(C).sub.c -- (I)whereinA represents units resulting from acrylic or methacrylic acid monomers,B represents units resulting from styrene monomers or a derivative thereof,C represents units resulting from C.sub.1 -C.sub.4 alkyl acrylate or methacrylate monomers,a, b and c represent the percentages by weight of A, B and C, respectively with respect to total weight of the monomers,wherein the copolymer yields a homogeneous solution which is clear to cloudy in a medium of neutral or alkaline pH and wherein the copolymer has a specific viscosity of less than or equal to 15, which imparts increased water resistance to dry or drying films made from aqeuous emulsion compositions containing the copolymer dispersant. The resulting aqueous compositions are useful as textured coatings, coatings, aqueous paints and coating compositions.
    Type: Grant
    Filed: April 9, 1996
    Date of Patent: May 18, 1999
    Assignee: Coatex, S.A.
    Inventors: Henri Grondin, Jean-Bernard Egraz, Jean-Marc Suau
  • Patent number: 5891972
    Abstract: Homopolymers and/or copolymers are manufactured by polymerizing ethylenically monounsaturated monomer(s) in an aqueous solution in a reaction vessel containing compounds which contain a phosphorus atom of degree of oxidation less than 5, phosphorous compounds being introduced in amounts of 0.005-0.49 gram-atom phosphorus per mol of unsaturation in said ethylenically unsaturated monomer(s) in the presence of hydrogen peroxide and in the absence of any agent(s) which decomposes hydrogen peroxide thereby forming free radicals, in the absence of any other generator of free radicals, and in the absence of any per salt and/or any other transfer agent.
    Type: Grant
    Filed: July 21, 1997
    Date of Patent: April 6, 1999
    Assignee: Coatex S.A.
    Inventors: Jean-Bernard Egraz, Jean-Marc Suau, Yves Kensicher
  • Patent number: 5736601
    Abstract: A grinding agent containing polymers and/or copolymers partially neutralized by magnesium, for aqueous suspensions of mineral substances to be used in pigmentary applications is disclosed.A grinding agent composed of polymers and/or copolymers having a specific viscosity of between 0.3 and 0.8 and obtained by treatment, using one or several solvents, of a polymer and/or copolymer resulting from polymerization and/or copolymerization of acrylic and/or vinyl monomers comprising acid groups whose active acid sites are partially or completely neutralized to a degree of neutralization of 40 to 60%, including terminals, of the active acid sites using a neutralizing agent containing magnesium ions, and a degree of neutralization reaching 60% using a neutralizing agent containing sodium ions is disclosed.
    Type: Grant
    Filed: April 24, 1996
    Date of Patent: April 7, 1998
    Assignee: Coatex S.A.
    Inventors: Jean-Bernard Egraz, Jacques Mongoin, Georges Ravet, Jean-Marc Suau
  • Patent number: 5569702
    Abstract: A grinding agent containing polymers and/or copolymers partially neutralized by magnesium, for aqueous suspensions of mineral substances to be used in pigmentary applications is disclosed.A grinding agent composed of polymers and/or copolymers having a specific viscosity of between 0.3 and 0.8 and obtained by treatment, using one or several solvents, of a polymer and/or copolymer resulting from polymerization and/or copolymerization of acrylic and/or vinyl monomers comprising acid groups whose active acid sites are partially or completely neutralized to a degree of neutralization of 40 to 60%, including terminals, of the active acid sites using a neutralizing agent containing magnesium ions, and a degree of neutralization reaching 60% using a neutralizing agent containing sodium ions is disclosed.
    Type: Grant
    Filed: February 6, 1995
    Date of Patent: October 29, 1996
    Assignee: Coatex S.A.
    Inventors: Jean-Bernard Egraz, Jacques Mongoin, Georges Ravet, Jean-Marc Suau
  • Patent number: 5534586
    Abstract: A grinding agent containing polymers and/or copolymers partially neutralized by magnesium, for aqueous suspensions of mineral substances to be used in pigmentary applications is disclosed.A grinding agent composed of polymers and/or copolymers obtained by polymerization and/or copolymerization of acrylic and/or vinyl monomers containing acid groups, and in which the active acid sites are completely or partially neutralized to a degree of 40% to 60%, including terminals, using a neutralizing agent containing magnesium ions, and to a degree of up to 60% using a neutralizing agent containing monovalent ions is disclosed.A procedure for grinding in an aqueous suspension using said agent, as well as the aqueous suspensions produced using said procedure and their applications to the fields of weight fillers, paper coating, paints, and plastics is also disclosed.
    Type: Grant
    Filed: February 6, 1995
    Date of Patent: July 9, 1996
    Assignee: Coatex S.A.
    Inventors: Jean-Bernard Egraz, Jacques Mongoin, Georges Ravet
  • Patent number: 5474702
    Abstract: A stable aqueous zeolite suspension containing, as stabilizing agent, a copolymer comprising units of (i) at least one acrylic monomer having a carboxylic acid group, (ii) at least one acrylic and/or vinyl monomer not having a carboxylic acid group, and (iii) at least one oxyalkylated monomer having ethylenic unsaturation, and terminated by a fatty hydrophobic chain having 12-40 C atoms.
    Type: Grant
    Filed: December 8, 1994
    Date of Patent: December 12, 1995
    Assignee: Coatex, S.A.
    Inventors: Jean-Bernard Egraz, Henri Grondin, Jean-Marc Suau
  • Patent number: 5464895
    Abstract: A dispersing agent for use in a thermosetting composition, a thermosetting composition containing said dispersing agent, and application thereof to thermosetting composition having no yield point. The dispersing agent acting on mineral fillers and used in filled acrylic or polyester resin-based thermosetting compositions belongs to the family of organophosphates corresponding to the general formula: ##STR1## where: A is a branched or unbranched polyaryl group,x and y are whole numbers between 0 and 100 such that x+y is a whole number greater than 40 but not greater than 100, ##STR2## B and E are independently a branched or unbranched polyaryl group, or an alkyl, aryl, arylalkyl, alkylaryl, alkanoyl, or amine radical, and in B and E, and R.sub.1 and R.sub.2 may be identical or different, x1, y1, x2 and y2 are whole numbers, and the sums x1+y1 and x2+y2 are not greater than 100.
    Type: Grant
    Filed: September 29, 1994
    Date of Patent: November 7, 1995
    Assignee: Coatex, S.A.
    Inventors: Pierre Blanchard, Jean-Bernard Egraz, Georges Ravet
  • Patent number: 5432238
    Abstract: A grinding agent containing polymers and/or copolymers partially neutralized by magnesium, for aqueous suspensions of mineral substances to be used in pigmentary applications is disclosed.A grinding agent composed of polymers and/or copolymers having a specific viscosity of between 0.3 and 0.8 and obtained by treatment, using one or several solvents, of a polymer and/or copolymer resulting from polymerization and/or copolymerization of acrylic and/or vinyl monomers comprising acid groups whose active acid sites are partially or completely neutralized to a degree of neutralization of 40 to 60%, including terminals, of the active acid sites using a neutralizing agent containing magnesium ions, and a degree of neutralization reaching 60% using a neutralizing agent containing sodium ions is disclosed.
    Type: Grant
    Filed: November 10, 1992
    Date of Patent: July 11, 1995
    Assignee: Coatex S.A.
    Inventors: Jean-Bernard Egraz, Jacques Mongoin, Georges Ravet
  • Patent number: 5432239
    Abstract: A grinding agent containing polymers and/or copolymers partially neutralized by magnesium, for aqueous suspensions of mineral substances to be used in pigmentary applications is disclosed.A grinding agent composed of polymers and/or copolymers obtained by polymerization and/or copolymerization of acrylic and/or vinyl monomers containing acid groups, and in which the active acid sites are completely or partially neutralized to a degree of 40% to 60%, including terminals, using a neutralizing agent containing magnesium ions, and to a degree of up to 60% using a neutralizing agent containing monovalent ions is disclosed.A procedure for grinding in an aqueous suspension using said agent, as well as the aqueous suspensions produced using said procedure and their applications to the fields of weight fillers, paper coating, paints, and plastics is also disclosed.
    Type: Grant
    Filed: November 10, 1992
    Date of Patent: July 11, 1995
    Assignee: Coatex S.A.
    Inventors: Jean-Bernard Egraz, Jacques Mongoin, Georges Ravet
  • Patent number: 5423999
    Abstract: A stable aqueous zeolite suspension containing, as stabilizing agent, a copolymer comprising units of (i) at least one acrylic monomer having a carboxylic acid group, (ii) at least one acrylic and/or vinyl monomer not having a carboxylic acid group, and (iii) at least one oxyalkylated monomer having ethylenic unsaturation, and terminated by a fatty hydrophobic chain having 12-40 C atoms.
    Type: Grant
    Filed: June 29, 1993
    Date of Patent: June 13, 1995
    Assignee: Coatex S.A.
    Inventors: Jean-Bernard Egraz, Henri Grondin, Jean-Marc Suau
  • Patent number: 5412139
    Abstract: A dispersing agent for use in a thermosetting composition, a thermosetting composition containing said dispersing agent, and application thereof to thermosetting composition having no yield point. The dispersing agent acting on mineral fillers and used in filled acrylic or polyester resin-based thermosetting compositions belongs to the family of organophosphates corresponding to the general formula: ##STR1## where: A is a branched or unbranched polyaryl group,x and y are whole numbers between 0 and 100 such that x+y is a whole number greater than 40 but not greater than 100, ##STR2## B and E are independently a branched or unbranched polyaryl group, or an alkyl, aryl, arylalkyl, alkylaryl, alkanoyl, or amine radical, and in B and E, and R.sub.1 and R.sub.2 may be identical or different, x1, y1, x2 and y2 are whole numbers, and the sums x1+y1 and x2+y2 are not greater than 100.
    Type: Grant
    Filed: January 14, 1992
    Date of Patent: May 2, 1995
    Assignee: Coatex, S.A.
    Inventors: Pierre Blanchard, Jean-Bernard Egraz, Georges Ravet
  • Patent number: 5362415
    Abstract: A copolymer comprised of at least one monomer having ethylenic unsaturation and a carboxylic acid group, optionally at least one monomer having ethylenic unsaturation and not having a carboxylic acid group, at least one oxyalkylated monomer having ethylenic unsaturation and terminated by a fatty hydrophobic chain having at least 26 C atoms, and optionally at least one monomer having at least two sites of ethylenic unsaturation. The copolymer is employed as a modifier of rheological properties, stabilizing agent, and/or an antisedimentation or suspension agent for coarse mineral of organic materials, in applications such as drilling muds, textile printing pies, cosmetics, detergents, plant protection, and paints and coatings.
    Type: Grant
    Filed: October 15, 1993
    Date of Patent: November 8, 1994
    Assignee: Coatex S.A.
    Inventors: Jean-Bernard Egraz, Henri Grondin, Jean-Marc Suau
  • Patent number: 5294693
    Abstract: A copolymer comprised of at least one monomer having ethylenic unsaturation and a carboxylic acid group, optionally at least one monomer having ethylenic unsaturation and not having a carboxylic acid group, at least one oxyalkylated monomer having ethylenic unsaturation and terminated by a fatty hydrophobic chain having at least 26 C atoms, and optionally at least one monomer having at least two sites of ethylenic unsaturation. The copolymer is employed as a modifier of rheological properties, stabilizing agent, and/or an antisedimentation or suspension agent for coarse mineral or organic materials, in applications such as drilling muds, textile printing pies, cosmetics, detergents, plant protection, and paints and coatings.
    Type: Grant
    Filed: June 29, 1993
    Date of Patent: March 15, 1994
    Assignee: Coatex S.A.
    Inventors: Jean-Bernard Egraz, Henri Grondin, Jean-Marc Suau
  • Patent number: 5278248
    Abstract: Water-soluble polymers and/or copolymers possessing enhanced biodegradability, and their applications are disclosed.Acrylic and/or vinyl polymers and/or copolymers containing acid groups, in which 35% to 90% of the active acid sites are neutralized by magnesium ions, the specific viscosity is at most 25, and biodegradability is enhanced. Their decomposition after 36 days is greater than 50% as measured by the modified Sturm test.These polymers can be used in industries as varied as: paper-making, paints, plastics, petroleum, drilling fluids, water treatment, detergents, cosmetics, textiles, inks, leather, grinding and/or splitting of minerals in water.
    Type: Grant
    Filed: November 10, 1992
    Date of Patent: January 11, 1994
    Assignee: Coatex S.A.
    Inventors: Jean-Bernard Egraz, Georges Ravet, Jacky Rousset
  • Patent number: 5066710
    Abstract: An associative thickening copolymer, water-soluble in a neutral or alkaline medium, for charged and/or pigmented, white or colored aqueous compositions is disclosed. The copolymer is composed of (a) at least one monomer with ethylenic unsaturation having at least one carboxylic function, (b) at least one other monomer with ethylenic unsaturation without a carboxylic function, (c) at least one surfactant monomer having at least one urethane function resulting from the reaction of an isocyanate with ethylenic unsaturation with a surfactant compound having a hydroxyl function which is reactive with regard to the --NCO group, wherein said copolymer belongs to the group composed of those which, by definition, placed in aqueous solution with 2% by weight of dry material, brought to a pH of 9 by the addition of ammonia and at a temperature of 20.degree. C., have a Brookfield viscosity at 100 revolutions per minute of at most equal to 220 centipoises.
    Type: Grant
    Filed: March 15, 1990
    Date of Patent: November 19, 1991
    Assignee: Coatex, S.A.
    Inventors: Benoit Simonet, Pierre Fabre, Jacques Laluet, Jean-Bernard Egraz
  • Patent number: 5015711
    Abstract: An associative thickening copolymer, water-soluble in a neutral or alkaline medium, for charged and/or pigmented, white or colored aqueous compositions is disclosed. The copolymer is composed of (a) at least one monomer with ethylenic unsaturation having at least one carboxylic function, (b) at least one other monomer with ethylenic unsaturation without a carboxylic function, (c) at least one surfactant monomer having at least one urethane function resulting from the reaction of an isocyanate with ethylenic unsaturation with a surfactant compound having a hydroxyl function which is reactive with regard to the --NCO group, wherein said copolymer belongs to the group composed of those which, by definition, placed in aqueous solution with 2% by weight of dry material, brought to a pH of 9 by the addition of ammonia and at a temperature of 20.degree. C., have a Brookfield viscosity at 100 revolutions per minute of at most equal to 220 centipoises.
    Type: Grant
    Filed: July 6, 1989
    Date of Patent: May 14, 1991
    Assignee: Coatex S.A.
    Inventors: Benoit Simonet, Pierre Fabre, Jacques Laluet, Jean-Bernard Egraz
  • Patent number: 4782120
    Abstract: Non-polluting thinning adjuvant for sea-water and/or fresh-water based drilling muds.Non-polluting thinning adjuvant for sea-water and/or fresh-water based drilling muds, with the aim to maintain their rheological characteristics in the extreme conditions of temperature and pressure which prevail in wells drilled at great depths. This thinning adjuvant is characterized by the fact that it is a hydrosoluble copolymer resulting from the copolymerization of ethylenic acids, acrylamides and ethylenic esters of phosphoric acid.Its general formula is: ##STR1## in which the indices m,n,p -expressed in % in mole- are chosen from the following intervals:0%<m<90%2%<n<100%0%<p<90%and where radicals R.sub.1, R.sub.2 and R.sub.4 are chosen from the group consisting of H and the alkyles, and radical R.sub.3 is chosen from the group consisting of alkylenes and alkylene-oxides and/or polyalkylene oxides.
    Type: Grant
    Filed: April 13, 1987
    Date of Patent: November 1, 1988
    Assignee: Coatex, S.A.
    Inventors: Jacky Rousset, Jean-Bernard Egraz, Gilles Letetour
  • Patent number: 4482606
    Abstract: A microencapsulation of varied substances such as aromatic agents, colorings, inks, chemical reactives, pharmaceutical and phytosanitary products, fireproof products, glues, finely dispersed in an aqueous phase, in order to obtain microcapsules that are simulaneously isodiametrical and with regularized diameters, which consists in placing face to place an aqueous solution of polymers and/or hydrosoluble copolymers including at least one of the chemical functions belonging to the group constituted by the radicles --COOH, --OH, --CONH.sub.2, --COHNR, --CONRR', --NH.sub.2, NHR and --NRR', constituting the material of the capsule containing shell, and a solution of substances to be coated in at least one hydrophobic organic solvent, density close to 1, then submitting the liquid medium thus constituted to a mechanical shearing action corresponding to a shearing coefficient included between 8,000 second.sup.-1 and 70,000 second.sup.-1, while the medium is maintained at a temperature between 15.degree. C. and 85.
    Type: Grant
    Filed: March 9, 1982
    Date of Patent: November 13, 1984
    Assignee: Printex
    Inventors: Hubert Bousquet, Jean Bernard Egraz, Georges Ravet
  • Patent number: 4282140
    Abstract: New medical self-polymerizable sealing cement with an acrylic polymer and/or copolymer base, applicable for prosthetic implants, which is obtained by mixing a liquid phase and a solid phase. The liquid phase, being viscous, forms a collodion of an acrylic polymer and/or copolymer in at least one monomer, while the solid phase is composed of an acrylic polymer and/or copolymer possibly containing a mineral load.The new cement is not dangerous for the patient, due to an absence of monomer exudation and due to a polymerization temperature which is always lower than the mobilization temperature of human fat.
    Type: Grant
    Filed: February 22, 1979
    Date of Patent: August 4, 1981
    Assignee: Societe d'Exploitation des Procedes Coatex
    Inventors: Gilles Bousquet, Jean-Bernard Egraz, Andre Rambert, Georges Ravet