Patents by Inventor Jean-Francois Le Page

Jean-Francois Le Page has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 4201661
    Abstract: Aromatic hydrocarbons of high purity are produced from saturated or unsaturated gasolines and hydrogen in the presence of a new catalyst containing alumina, platinum, at least one metal selected from the group consisting of iridium, rhodium and palladium and at least one metal selected from the group consisting of copper, silver and gold.
    Type: Grant
    Filed: March 26, 1974
    Date of Patent: May 6, 1980
    Assignee: Institut Francais du Petrole
    Inventors: Bernard Juguin, Jean-Francois Le Page, Jean Miquel
  • Patent number: 4199437
    Abstract: Process for steam dealkylation of alkylaromatic hydrocarbons, particularly useful to produce benzene from toluene and to de-alkylate the alkylaromatic hydrocarbons contained in the effluents from catalytic reforming and aromatic production units, wherein the catalyst contains, in addition to an alumina carrier (a) at least one metal selected from ruthenium, rhodium, palladium, osmium, iridium and platinum (b) rhenium and (c) an alkali metal selected from lithium, sodium, potassium, rubidium and cesium.
    Type: Grant
    Filed: February 23, 1979
    Date of Patent: April 22, 1980
    Assignee: Institut Francais du Petrole
    Inventors: Philippe Courty, Jean-Francois Le Page, Andre Sugier, Jean Cosyns
  • Patent number: 4197185
    Abstract: Process for producing butane and gasoline of high isooctane content, from a C.sub.4 olefin cut issued from a steam cracking unit, comprising the steps of:polymerizing at least 90% of the isobutene of the cut mainly to dimers and trimers thereof,hydrogenating the resulting polymerization mixture to normal butane, isooctane and isododecane,supplying the effluent from the hydrogenation unit to a separation zone to recover a gaseous fraction and a liquid mixture, andfractionating the liquid mixture to separate gasoline of high isooctane content, a C.sub.3.sup.- fraction and a butane fraction which is recycled to the steam cracking unit.
    Type: Grant
    Filed: August 25, 1978
    Date of Patent: April 8, 1980
    Assignee: Institut Francais du Petrole
    Inventors: Jean-Francois Le Page, Jean Cosyns, Jean Miquel, Bernard Juguin
  • Patent number: 4191632
    Abstract: A process for producing benzene is provided which comprises the steps of subjecting a charge rich in alkylaromatic hydrocarbons and containing 2-20% by weight paraffinic and/or naphthenic hydrocarbons, in a first catalytic zone, to a hydrotreatment in the presence of a catalyst mixture containing a selective mordenite catalyst and a reforming catalyst, then subjecting at least a portion of the resultant effluent to thermal or catalytic hydrodealkylation in a second zone, and separating and recovering benzene from the effluent from the second zone.
    Type: Grant
    Filed: April 6, 1978
    Date of Patent: March 4, 1980
    Assignee: Institut Francais du Petrole
    Inventors: Jean Cosyns, Christian Marcilly, Jean Miquel, Jean-Francois Le Page
  • Patent number: 4180453
    Abstract: A fresh charge containing aromatic hydrocarbons is hydrotreated in admixture with a recycle fraction, in the presence of a bifunctional catalyst, a portion of the effluent is subjected to steam-cracking, thereby recovering a gas oil fraction which is subjected to hydrogenation and forms said recycle fraction. The mixture of recycle fraction and charge is advantageously treated with hydrogen in the presence of a monofunctional catalyst to hydrogenate olefins, at a lower temperature than the hydrotreatment, and then passed to the hydrotreatment zone.
    Type: Grant
    Filed: February 10, 1978
    Date of Patent: December 25, 1979
    Assignee: Institut Francais du Petrole
    Inventors: Jean-Pierre Franck, Edouard Freund, Jean-Francois Le Page, Jean Miquel
  • Patent number: 4140621
    Abstract: A saturated hydrocarbon charge containing both butane and isobutane is subjected to selective hydrogenolysis in the presence of a catalyst comprising a specific carrier and 0.1 - 10 % b.w. of rhodium. Butane is thus selectively converted to ethane and propane, while isobutane is preserved or formed and can be recovered from the reaction product.
    Type: Grant
    Filed: September 20, 1977
    Date of Patent: February 20, 1979
    Assignee: Institut Francais du Petrole
    Inventors: Jean-Pierre Franck, Jean-Francois Le Page, Germain Martino, Jean Miquel
  • Patent number: 4133841
    Abstract: This process for upgrading effluents from syntheses of the Fischer-Tropsch type comprises several steps applied to the three cuts obtained from these effluents, i.e. a "light fraction", a "light oil" and a "decanted oil". The products are mainly gasoline, kerosene and gasoil cuts.
    Type: Grant
    Filed: March 25, 1977
    Date of Patent: January 9, 1979
    Assignee: Institut Francais du Petrole
    Inventors: Jean Cosyns, Yves Chauvin, Bernard Juguin, Jean-Francois Le Page, Jean Miquel
  • Patent number: 4132745
    Abstract: Process for isomerizing 1-butene to 2-butene by contacting 1-butene, at a temperature from 50 to 140.degree. C, in the presence of hydrogen, with an isomerization catalyst containing a noble metal from group VIII of the periodic classification of elements, which catalyst was previously contacted with a sulfur compound at a temperature from 50 to 400.degree. C and then with hydrogen at a temperature of at least 50.degree. C.
    Type: Grant
    Filed: February 21, 1978
    Date of Patent: January 2, 1979
    Assignee: Institut Francais du Petrole
    Inventors: Pierre Amigues, Jean Gaillard, Jean-Francois Le Page, Robert Stern
  • Patent number: 4125566
    Abstract: This process applies to effluents from syntheses of the Fischer-Tropsch type; it comprises several treatments applied to the three cuts obtained from these effluents, i.e. a "light fraction", a "light oil" and a "decanted oil". These treatments comprise such steps as distillation, polymerization, alkylation, hydrotreatment, cracking-decarboxylation, isomerization and hydro reforming. The products are mainly gasoline, kerosene and gasoil.
    Type: Grant
    Filed: August 17, 1977
    Date of Patent: November 14, 1978
    Assignee: Institut Francais du Petrole
    Inventors: Chan Trin Dinh, Jean-Francois Le Page, Jean Cosyns, Germain Martino, Jean Miquel
  • Patent number: 4092371
    Abstract: A catalyst useful for the alkylation of aromatic hydrocarbons is produced by reacting a compound of the formula AlX.sub.y R.sub.(3 - y), where X is halogen, R is a hydrocarbon radical and y is 1, 3/2, 2 or 3, except 3 when X is fluorine, with a carrier comprising aluminum oxide and boron oxide.
    Type: Grant
    Filed: July 7, 1977
    Date of Patent: May 30, 1978
    Assignee: Institut Francais du Petrole
    Inventors: Jean-Pierre Franck, Jean-Francois Le Page
  • Patent number: 4062805
    Abstract: A catalyst useful for the alkylation of aromatic hydrocarbons is produced by reacting a compound of the formula AlX.sub.y R.sub.(3 - y) , where X is halogen, R is a hydrocarbon radical and y is 1, 3/2, or 2, except, with a carrier comprising aluminum oxide and boron oxide.
    Type: Grant
    Filed: June 24, 1976
    Date of Patent: December 13, 1977
    Assignee: Institut Francais du Petrole
    Inventors: Jean-Pierre Franck, Jean-Francois Le Page
  • Patent number: 4058450
    Abstract: Process for producing aromatic hydrocarbons from gasolines substantially free of mono- and diolefins, comprising an aromizing step in the presence of a catalyst at a temperature from 400.degree. to 600.degree. C under a pressure from 1 to 30 kg/cm.sup.2 followed with the separation of an aromatic cut and of an alkylaromatic cut and a step of hydrodealkylating said alkylaromatic cut by means of hydrogen recovered from the aromizing step, in the presence of a catalyst, at a temperature from 400.degree. to 650.degree. C, under a pressure substantially equal or lower than that of the aromizing step.
    Type: Grant
    Filed: March 22, 1976
    Date of Patent: November 15, 1977
    Assignee: Institut Francais du Petrole
    Inventors: Jean-Francois Le Page, Bernard Juguin, Jean Miquel
  • Patent number: 4043944
    Abstract: New catalyst comprising a carrier such for example as alumina, platinum, at least one metal selected from iridium, tungsten and ruthenium, cobalt, at least one metal selected from the group consisting of copper, manganese, silver and gold, and at least one halogen such for example as chlorine.
    Type: Grant
    Filed: October 7, 1975
    Date of Patent: August 23, 1977
    Assignee: Societe Francaise des Produits pour Catalyse
    Inventors: Bernard Juguin, Jean Cosyns, Jean-Francois Le Page, Jean Miquel
  • Patent number: 3992468
    Abstract: Process for hydrodealkylating alkylaromatic hydrocarbons using a catalyst comprising at least two metals deposited on a carrier, a first of these two metals being selected either from the group consisting of cobalt, ruthenium, osmium, palladium, rhodium, iridium and platinum or from the group consisting of chromium, molybdenum, tungsten and manganese, and the second of these two metals being selected from zinc, cadmium, gallium, indium, thallium, manganese, copper, silver, gold, yttrium, titanium, niobium, tentalum, chromium, molybdenum, tungsten, rhenium, germanium, tin and lead.
    Type: Grant
    Filed: February 24, 1975
    Date of Patent: November 16, 1976
    Assignee: Institut Francais du Petrole, des Carburants et Lubrifiants et Entreprise de Recherches et d'Activities Petrolieres Elf
    Inventors: Jean Cosyns, Bernard Juguin, Jean-Francois Le Page, Jean Miquel
  • Patent number: 3980721
    Abstract: New catalyst, particularly suitable for dehydrogenating saturated hydrocarbons, which contains alumina, at least one metal selected from molybdenum, tungsten and rhenium and at least one metal selected from gallium, indium, thallium, germanium, tin, lead, antimony and bismuth, said catalyst having a specific surface from 20 to 150 m.sup.2 /g and a neutralization heat by ammonia absorption at 320.degree.C under 300 mm Hg lower than 10 calories per gram.
    Type: Grant
    Filed: April 3, 1975
    Date of Patent: September 14, 1976
    Assignee: Institut Francaise du Petrole, des Carburants et Lubrifiants et Entreprise de Recherches et d'Activites Petrolieres Elf
    Inventors: Bernard Juguin, Jean-Francois Le Page
  • Patent number: 3975302
    Abstract: Process for manufacturing a supported catalyst whose active phase contains mainly molybdenum and iron by impregnating a carrier with an aqueous solution of alkanolamine and a complex of the active phase elements, drying and thereafter roasting the impregnated carrier.
    Type: Grant
    Filed: September 3, 1974
    Date of Patent: August 17, 1976
    Assignee: Institut Francais du Petrole, des Carburants et Lubrifiants et Entreprise de Recherches et d'Activities Petrolieres Elf
    Inventors: Philippe Courty, Andre Sugier, Jean-Francois Le Page
  • Patent number: 3966833
    Abstract: Process for hydrodealkylating an alkylaromatic hydrocarbon charge at a temperature from 400.degree. to 650.degree.C under a pressure from 1 to 30 kg/cm.sup.2 at a space velocity from 1 to 10 by reacting said charge with hydrogen in a molar proportion with respect to the effluent of the reactor in the range from 1 to 10, in the presence of a catalyst containing alumina and at least one metal selected from ruthenium, osmium, palladium, rhodium, iridium, platinum and manganese in an amount from 0.05 to 5 % of the catalyst, said catalyst having a specific surface from 1 to 100 m.sup.2 /g., a total pore volume of 0.2-0.8 g/cc and a heat of neutralization lower than 10 calories per gram are measured by ammonia adsorption at 320.degree. C. under 300 mm Hg.
    Type: Grant
    Filed: December 13, 1974
    Date of Patent: June 29, 1976
    Assignee: Institut Francaise du Petrole, de Carburants et Lubrifiants
    Inventors: Jean Cosyns, Bernard Juguin, Jean-Francois Le Page, Jean Miquel
  • Patent number: 3954601
    Abstract: Aromatic hydrocarbons are hydrogenated in the presence of a catalyst obtained by admixing an aluminous carrier with a group VIII noble metal compound and a reducing agent of the formula Al X.sub.y R.sub.3-y where y is 1, 3/2 or 2, X is halogen and R is a monovalent hydrocarbon radical.
    Type: Grant
    Filed: August 7, 1974
    Date of Patent: May 4, 1976
    Assignee: Institut Francais du Petrole
    Inventors: Jean Cosyns, Germain Martino, Jean-Francois Le Page
  • Patent number: 3951648
    Abstract: Process for recovering palladium from a catalyst having a palladium content of less than 5 %, comprising contacting said catalyst with a gaseous chlorinated organic compound at a temperature sufficient for vaporizing the palladium and cooling the gaseous phase so as to recover the formed chlorinated palladium derivative.
    Type: Grant
    Filed: March 27, 1974
    Date of Patent: April 20, 1976
    Assignee: Institut Francais du Petrole
    Inventors: Robert Stern, Jean-Pierre Franck, Jean-Francois Le Page