Abstract: The invention concerns a microporous diaphragm obtainable by filtering through a porous support, an aqueous dispersion free of asbestos fibres and titanate fibres, comprising organic fibres, at least a binding agent selected among halogenated polymers, at least a pore-forming agent and mineral particles with non-fibrous structure. The invention also concerns a combination comprising said diaphragm and a fibrous mat obtainable by filtration deposit through a porous support of a dispersion comprising fibres whereof part is electrically conductive, at least a binding agent selected among halogenated polymers, at least an electrolytic agent, at least a pore-forming agent. The invention further concerns the preparation of the diaphragm and the combination, and the use thereof to obtain an alkali metal hydroxide solution by electrolysis of aqueous alkali metal halide solutions.

Abstract: Microporous diaphragms adapted for wet-consolidation with composite cathodes for use in electrolytic cells, e.g., chlorine/soda electrolysis cells, comprise a sintered, fluoropolymer microconsolidated asbestos-based microporous fibrous sheet material, such sheet material including from 3% to 35% by weight of fluoropolymer binder, from 1% to 50% by weight of a uniformly distributed gel of an oxohydroxide of at least one metal of Groups IVA, IVB, VB and VIB of the Periodic Table or of the lanthanide or actinide series thereof, and from 20% to 95% by weight of fibers, at least 1% by weight of such fibers being asbestos fibers.

Abstract: Microporous diaphragms adapted for wet-consolidation with composite cathodes for use in electrolytic cells, e.g., chlorine/soda electrolysis cells, comprise a sintered, fluoropolymer microconsolidated asbestos-based microporous fibrous sheet material, such sheet material including from 3% to 35% by weight of fluoropolymer binder, from 1% to 50% by weight of a uniformly distributed gel of an oxohydroxide of at least one metal of Groups IVA, IVB, VB and VIB of the Periodic Table or of the lanthanide or actinide series thereof, and from 20% to 95% by weight of fibers, at least 1% by weight of such fibers being asbestos fibers.

Abstract: Disclosed are electroactivated shaped articles, well adapted as cathode elements and composites, especially for electrolytic cells for the electrolysis of sodium chloride. The articles include a mass of fibrous material consolidated in a matrix of fluoropolymer binder wherein at least a portion of the fibers are electrically conductive. The shaped articles have a resistivity of less than 0.4 ohm cm, and have at least one electrocatalytically active agent uniformly dispersed therethrough. The electrocatalytically active agent(s) is (are) selected from Raney metals or Raney alloys depleted in fugitive metal values.

Abstract: Heat-set woven diaphragms based on polyvinyl chloride, well adapted for the electrolysis of hydrochloric acid, comprise:(a) a combination of warp threads and weft threads woven into a cloth weave and having a number of crossings per square centimeter ranging from 270 to 350;(b) warp threads and the weft threads which comprise a mixture of atactic polyvinyl chloride and superchlorinated polyvinyl chloride;(c) an average thickness of from 0.5 to 0.7 mm; and(d) high creasing resistance.