Abstract: The invention relates to a process for the co-production of alkyl mercaptan and of dialkyl disulfide, comprising the following successive steps: a) reaction of a C1-C4 alcohol in the presence of hydrogen sulfide (H2S) to form a stream (M) comprising an alkyl mercaptan, water, and possibly unreacted hydrogen sulfide, b) purification of the stream (M) to obtain a stream (N) enriched in alkyl mercaptan, c) recovery of a first portion of the stream (N) including the alkyl mercaptan purified in step b), d) oxidation with sulfur of the second portion of the stream (N) of alkyl mercaptan, to form a stream (O) comprising a dialkyl disulfide, hydrogen sulfide, and possibly unreacted alkyl mercaptan, e) purification of the stream (O) to separate, on the one hand, the enriched dialkyl disulfide and, on the other hand, the hydrogen sulfide and possibly the alkyl mercaptan that has not reacted in step d), f) recycling of the hydrogen sulfide and possibly of the alkyl mercaptan isolated in step e) into the stream (M) ob

Abstract: The present invention relates to a process for drying methyl mercaptan, notably by azeotropic distillation, comprising the following steps: 1) a stream (A) comprising methyl mercaptan and water is introduced into a distillation column (1); 2) said stream (A) is distilled in said column (1); 3) the distillate (B) is recovered in gaseous form, preferably at the top of the column; 4) the distillate (B) is condensed, preferably in a condenser (2), so as to obtain a condensate (C) in liquid form; 5) said condensate (C) is separated, preferably using a decanter (3), so as to obtain two separate liquid phases: an aqueous phase (D); and an organic phase (E) comprising methyl mercaptan; 6) all or part of the organic phase (E) is optionally introduced into the distillation column (1) as reflux; and 7) a stream (F) comprising the dried methyl mercaptan is recovered, preferably at the bottom of column (1).

Abstract: The present invention relates to a process for producing methyl mercaptan, comprising the following steps: A) methanol is reacted with hydrogen sulfide to form a stream (M), preferably in gaseous form, comprising methyl mercaptan, unreacted H2S and possibly sulfur byproducts; B) optionally, said stream (M) is condensed; C) at least one step of purification of said stream (M) is performed to obtain a stream enriched in methyl mercaptan; D) the gaseous vents resulting from said at least one purification step are recovered, said gaseous vents comprising at least one sulfur compound, preferably H2S; E) a gas-liquid extraction of said at least one sulfur compound, preferably H2S, is performed with liquid methanol so as to obtain a liquid methanol enriched in sulfur compound(s), preferably in H2S; and F) optionally, said enriched methanol is used as reagent for the reaction of step A).

Abstract: The invention relates to a process for the co-production of alkyl mercaptan and of dialkyl disulfide, comprising the following successive steps: a) reaction of a C1-C4 alcohol in the presence of hydrogen sulfide (H2S) to form a stream (M) comprising an alkyl mercaptan, water, and possibly unreacted hydrogen sulfide, b) purification of the stream (M) to obtain a stream (N) enriched in alkyl mercaptan, c) recovery of a first portion of the stream (N) including the alkyl mercaptan purified in step b), d) oxidation with sulfur of the second portion of the stream (N) of alkyl mercaptan, to form a stream (O) comprising a dialkyl disulfide, hydrogen sulfide, and possibly unreacted alkyl mercaptan, e) purification of the stream (O) to separate, on the one hand, the enriched dialkyl disulfide and, on the other hand, the hydrogen sulfide and possibly the alkyl mercaptan that has not reacted in step d), f) recycling of the hydrogen sulfide and possibly of the alkyl mercaptan isolated in step e) into the stream (M) ob

Abstract: The invention relates to a process for the co-production of methyl mercaptan and of dimethyl disulfide, comprising the following successive steps: a) reaction of at least one carbon oxide in the presence of hydrogen sulfide (H2S) and hydrogen to form a stream (M) comprising methyl mercaptan, water, and possibly unreacted hydrogen sulfide, b) purification of the stream (M) to obtain a stream (N) enriched in methyl mercaptan and a stream containing the uncondensable compounds (Muncond), c) optional recycling of the stream of uncondensable compounds (Muncond) obtained from step b) into step a), d) recovery of a first portion of the stream (N) including methyl mercaptan purified in step b), e) oxidation with sulfur of the second portion of the stream (N) of methyl mercaptan, to form a stream (O) comprising dimethyl disulfide, hydrogen sulfide, and possibly unreacted methyl mercaptan, f) purification of the stream (O) to separate, on the one hand, the enriched dimethyl disulfide and, on the other hand, the hydr

Abstract: The present invention relates to a method for preparing methyl mercaptan, in batches or continuously, preferably continuously, said method including at least the following steps: a) reacting at least one hydrocarbon feedstock in the presence of hydrogen sulphide (H2S) and optionally sulphur (S) such as to form carbon disulphide (CS2) and hydrogen (H2); b) reacting said carbon disulphide (CS2) by hydrogenation in the presence of said hydrogen (H2) obtained in step a) such as to form methyl mercaptan (CH3SH), hydrogen sulphide (H2S) and possibly hydrogen (H2); c) optionally recirculating said hydrogen sulphide (H2S) formed during step b) to step a); and d) recovering the methyl mercaptan.

Abstract: The present invention relates to a method for preparing methyl mercaptan, in batches or continuously, preferably continuously, said method including at least the following steps: a) reacting at least one hydrocarbon feedstock in the presence of hydrogen sulphide (H2S) and optionally sulphur (S) such as to form carbon disulphide (CS2) and hydrogen (H2); b) reacting said carbon disulphide (CS2) by hydrogenation in the presence of said hydrogen (H2) obtained in step a) such as to form methyl mercaptan (CH3SH), hydrogen sulphide (H2S) and possibly hydrogen (H2); c) optionally recirculating said hydrogen sulphide (H2S) formed during step b) to step a); and d) recovering the methyl mercaptan.

Abstract: The present invention relates to a method for preparing methyl mercaptan, in batches or continuously, preferably continuously, said method including at least the following steps: a) reacting at least one hydrocarbon feedstock in the presence of hydrogen sulphide (H2S) and optionally sulphur (S) such as to form carbon disulphide (CS2) and hydrogen (H2); b) reacting said carbon disulphide (CS2) by hydrogenation in the presence of said hydrogen (H2) obtained in step a) such as to form methyl mercaptan (CH3SH), hydrogen sulphide (H2S) and possibly hydrogen (H2); c) optionally recirculating said hydrogen sulphide (H2S) formed during step b) to step a); and d) recovering the methyl mercaptan.

Abstract: The present invention relates to a method for preparing dimethyl disulphide, in batches or continuously, preferably continuously, said method including at least the following steps: a) reacting at least one hydrocarbon feedstock in the presence of hydrogen sulphide (H2S) and optionally sulphur (S) such as to form carbon disulphide (CS2) and hydrogen (H2); b) reacting said carbon disulphide (CS2) by hydrogenation in the presence of said hydrogen (H2) obtained in step a), such as to form methyl mercaptan (CH3SH), hydrogen sulphide (H2S) and optionally hydrogen (H2); c) optionally, but preferably, recirculating said hydrogen sulphide (H2S) formed in step b) to step a); d) reacting the methyl mercaptan formed in step b) with sulphur such as to form dimethyl disulphide and hydrogen sulphide; e) optionally recirculating the hydrogen sulphide formed during step d) to step a); and f) recovering the dimethyl disulphide.

Abstract: In one embodiment, the present invention may be implemented as a software platform, data model and method to build robotic managers (RM). A robotic manager is, in one embodiment, a computer system that automates tasks performed by a human manager. A MAP RM has a skillset which may be divided into two categories: 1) basic skills such as visual recognition, voice command processing, data visualization, unstructured search, and 2) expert skills such as finance, risk management, cyber security, and information technology. Expert skills may be categorized by domain.

Abstract: The present invention relates to a method for preparing methyl mercaptan, in batches or continuously, preferably continuously, said method including at least the following steps: a) reacting at least one hydrocarbon feedstock in the presence of hydrogen sulphide (H2S) and optionally sulphur (S) such as to form carbon disulphide (CS2) and hydrogen (H2); b) reacting said carbon disulphide (CS2) by hydrogenation in the presence of said hydrogen (H2) obtained in step a) such as to form methyl mercaptan (CH3SH), hydrogen sulphide (H2S) and possibly hydrogen (H2); c) optionally recirculating said hydrogen sulphide (H2S) formed during step b) to step a); and d) recovering the methyl mercaptan.

Abstract: The present invention relates to a method for preparing dimethyl disulphide, in batches or continuously, preferably continuously, said method including at least the following steps: a) reacting at least one hydrocarbon feedstock in the presence of hydrogen sulphide (H2S) and optionally sulphur (S) such as to form carbon disulphide (CS2) and hydrogen (H2); b) reacting said carbon disulphide (CS2) by hydrogenation in the presence of said hydrogen (H2) obtained in step a), such as to form methyl mercaptan (CH3SH), hydrogen sulphide (H2S) and optionally hydrogen (H2); c) optionally, but preferably, recirculating said hydrogen sulphide (H2S) formed in step b) to step a); d) reacting the methyl mercaptan formed in step b) with sulphur such as to form dimethyl disulphide and hydrogen sulphide; e) optionally recirculating the hydrogen sulphide formed during step d) to step a); and f) recovering the dimethyl disulphide.

Abstract: The present disclosure relates to a process for obtaining dialkyl disulphides from alkyl mercaptan and from sulphur, in which a reaction intermediate present in the final disulphide is decomposed at the end of synthesis. This operation makes it possible to avoid the degradation of said reaction intermediate over time, which is responsible for the decrease in purity of the dialkyl disulphide.

Abstract: The present disclosure relates to a process for obtaining dialkyl disulphides from alkyl mercaptan and from sulphur, in which a reaction intermediate present in the final disulphide is decomposed at the end of synthesis. This operation makes it possible to avoid the degradation of said reaction intermediate over time, which is responsible for the decrease in purity of the dialkyl disulphide.