Abstract: The invention provides shrinkable films comprised of polyesters comprising certain combinations of glycols and diacids in particular proportions. These polyesters afford certain advantageous properties in the resulting shrinkable films, and thus are suitable as drop-in replacements for commercially available shrink films made using poly(vinyl chloride).

Abstract: The invention provides shrinkable films comprised of polyesters comprising certain combinations of glycols and diacids in particular proportions. These polyesters afford certain advantageous properties in the resulting shrinkable films, and thus are suitable as drop-in replacements for commercially available shrink films made using poly(vinyl chloride).

Abstract: The present invention is directed to films that are deposited with foamable inks or coatings. One purpose is to facilitate their separation for recycling purposes. The films are particularly useful as packaging labels. The inks/coatings are designed so that foaming is activated when the film is in the hot-wash stage of a typical recycle process. This provides added buoyancy to the film allowing it to float to the surface and be removed, thereby significantly improving the efficiency of the recycle process. A feature of the invention is that, prior to this hot wash, the inks/coatings remain substantially unfoamed and thereby do not negatively affect the aesthetics of labeled package. The foamable inks/coatings can be used with any type of film.

Abstract: The present invention is directed to films that are deposited with foamable inks or coatings. One purpose is to facilitate their separation for recycling purposes. The films are particularly useful as packaging labels. The inks/coatings are designed so that foaming is activated when the film is in the hot-wash stage of a typical recycle process. This provides added buoyancy to the film allowing it to float to the surface and be removed, thereby significantly improving the efficiency of the recycle process. A feature of the invention is that, prior to this hot wash, the inks/coatings remain substantially unfoamed and thereby do not negatively affect the aesthetics of labeled package. The foamable inks/coatings can be used with any type of film.

Abstract: The present invention comprises the use of sulfite additives to reduce discoloration of L-ascorbic acid produced from acid or aqueous solutions of 2-keto-L-gulonic acid. In one aspect, the present invention comprises a continuous process for producing L-ascorbic acid from an aqueous solution of 2-keto-L-gulonic acid. The use of sulfite additives reduces product stream color and improves product recovery by binding to high molecular weight reaction by-products. In a continuous process, the reaction stream is separated from residual sulfite and sulfite-bound by-products to produce a product stream enriched in aqueous ascorbic acid for recovery, and an enriched 2-keto-L-gulonic acid stream which is recycled to the reactor. The in situ use of sulfite additives during the reaction increases the overall yield of L-ascorbic acid, with no loss in selectivity of the synthesis.

Abstract: The present invention describes the preparation of multifunctional imine-esters and their application as novel crosslinkers for surface coatings. The imine-esters are prepared by reacting a di- or tri-aldehyde with an &agr;-aminoester such as glycine ethyl ester hydrochloride. These novel crosslinkers may then be formulated with polyesters containing maleic anhydride residues to give enamel coating formulations. The enamels may be cured by a 1,3-dipolar cycloaddition mechanism to give carbon-carbon bonds and cyclic structure. Coatings thus prepared have advantages of low toxicity, no formaldehyde evolution, and improved performance.

Abstract: The present invention provides methods and an apparatus for the manufacture of an L-ascorbic acid product in high yield by direct conversion of an aqueous solution containing 2-keto-L-gulonic acid by contact with an acid catalyst or under thermal self-catalyzed conditions at a conversion level that maximizes the formation of L-ascorbic acid and minimizes decomposition of the L-ascorbic acid thus formed. The separation process for L-ascorbic acid and KLG is operated in such a way that an efficient separation process allows the majority of the KLG to be recycled for further conversion. The product stream from the separation process is then subjected to a recovery step to obtain crystalline L-ascorbic acid product.

Abstract: The present invention comprises the use of sulfite additives to reduce discoloration of L-ascorbic acid produced from acid or aqueous solutions of 2-keto-L-gulonic acid. In one aspect, the present invention comprises a continuous process for producing L-ascorbic acid from an aqueous solution of 2-keto-L-gulonic acid. The use of sulfite additives reduces product stream color and improves product recovery by binding to high molecular weight reaction by-products. In a continuous process, the reaction stream is separated from residual sulfite and sulfite-bound by-products products to produce a product stream enriched in aqueous ascorbic acid for recovery, and an enriched 2-keto-L-gulonic acid stream which is recycled to the reactor. The in situ use of sulfite additives during the reaction increases the overall yield of L-ascorbic ascorbic acid, with no loss in selectivity of the synthesis.

Abstract: The present invention describes the preparation of multifunctional imine-esters and their application as novel crosslinkers for surface coatings. The imine-esters are prepared by reacting a di- or tri-aldehyde with an &agr;-aminoester such as glycine ethyl ester hydrochloride. These novel crosslinkers may then be formulated with polyesters containing maleic anhydride residues to give enamel coating formulations. The enamels may be cured by a 1,3-dipolar cycloaddition mechanism to give carbon-carbon bonds and cyclic structure. Coatings thus prepared have advantages of low toxicity, no formaldehyde evolution, and improved performance.