Publication number: 20220275275
Abstract: According to some embodiments, an apparatus and method are provided comprising: an enclosure defining a cavity within the enclosure, the cavity comprising a depth dimension; at least one LED chip; a layer comprising a blend of an encapsulant material and phosphor composition, the layer overlaying the at least one LED chip and disposed within the cavity; the phosphor composition comprising a yellow-green phosphor and a Mn4+ doped complex fluoride phosphor of formula I, Ax[MFy]:Mn4+ (I) where A is Li, Na, K, Rb, Cs, NR4 or a combination thereof; M is Si, Ge, Sn, Ti, Zr, Al, Ga, In, Sc, Hf, Y, La, Nb, Ta, Bi, Gd, or a combination thereof; R is H, lower alkyl, or a combination thereof; x is the absolute value of the charge of the [Mfy] ion; and y is 5, 6, or 7; wherein the Mn4+ doped complex fluoride phosphor of formula I comprises a d50 particle size of from about 1 micrometers to about 10 micrometers, and the LED lighting apparatus, when activated, emits visible light comprising a correlated color temperature (
Type:
Application
Filed:
July 30, 2020
Publication date:
September 1, 2022
Inventors:
Jenna Marie Baldesare, Fangming Du, Ashfaqul Islam Chowdhury, Rick Dean Dureiko, Clark Nelson
Patent number: 10793773
Abstract: A process for preparing a Mn+4 doped phosphor of formula I includes gradually adding a first solution comprising a source of M and HF and a second solution comprising a source of Mn to a reactor, in the presence of a source of A and an anion selected from phosphate, sulfate, acetate, and combinations thereof, to form a product liquor comprising the Mn+4 doped phosphor. The process also includes gradually discharging the product liquor from the reactor while volume of the product liquor in the reactor remains constant. A is Li, Na, K, Rb, Cs, or a combination thereof; M is Si, Ge, Sn, Ti, Zr, Al, Ga, In, Sc, Y, La, Nb, Ta, Bi, Gd, or a combination thereof; x is the absolute value of the charge of the [MFy] ion; and y is 5, 6 or 7.
Type:
Grant
Filed:
September 20, 2017
Date of Patent:
October 6, 2020
Assignee:
CURRENT LIGHTING SOLUTIONS, LLC
Inventors:
Fangming Du, James Edward Murphy, Srinivas Prasad Sista, Clark David Nelson, Jenna Marie Baldesare
Publication number: 20180265778
Abstract: A process for preparing a Mn+4 doped phosphor of formula I includes gradually adding a first solution comprising a source of M and HF and a second solution comprising a source of Mn to a reactor, in the presence of a source of A and an anion selected from phosphate, sulfate, acetate, and combinations thereof, to form a product liquor comprising the Mn+4 doped phosphor. The process also includes gradually discharging the product liquor from the reactor while volume of the product liquor in the reactor remains constant. A is Li, Na, K, Rb, Cs, or a combination thereof; M is Si, Ge, Sn, Ti, Zr, Al, Ga, In, Sc, Y, La, Nb, Ta, Bi, Gd, or a combination thereof; x is the absolute value of the charge of the [MFy] ion; and y is 5, 6 or 7.
Type:
Application
Filed:
September 20, 2017
Publication date:
September 20, 2018
Inventors:
Fangming DU, James Edward MURPHY, Srinivas Prasad SISTA, Clark David NELSON, Jenna Marie BALDESARE