Abstract: A bimodal lithium transition metal oxide based powder mixture comprising a first and a second lithium transition metal oxide based powder. The first powder comprises a material A having a layered crystal structure comprising the elements Li, a transition metal based composition M and oxygen and has a particle size distribution with a span <1.0. The second powder has a monolithic morphology and a general formula Li1+bN?1-bO2, wherein ?0.03?b?0.10, and N?=NixM?yCozEd, wherein 0.30?x?0.92, 0.05?y?0.40, 0.05?z?0.40 and 0?d?0.10, with M? being one or both of Mn or Al, and E being a dopant different from M?. The first powder has an average particle size D50 between 10 and 40 ?m. The second powder has an average particle size D50 between 2 and 4 ?m. The weight ratio of the second powder in the bimodal mixture is between 20 and 60 wt %.

Abstract: A bimodal lithium transition metal oxide based powder mixture comprises a first and a second lithium transition metal oxide based powder. The first powder comprises particles of a material A comprising the elements Li, a transition metal based composition M and oxygen. The first powder has a particle size distribution characterized by a (D90?D10)/D50<1.0. The second powder comprises a material B having single crystal particles, said particles having a general formula Li+bN??bO2, wherein ?0.03?b?0.10, and N?=NixM?yCozEd, wherein 0.30?x?0.92, 0.05?y?0.40, 0.05?z?0.40 and 0?d?0.10, wherein M? is one or both of Mn or Al, and E is a dopant different from M?. The first powder has an average particle size D50 between 10 and 40 ?m. The second powder has a D50 between 2 and 4 ?m. The weight ratio of the second powder in the mixture is between 15 and 60 wt %.

Abstract: The invention relates to an electrochemically active powder comprising particles containing a compound represented by formula AaMm(XO4)n wherein A comprises an alkaline metal; M comprises at least one transition metal and optionally at least one non-transition metal; and X is chosen among S, P and Si; wherein 0<a?3.2; 1?m?2; and 1?n?3; wherein said particles are at least partially coated with a layer comprising a carbonaceous material, said carbonaceous material comprising a highly ordered graphite, wherein said highly ordered graphite has a ratio (I1360/I1580) of a peak intensity (I1360) at 1360 cm?1 to a peak intensity (I1580) at 1580 cm?1, obtained by Raman spectrum analysis, of at most 3.05.

Abstract: The invention provides a positive electrode material for lithium ion batteries, comprising a lithium transition metal-based oxide powder having a general formula Li1+a ((Niz(Ni0.5Mn0.5)y Cox)1-k Ak)1-a O2, wherein A is a dopant, with -0.025?a?0.025, 0.15?x?0.22, 0.42?z?0.52, 1.075<z/y<1.300, x+y+z=1 and k<0.01. Different embodiments provide the following features: the lithium transition metal-based oxide powder has a carbon content ?1000 ppm or even ?400 ppm; the lithium transition metal-based oxide powder has a sulfur content between 0.05 and 1.0 wt%; and a dopant A is Zr, and the powder further comprises up to 1 wt% of a coating comprising a boron compound and WO3.

Abstract: The present invention provides a process is presented for preparing a positive electrode active material for rechargeable lithium ion batteries. The process comprises a sintering step having a short sintering time. This improves the production throughput. More particularly, the process applies to positive electrode active material powders having a general formula Li(1+a)(NixMnyCozMec)(1?a)O2, wherein Me comprises at least one element of the group consisting of Al, Mg, Ti, Zr, W, Nb, B, and Sr, with ?0.1?a?0.1, 0.33?x?0.95, 0?y?0.35, 0<z?0.35, 0?c?0.05, and x+y+z+c=1. The sintering step is performed for a predefined sintering time ts, expressed in hours, and at a predefined temperature Ts, expressed in ° C., such that 0.3?ts?6.0, and 1140+50 Log10 (6/t)?580 x?Ts?1245+50 Log10(6/ts)?580 x.

Abstract: A lithium secondary cell having an operating voltage ?4.35V, comprising a cathode comprising a doped LiCoO2 active material, an anode comprising graphite, and an electrolyte comprising a carbonate-based solvent, a lithium salt and both a succinonitrile (SN) and a lithium bis(oxalato)borate (LiBOB) additive wherein during the discharge at 45° C. from a state of charge (SOC) of 100% at 4.5V to a SOC of 0 at 3V at a C/10 rate the difference of the SOC at 4.42V and 4.35V is at least 7% but less than 14%, and wherein the active material is doped by at least 0.5 mole % of either one or more of Mn, Mg and Ti.

Abstract: A lithium cobalt-based oxide cathode active material powder having: —a primary phase comprising Li, Co, and O, and —a secondary phase comprising LiNaSO4, wherein the content of said LiNaSO4 secondary phase in said powder is of at least 0.4 wt. % and inferior or equal to 1.1 wt. % with respect to a total weight of the cathode active material powder, said cathode active material powder being characterized in that it has a S/Na atomic ratio superior or equal to 0.80 and inferior or equal to 1.20.

Abstract: The invention provides a positive electrode active material for a lithium ion battery, comprising a lithium transition metal-based oxide powder, the powder comprising single crystal monolithic particles comprising Ni and Co and having a general formula Li1+a ((Niz (Ni1/2 Mn1/2)y Cox)1?kAk)1-a 02, wherein A is a dopant, ?0.02<a?0.06, 0.10?x?0.35, 0?z?0.90, x+y+z=1 and k?0.01, the particles having a cobalt concentration gradient wherein the particle surface has a higher Co content than the particle center.

Abstract: A positive electrode active material for a lithium ion battery comprises a lithium transition metal-based oxide powder, the powder comprising single crystal monolithic particles comprising Ni and Co and having a general formula Li1+a (Niz Mny Cox Zrq Ak)1?a O2, wherein A is a dopant, ?0.025?a<0.005, 0.60?z?0.95, y?0.20, 0.05?x?0.20, k?0.20, 0?q?0.10, and x+y+z+k+q=1. The particles have a cobalt concentration gradient wherein the particle surface has a higher Co content than the particle center.

Abstract: A crystalline precursor compound for manufacturing a lithium transition metal based oxide powder usable as an active positive electrode material in lithium-ion batteries, the precursor having a general formula M(O)x(OH)2-x-y(CO3)y, with 0<x?1, 0<y<0.03 and M=NiaMnbCocAd. A being a dopant, with 0.30?a<0.90, 0.10?b<0.40, 0.10?c<0.40, d<0.05 and a+b+c+d=1, the precursor having a Na content less than 200 ppm, a S content less than 250 ppm, the precursor having a specific surface area with a BET value expressed in m2/g and a tap density TD expressed in g/cm3, with a ratio BET/TD>30.104 cm5/g2.

Abstract: A carbonate precursor compound for manufacturing a lithium metal (M)-oxide powder usable as an active positive electrode material in lithium-ion batteries, M comprising 20 to 90 mol % Ni, 10 to 70 mol % Mn and 10 to 40 mol % Co, the precursor further comprising a sodium and sulfur impurity, wherein the sodium to sulfur molar ratio (Na/S) is 0.4<Na/S<2. Thes lithium metal (M)-oxide powder has a particle size distribution with 10 ?m?D50?20 ?m, a specific surface with 0.9?BET?5, the BET being expressed in g/cm2, the powder further comprises a sodium and sulfur impurity, wherein the sum (2*Nawt)+Swt of the sodium (Nawt) and sulfur (Swt) content expressed in wt % is more than 0.4 wt % and less than 1.6 wt %, and wherein the sodium to sulfur molar ratio (Na/S) is 0.4<Na/S<2.

Abstract: A positive electrode active material powder suitable for lithium-ion batteries, comprising lithium transition metal-based oxide particles comprising a core and a surface layer, said surface layer being on top of said core, said particles comprising the elements: Li, a metal M? and oxygen, wherein the metal M? has a formula: M?(NizMnyCox)1?kAk, wherein A is a dopant, 0.55?z?0.89, 0.05?y?0.25, 0.05?x?0.25, x+y+z+k=1, and k?0.01, said positive electrode active material powder having a mean particle size D50 ranging from 3 ?m to 15 ?m and a surface layer thickness ranging from 5 nm to 200 nm. The surface layer comprises aluminum in a content superior or equal to 0.04 wt % and inferior or equal to 0.15 wt % relative to the total weight of the positive electrode active material.

Abstract: This invention relates to an industrial process of manufacturing hydroxide precursor for lithium transition metal oxide used in secondary lithium ion batteries. More particularly, this process utilizes highly concentrated nitrate salts and is designed to mitigate waste production.

Abstract: A method for producing a M-carbonate precursor of a Li-M oxide cathode material in a continuous reactor, wherein M=NixMnyCozAn, A being a dopant, with x>0, y>0, 0?z?0.35, 0?n?0.02 and x+y+z+n=1, the method comprising the steps of: —providing a feed solution comprising Ni-, Mn-, Co- and A-ions, and having a molar metal content M? feed, —providing an ionic solution comprising either one or both of a carbonate and a bicarbonate solution, the ionic solution further comprising either one or both of Na- and K-ions, —providing a slurry comprising seeds comprising M?-ions and having a molar metal content M? seeds, wherein M?=Nix?Mny?Coz?A?n?, A? being a dopant, with 0?x??1, 0?y??1, 0?z??1, 0?n??1 and x?+y?+z?+n?=1, and wherein the molar ratio M? seeds/M? feed is between 0.001 and 0.

Abstract: A method for preparing a N(M)C-based positive electrode materials according to the present invention comprises the following steps: —Precipitation of a metal (at least Ni— and Co—, preferably comprising Mn—) bearing precursor (MBP), —Fractionation of the MBP in a first (A) fraction and at least one second (B) fraction, —Lithiation of each of the first and second fraction, wherein the A fraction is converted into a first polycrystalline lithium transition metal oxide-based powder and the B fraction(s) is(are) converted into a second lithium transition metal oxide-based powder and, and —Mixing the first and second monolithic lithium transition metal oxide-based powder to obtain the N(M)C-based positive electrode material.

Abstract: A rechargeable lithium ion battery including: a positive electrode including coated particles, wherein each particle includes a core and a coating disposed thereon, wherein the core consists of Li, M, and O, and the coating includes Li, M, O, and AI2O3; wherein: M is (Niz(Ni1/2Mn1/2)yCox)1?kAk; 0.15?z?0.50; 0.17?x?0.30; 0.35?y?0.75; 0<k<0.1; x+y+z=1; and A includes Al and optionally at least one additional metal dopant selected from Mg, Zr, W, Ti, Cr, V, Nb, B, and Ca, and combinations thereof; and wherein the Li and M are present in the core in a molar ratio of Li to M of at least 0.95 and no greater than 1.

Abstract: A lithium metal oxide powder for a cathode material in a rechargeable battery comprises a core and a surface layer. The surface layer is delimited by an outer and an inner interface. The inner interface is in contact with the core. The cathode material has a layered crystal structure comprising the elements Li, M, and oxygen. M has the formula M=(Niz(Ni1/2 Mn1/2)y Cox)1-k Ak, with 0.15?x?0.30, 0.20?z?0.55, x+y+z=1 and 0<k?0.1. The Li content is stoichiometrically controlled with a molar ratio 0.95?Li:M?1.10. A is at least one dopant and comprises Al. The core at the inner interface has an Al content of 0.3-3 mol %. The surface layer comprises an intimate mixture of Ni, Co, Mn, LiF and Al2O3 determined by XPS. The surface layer has a Mn content that decreases from the Mn content at the inner interface to less than 50% of the Mn content at the outer interface.

Abstract: A method for manufacturing a cobalt based hydroxide carbonate compound having a malachite-rosasite mineral structure, comprising the steps of: providing an first aqueous solution comprising a source of Co, providing a second aqueous solution comprising Na2CO3, mixing both solutions in a precipitation reactor at a temperature above 70° C., thereby precipitating a cobalt based hydroxide carbonate compound whilst evacuating from the reactor any CO2 formed by the precipitation reaction, wherein the residence time of the compound in the reactor is between 1 and 4 hours, and recovering the cobalt based hydroxide carbonate compound. The cobalt based hydroxide carbonate compound is used as a precursor of a lithium cobalt based oxide usable as an active positive electrode material in lithium ion batteries.

Abstract: A liquid electrolyte lithium secondary battery cell comprising: —a positive electrode material comprising a lithium transition metal-based oxide powder having a general formula Li1+a ((Niz (Ni0.5Mn0.5)y Cox)1-k Ak)1-a O2, wherein A is a dopant, ?0.025?a?0.025, 0.18?x?0.22, 0.42?z?0.52, 1.075<z/y<1.625, x+y+z=1 and k?0.01; and—an electrolyte composition comprising: a) at least one cyclic carbonate, b) at least one fluorinated acyclic carboxylic acid ester, c) at least one electrolyte salt, d) at least one lithium compound selected from lithium phosphate compounds, lithium boron compounds, lithium sulfonate compounds and mixtures thereof, e) at least one cyclic sulfur compound, and f) optionally at least one cyclic carboxylic acid anhydride.

Abstract: A lithium metal oxide powder for a cathode material in a rechargeable battery, consisting of a core and a surface layer, the surface layer being delimited by an outer and an inner interface, the inner interface being in contact with the core, the core having a layered crystal structure comprising the elements Li, M and oxygen, wherein M has the formula M=(Niz (Ni1/2 Mn1/2)y Cox)1-k Ak, with 0.15?x?0.30, 0.20?z?0.55, x+y+z=1 and 0<k?0.1, wherein the Li content is stoichiometrically controlled with a molar ratio 0.95?Li:M?1.10; wherein A is at least one dopant and comprises Al; wherein the core has an Al content of 0.3-3 mol % and a F content of less than 0.05 mol %; and wherein the surface layer has an Al content that increases continuously from the Al content of the core at the inner interface to at least 10 mol % at the outer interface, and a F content that increases continuously from less than 0.