Abstract: A reversible cycle phase change liquid comprises a polar working fluid, nanoparticles of a material having a density greater than 3000 kg/m3, and a controllable gel. The gel is switchable between hydrophilic and hydrophobic phases by application of a phase change driver. The gel coats the nanoparticles to a first thickness when the gel is in the hydrophilic phase and is swollen by the polar working fluid, and coats the nanoparticles to a reduced thickness when in the hydrophobic phase. The coated nanoparticles form clusters, or comprise individual unclustered nanoparticles, when the gel is in the hydrophilic phase, and form larger clusters when the gel is in the hydrophobic phase. In embodiments aggregation of the nanoparticles into clusters is self-limiting because of electrical charges on the nanoparticles, such that when the gel is in the hydrophobic phase the clusters remain soluble within the liquid.

Abstract: It has been discovered that specially structured metallic films containing voids can deliver a hugely enhanced surface enhanced Raman spectroscopy (SERS) effect. By selecting a particular size and geometry for the voids, metallic films can be provided which have an enhanced photon-to-plasmon conversion efficiency for incident radiation of a predetermined wavelength. Controllable surface-enhanced absorption and emission characteristics may thus be provided, which are useful for SERS and potentially also other optical spectrometry and filtering applications. With such a large Raman signal, the invention enables fast, compact and inexpensive Raman spectrometers to be provided opening up many new application possibilities.

Abstract: In order to create an optical device with a photonic band gap extending in two dimensions and with very uniform properties in any direction and for any polarisation state, to within 1%, air holes are etched within a substrate of low refractive index material such silicon oxynitride or silica glass. The ratio of air hole area to the remainder of the substrate is low, being less than 35%. The air holes define a quasicrystal structure, having twelve fold symmetry, being based on a square-triangle system. In another development, an etched substrate with a regular crystal structure or quasicrystal structure exhibits a non-linear refractive index. Two adjacent areas in such a substrate have different lattice properties, or have defects in the lattices, to create a unidirectional transmission path (diode action). A further beam of light may be used to modulate the transmission path by reason of the non-linear refractive index.

Abstract: In order to create an optical device with a photonic band gap extending in two dimensions and with very uniform properties in any direction and for any polarisation state, to within 1%, air holes are etched within a substrate of low refractive index material such silicon oxynitride or silica glass. The ratio of air hole area to the remainder of the substrate is low, being less than 35%. The air holes define a quasicrystal structure, having twelve fold symmetry, being based on a square-triangle system. In another development, an etched substrate with a regular crystal structure or quasicrystal structure exhibits a non-linear refractive index. Two adjacent areas in such a substrate have different lattice properties, or have defects in the lattices, to create a unidirectional transmission path (diode action). A further beam of light may be used to modulate the transmission path by reason of the non-linear refractive index.

Abstract: Optically generated charge carriers in an optically responsive medium, such as an optical switch, which are produced in response to a first pulse of optical radiation (P1), are de-excited by directing a second pulse (P2) of optical radiation into the medium. The second pulse occurs while the excitation produced by the first pulse remains coherent, and the relative phase of the first and second pulses is selected so that the second pulse destructively interferes with the excitation produced by the first pulse. The apparatus may be used as an optical switch or as a photodetector.