Abstract: Positive electrode for lithium-ion electrochemical cells are provided that have capacity retentions of greater than about 95% after 50 charge-discharge cycles when comparing the capacity after cycle 52 with the capacity after cycle 2 when cycled between 2.5 V and 4.7 V vs. Li/Li+ at 30° C. Compositions useful in the provided positive electrodes can have the formula, Li1+x(NiaMnbCoc)1?xO2, wherein 0.05?x?0.10, a+b+c=1, 0.6?b/a?1.1, c/(a+b)<0.25, and a, b, and c are all greater than zero. The process of making these positive electrodes includes firing the compositions at 850° C. to 925° C.

Abstract: Positive electrode for lithium-ion electrochemical cells are provided that have capacity retentions of greater than about 95% after 50 charge-discharge cycles when comparing the capacity after cycle 52 with the capacity after cycle 2 when cycled between 2.5 V and 4.7 V vs. Li/Li+ at 30° C. Compositions useful in the provided positive electrodes can have the formula, Li1+x(NiaMnbCoc)1?x O2, wherein 0.05?x?0.10, a+b+c=1, 0.6?b/a?1.1, c/(a+b)<0.25, and a, b, and c are all greater than zero. The process of making these positive electrodes includes firing the compositions at 850° C. to 925° C.

Abstract: Positive electrode for lithium-ion electrochemical cells are provided that have capacity retentions of greater than about 95% after 50 charge-discharge cycles when comparing the capacity after cycle 52 with the capacity after cycle 2 when cycled between 2.5 V and 4.7 V vs. Li/Li+ at 30° C. Compositions useful in the provided positive electrodes can have the formula, Li1+x(NiaMnbCoc)1?x O2, wherein 0.05?x?0.10, a+b+c=1, 0.6?b/a?1.1, c/(a+b)<0.25, and a, b, and c are all greater than zero. The process of making these positive electrodes includes firing the compositions at 850° C. to 925° C.

Abstract: A lithium-ion electrochemical cell is provided that has high total energy, high energy density and good performance upon repeated charge-discharge cycles. The cell includes a composite positive electrode that comprises a metal oxide electrode material, a composite negative electrode that comprises a alloy anode active material having a first cycle irreversible capacity of 10 percent or higher and an electrolyte. The first cycle irreversible capacity of the composite positive electrode is within 40 percent of the first cycle irreversible capacity of the composite negative electrode.

Abstract: Single-phase lithium-transition metal oxide compounds containing cobalt, manganese and nickel can be prepared by wet milling cobalt-, manganese-, nickel- and lithium-containing oxides or oxide precursors to form a finely-divided slurry containing well-distributed cobalt, manganese, nickel and lithium, and heating the slurry to provide a lithium-transition metal oxide compound containing cobalt, manganese and nickel and having a substantially single-phase O3 crystal structure. Wet milling provides significantly shorter milling times than dry milling and appears to promote formation of single-phase lithium-transition metal oxide compounds. The time savings in the wet milling step more than offsets the time that may be required to dry the slurry during the heating step.

Abstract: Single-phase lithium-transition metal oxide compounds containing cobalt, manganese and nickel can be prepared by wet milling cobalt-, manganese-, nickel- and lithium-containing oxides or oxide precursors to form a finely-divided slurry containing well-distributed cobalt, manganese, nickel and lithium, and heating the slurry to provide a lithium-transition metal oxide compound containing cobalt, manganese and nickel and having a substantially single-phase O3 crystal structure. Wet milling provides significantly shorter milling times than dry milling and appears to promote formation of single-phase lithium-transition metal oxide compounds. The time savings in the wet milling step more than offsets the time that may be required to dry the slurry during the heating step.