Abstract: Described herein are methods of improving the durability of concrete by the infusion of the concrete with a low-viscosity oligomeric solution, and subsequent curing of the oligomeric solution to form a high toughness polymer. Also described herein are compositions containing concrete and high toughness polymers, and formed articles made from concrete and high toughness polymers. The methods and compositions are useful for improving the durability of concrete roads and structures, as well as the durability of repairs to concrete roads.