Abstract: Described herein are methods of producing a coated optical fiber from a primary and/or secondary coating composition that contain a reactive oligomer having an average of at least one polymerizable group, a monomer having an average of at least one polymerizable group, and a photoinitiator, wherein the photoinitiator possesses specified normalized rates of polymerization at (150) degrees Celsius and/or a potential excited triplet state with certain ionization potential values. Also described and claimed are the compositions for use therewith, including primary coating compositions and secondary coating compositions. Yet further described and claimed are the coated optical fibers produced from the methods and/or compositions elsewhere described.

Abstract: Radiation curable compositions for coating optical fibers are disclosed herein. In an embodiment, a radiation curable composition includes a reactive oligomer component, wherein a portion of the polymerizable groups of the reactive oligomer component include methacrylate groups; a reactive diluent monomer component, wherein a portion of the polymerizable groups of the reactive diluent monomer component include acrylate groups, acrylamide groups, or N-vinyl amide groups, or combinations thereof; a photoinitiator component, and an optional additive component. Also described are methods of coating the radiation curable compositions elsewhere described, and the fiber optic coatings and cables resulting therefrom.

Abstract: The present invention is directed to a process for producing a coating, wherein the process comprises (1) Irradiating a radiation-curable coating composition with UV light having a wavelength ?220 nm under inert gas, followed by (2) Irradiating with UV light having a wavelength ?300 nm or with E-beam, wherein the radiation-curable coating composition comprises (A) One or more oligomeric urethane acrylates (A) with a molar mass of from 1100 to 5000 g/mol with an acrylate functionality of from 4 to 14, and (B) One or more acrylate diluents (B) with a molar mass less than 650 g/mol and with an acrylate functionality of from 2 to 4, and wherein the amount of (A) is from 20 to 75 wt. % and the amount of (B) is from 25 to 80 wt. %, based on the total amount of (A) and (B), and the total amount of (A) and (B) is at least 50 wt. % by weight of the radiation-curable coating composition.

Abstract: A method of forming a three-dimensional object comprises the steps of forming a layer of a particulate composition, selectively depositing a liquid composition onto the layer of the particulate composition in accordance with computer data corresponding to the shape of at least a portion of a three-dimensional object, and repeating the steps a plurality of times to form a three-dimensional object. The particulate composition comprises a plurality of first particles that comprise a resin component comprising a first resin, the first resin comprising a first resin polymerizable group. Either or both of the particulate composition and the liquid composition comprise an initiator capable of initiating polymerization of at least the first resin. At least the first resin undergoes melting and polymerization in a plurality of the locations where the liquid composition has been selectively deposited.

Abstract: The present invention is directed to water-swellable, radiation curable compositions suitable for use in coating water-blocking fibers, such as optical fibers. The present invention is further directed to fibers, including optical fibers, which are coated with water-swellable exterior coatings that are configured to buckle and detach from the associated fiber to facilitate superior performance in longitudinal water-blocking testing. Also claimed and described are methods of applying such water-swellable coatings to optical fiber coatings. Further claimed and described are buffered bundles of fibers including at least one optical fiber that is coated with a water-swellable, radiation curable coating to ensure superior longitudinal water blocking performance.

Abstract: A method of forming a three-dimensional object comprises the steps of forming a layer of a particulate composition, selectively depositing a liquid composition onto the layer of the particulate composition in accordance with computer data corresponding to the shape of at least a portion of a three-dimensional object, and repeating the steps a plurality of times to form a three-dimensional object. The particulate composition comprises a plurality of first particles that comprise a resin component comprising a first resin, the first resin comprising a first resin polymerizable group. Either or both of the particulate composition and the liquid composition comprise an initiator capable of initiating polymerization of at least the first resin. At least the first resin undergoes melting and polymerization in a plurality of the locations where the liquid composition has been selectively deposited.

Abstract: Disclosed and claimed herein are radiation curable compositions for coating an optical fiber containing an oligomer, a diluent, a photoinitiator, and optionally, additives. The oligomer includes a reactive urethane oligomer having at least three arms, each arm having a most distal termination point and bound together at a single junction point, wherein at least one arm comprises the reaction product of a polyol, a polyisocyanate, and an isocyanate-reactive (meth)acrylate. The reactive urethane oligomer possesses specified molecular weight and/or average functionality values, and it may possess specified chain length values between the oligomer junction point and the distal termination point along one or more arm(s). Also disclosed are methods of coating an optical fiber incorporating the compositions described herein, along with the coated optical fibers and cables produced therefrom.

Abstract: A thermosetting powder coating composition C (PCC C) includes a physical mixture of a thermosetting powder coating composition A (PCC A) with a separate, distinct thermosetting powder coating composition B (PCC B). Also provided are processes for making the thermosetting powder coating composition C and for coating an article with the thermosetting powder coating composition C. A cured thermosetting powder coating composition C (c-PCC C) is also provided so as to obtain articles having coated and cured thereon the thermosetting powder coating composition C. Heat-curing can occur at low temperatures. The cured c-PCC C is a powder coating having at least one desirable property such as excellent resistance to swelling, good smoothness, good chemical resistance, low gloss, and/or low yellowness.

Abstract: Disclosed and claimed herein are radiation curable compositions for coating an optical fiber containing an oligomer, a diluent, a photoinitiator, and optionally, additives. The oligomer includes a reactive urethane oligomer having at least three arms, each arm having a most distal termination point and bound together at a single junction point, wherein at least one arm comprises the reaction product of a polyol, a polyisocyanate, and an isocyanate-reactive (meth)acrylate. The reactive urethane oligomer possesses specified molecular weight and/or average functionality values, and it may possess specified chain length values between the oligomer junction point and the distal termination point along one or more arm(s). Also disclosed are methods of coating an optical fiber incorporating the compositions described herein, along with the coated optical fibers and cables produced therefrom.

Abstract: Radiation curable compositions for coating optical fibers are disclosed herein. In an embodiment, a radiation curable composition includes a reactive oligomer component, wherein a portion of the polymerizable groups of the reactive oligomer component include methacrylate groups; a reactive diluent monomer component, wherein a portion of the polymerizable groups of the reactive diluent monomer component include acrylate groups, acrylamide groups, or N-vinyl amide groups, or combinations thereof; a photoinitiator component, and an optional additive component. Also described are methods of coating the radiation curable compositions elsewhere described, and the fiber optic coatings and cables resulting therefrom.

Abstract: A method of forming a three-dimensional object comprises the steps of forming a layer of a particulate composition, selectively depositing a liquid composition onto the layer of the particulate composition in accordance with computer data corresponding to the shape of at least a portion of a three-dimensional object, initiating polymerization, and repeating the steps a plurality of times to form a three-dimensional object. The particulate composition comprises a plurality of first particles that comprise a resin component comprising a first resin, the first resin comprising a first resin polymerizable group, the first resin polymerizable group comprising a carbon-carbon double bond directly attached to an electron withdrawing group, a thermal radical initiator dispersed or dissolved in the resin component, and a retardant dispersed or dissolved in the resin component.

Abstract: The present invention is directed to water-swellable, radiation curable compositions suitable for use in coating water-blocking fibers, such as optical fibers. The present invention is further directed to fibers, including optical fibers, which are coated with water-swellable exterior coatings that are configured to buckle and detach from the associated fiber to facilitate superior performance in longitudinal water-blocking testing. Also claimed and described are methods of applying such water-swellable coatings to optical fiber coatings. Further claimed and described are buffered bundles of fibers including at least one optical fiber that is coated with a water-swellable, radiation curable coating to ensure superior longitudinal water blocking performance.

Abstract: The present invention is directed to water-swellable, radiation curable compositions suitable for use in coating water-blocking fibers, such as optical fibers. The present invention is further directed to fibers, including optical fibers, which are coated with water-swellable exterior coatings that are configured to buckle and detach from the associated fiber to facilitate superior performance in longitudinal water-blocking testing. Also claimed and described are methods of applying such water-swellable coatings to optical fiber coatings. Further claimed and described are buffered bundles of fibers including at least one optical fiber that is coated with a water-swellable, radiation curable coating to ensure superior longitudinal water blocking performance.

Abstract: Described herein are methods of producing a coated optical fiber from a primary and/or secondary coating composition that contain a reactive oligomer having an average of at least one polymerizable group, a monomer having an average of at least one polymerizable group, and a photoinitiator, wherein the photoinitiator possesses specified normalized rates of polymerization at (150) degrees Celsius and/or a potential excited triplet state with certain ionization potential values. Also described and claimed are the compositions for use therewith, including primary coating compositions and secondary coating compositions. Yet further described and claimed are the coated optical fibers produced from the methods and/or compositions elsewhere described.

Abstract: A method of forming a three-dimensional object comprises the steps of forming a layer of a particulate composition, selectively depositing a liquid composition onto the layer of the particulate composition in accordance with computer data corresponding to the shape of at least a portion of a three-dimensional object, initiating polymerization, and repeating the steps a plurality of times to form a three-dimensional object. The particulate composition comprises a plurality of first particles that comprise a resin component comprising a first resin, the first resin comprising a first resin polymerizable group, the first resin polymerizable group comprising a carbon-carbon double bond directly attached to an electron withdrawing group, a thermal radical initiator dispersed or dissolved in the resin component, and a retardant dispersed or dissolved in the resin component.

Abstract: Described and claimed herein are radiation curable compositions for coating an optical fiber, particularly primary coating compositions, wherein the composition possesses specified liquid glass transition temperatures, and/or viscosity ratios between, e.g., 25° C. and 85° C. Such compositions preferably possess large amounts of a reactive oligomer component that is either not substantially derived from, or preferably substantially free from polypropylene glycol, with select diisocyanate constituents, one or more reactive diluent monomers, a photoinitiator, and optionally, one or more additives. Such compositions also are preferably sufficiently viscous at room temperature to ensure optimum optical fiber coating processability. Also described and claimed are methods of using such radiation curable compositions in high speed and/or low helium optical fiber coating applications, along with the coated optical fibers produced therefrom.

Abstract: A method of forming a three-dimensional object comprises the steps of forming a layer of a particulate composition, selectively depositing a liquid composition onto the layer of the particulate composition in accordance with computer data corresponding to the shape of at least a portion of a three-dimensional object, initiating polymerization, and repeating the steps a plurality of times to form a three-dimensional object. The particulate composition comprises a plurality of first particles that comprise a resin component comprising a first resin, the first resin comprising a first resin polymerizable group, the first resin polymerizable group comprising a carbon-carbon double bond directly attached to an electron withdrawing group, a thermal radical initiator dispersed or dissolved in the resin component, and a retardant dispersed or dissolved in the resin component.

Abstract: Radiation curable compositions for coating optical fibers are disclosed herein. In an embodiment, a radiation curable composition includes a reactive oligomer component, wherein a portion of the polymerizable groups of the reactive oligomer component include methacrylate groups; a reactive diluent monomer component, wherein a portion of the polymerizable groups of the reactive diluent monomer component include acrylate groups, acrylamide groups, or N-vinyl amide groups, or combinations thereof; a photoinitiator component, and an optional additive component. Also described are methods of coating the radiation curable compositions elsewhere described, and the fiber optic coatings and cables resulting therefrom.

Abstract: Radiation curable compositions for coating optical fibers are disclosed herein. In an embodiment, a radiation curable composition includes a reactive oligomer component, wherein a portion of the polymerizable groups of the reactive oligomer component include methacrylate groups; a reactive diluent monomer component, wherein a portion of the polymerizable groups of the reactive diluent monomer component include acrylate groups, acrylamide groups, or N-vinyl amide groups, or combinations thereof; a photoinitiator component, and an optional additive component. Also described are methods of coating the radiation curable compositions elsewhere described, and the fiber optic coatings and cables resulting therefrom.

Abstract: The present invention is directed to water-swellable, radiation curable compositions suitable for use in coating water-blocking fibers, such as optical fibers. The present invention is further directed to fibers, including optical fibers, which are coated with water-swellable exterior coatings that are configured to buckle and detach from the associated fiber to facilitate superior performance in longitudinal water-blocking testing. Also claimed and described are methods of applying such water-swellable coatings to optical fiber coatings. Further claimed and described are buffered bundles of fibers including at least one optical fiber that is coated with a water-swellable, radiation curable coating to ensure superior longitudinal water blocking performance.