Patent number: 7129369
Abstract: A process for preparing amino-functional organopolysiloxanes comprising (i) mixing aminosilanes of the general formula RaQbSi(OR1)4?(a+b), where R and R1 are hydrogen or optionally substituted hydrocarbyl, a is 0, 1 or 2, b is 1, 2 or 3, and a+b is ?3, Q is —R5—[NR6(CH2)n]eN(R6)2, where R5 is a hydrocarbyl diradical and R6 is hydrogen, hydrocarbyl, or acyl, e is 0, 1, 2, 3 or 4, n is 2, 3, 4, 5 or 6, with organosilicon compounds selected from siloxanes comprising units R d ? ( O ? R 1 ) f ? SiO 4 - ( d + f ) 2 ? ? and ? ? R c ? SiO 4 - c 2 or silanes RcSi(OR1)4?c, where c is 0, 1, 2 or 3, d is 0, 1 or 2, f is 1, 2 or 3, with the proviso that d+f is ?3, basic catalysts selected from alkali metal hydroxides, alcoholates and siloxanolates, and optionally, alcohols H—[O(CHR2)p]mOR3, where R2 and R3 are hydrogen or hydrocarbyl, p is 2, 3 or 4, and m is 0 or an integer from 1 to 100, (ii) reacting by heating to 70–100° C.
Type:
Grant
Filed:
February 28, 2005
Date of Patent:
October 31, 2006
Assignee:
Wacker Chemie AG
Inventors:
Anton Heller, Johann Bindl
Publication number: 20050215806
Abstract: A process for preparing amino-functional organopolysiloxanes comprising (i) mixing aminosilanes of the general formula RaQbSi(OR1)4?(a+b), where R and R1 are hydrogen or optionally substituted hydrocarbyl, a is 0, 1 or 2, b is 1, 2 or 3, and a+b is ?3, Q is —R5—[NR6(CH2)n]eN(R6)2, where R5 is a hydrocarbyl diradical and R6 is hydrogen, hydrocarbyl, or acyl, e is 0, 1, 2, 3 or 4, n is 2, 3, 4, 5 or 6, with organosilicon compounds selected from siloxanes comprising units R d ? ( O ? R 1 ) f ? SiO 4 - ( d + f ) 2 ? ? ? and ? ? ? R c ? SiO 4 - c 2 or silanes RcSi(OR1)4?c, where c is 0, 1, 2 or 3, d is 0, 1 or 2, f is 1, 2 or 3, with the proviso that d+f is ?3, basic catalysts selected from alkali metal hydroxides, alcoholates and siloxanolates, and optionally, alcohols H—[O(CHR2)p]mOR3, where R2 and R3 are hydrogen or hydrocarbyl, p is 2, 3 or 4, and m is 0 or an integer from 1 to 100, (ii) reacting by heating to 70-100° C.
Type:
Application
Filed:
February 28, 2005
Publication date:
September 29, 2005
Applicant:
Wacker-Chemie GmbH
Inventors:
Anton Heller, Johann Bindl