Abstract: Methods of and apparatus for Nuclear Quadrupole Resonance (NQR) testing a sample containing quadrupolar nuclei exhibiting a given value of spin-lattice relaxation time, T1, are disclosed. The method comprises applying two excitation blocks to excite nuclear quadrupole resonance, there being a given delay time between the two blocks, detecting resonance response signals, and comparing the response signals from respective blocks. The delay time is less than the T1 value of the nuclei.

Abstract: A method of nuclear quadrupole resonance testing a sample is disclosed in which the excitation applied to the sample is arranged so that phase and amplitude information may be obtained from the response signal, and in which the signal is resolved into two components. Particularly if a parameter such as radio-frequency field strength varies with position, this may give an indication of the distribution of nuclei in the sample, preferably from the phase of the response signal. Positional information can also be obtained by measuring from two or more reference points. This may be employed in imaging. The phase information may be employed to improve the signal to noise ratio obtainable in other methods where only amplitude information was previously available, for example in distinguishing genuine NQR response signals from spurious signals.

Abstract: An apparatus for and a method of Nuclear Quadrupole Resonance testing a sample in the presence of interference are disclosed. The apparatus comprises excitation applying means for applying excitation, a first antenna for detecting a response to the excitation together with the interference, and a second antenna for detecting the interference, the first and second antennas being arranged such that a signal commonly detected in the two antennas is attenuated relative to a signal that is detected by only one of the antennas. The apparatus may provide suppression of interference.

Abstract: A method of and apparatus for analysing a signal is disclosed, the method comprising producing a model of the signal and comparing the model to a predetermined model of a signal due to a phenomenon, thereby to determine whether the model represents a signal due to that phenomenon. A method of and apparatus for detecting the presence of a sample in a larger sample which is not known to contain the sample is also disclosed, the method comprising detecting a signal comprising a response from the sample, producing a model of the signal, and comparing the model to a predetermined model of a response from the sample, thereby to determine whether the sample is present. The techniques have particular application in Magnetic Resonance and Quadrupole Resonance.

Abstract: A method of Nuclear Quadrupole Resonance testing a sample containing a given species of quadrupolar nucleus, the sample being subjected to an inhomogeneous distribution of an extrinsic parameter having a variation over the sample over a particular range, comprises applying excitation to the sample at a plurality of different excitation frequencies to excite nuclear quadrupole resonance, such frequencies falling within the resonance frequency range for the nucleus corresponding to the range of the extrinsic parameter, and detecting the resonance response signal.

Abstract: A method of nuclear quadrupole resonance testing a sample comprising a first type substance containing quadrupolar nuclei and a second type substance which may give rise to spurious signals which interfere with response signals from the quadrupolar nuclei, comprises applying a pulse sequence to the sample to excite nuclear quadrupole resonance, the pulse sequence comprising at least one pair of pulses; detecting response signals; and comparing, for the or each such pair, the respective response signals following the two member pulses of the pair, the pulse sequence being such that the respective spurious signals following the two member pulses can be at least partially cancelled by the comparison without the corresponding true quadrupole resonance signals being completely cancelled; and for the or each such pair, the two member pulses being of like phase.

Abstract: Apparatus for Nuclear Quadrupole Resonance testing a remote sample containing a given species of quadrupolar nucleus includes at least one probe (112) having a given maximum cross-sectional dimension; a device (102) for applying excitation to the probe or at least one of the probes to excite nuclear quadruple resonance for a selected range of distance of the sample from each such probe, the selected range being at least one tenth of the given maximum dimension of the probe, the apparatus being adapted to produce a non-uniform field over the selected range; and a device (106) for detecting the resonance response signal from the sample via the probe or at least one of the probes; the excitation being such as would generate non-zero resonance signals at all distances within the selected range.

Abstract: Methods of testing a sample in which long composite pulses comprising a sequence of short closely spaced pulse elements are disclosed. The pulses generate a qualitatively different response characteristic, which can be tailored as desired by suitable adjustment of the pulses. Near sinusoidal dependence on pulse length can be attained, and effective, efficient, inversion pulses can be produced. Typically each pulse element generates a small flip angle of a few degrees, and the sequence conatins tens or even hundreds of elements. Similar excitation and effects may be produced by amplitude modulating a carrier, rather than switching pulses on and off; there is little discernible difference in the excitation seen by the sample.

Abstract: A method and apparatus for imaging within a sample space an object containing quadrupolar nuclei comprises irradiating the object to excite nuclear quadrupole resonance, applying to the object a magnetic field gradient having a profile Bo(x) such that the square of the profile (Bo(x))2 varies linearly with distance (x), detecting resonance response signals from the nuclei, and deriving an image from the response signals. A method of and apparatus for nuclear quadrupole resonance testing an object, and a method of and apparatus for detecting the presence of a particular substance containing a given species of quadrupolar nucleus, are also disclosed.

Abstract: A method of Nuclear Quadrupole Resonance testing a sample containing a given species of quadrupolar nucleus, the sample being subjected to an inhomogeneous distribution of an extrinsic parameter having a variation over the sample over a particular range, comprises applying excitation to the sample at a plurality of different excitation frequencies to excite nuclear quadrupole resonance, such frequencies falling within the resonance frequency range for the nucleus corresponding to the range of the extrinsic parameter, and detecting the resonance response signal.

Abstract: Apparatus for Nuclear Quadrupole Resonance testing a sample comprises: means for applying excitation to the sample to excite NQR resonance, the excitation comprising at least one excitation pulse, the or each pulse covering a selected excitation frequency range, for the or each pulse the phase of the excitation varying generally non-linearly with the excitation frequency over the selected range; and means for detecting the NQR response signal.