Abstract: An apparatus can include a housing, a plurality of electrochemical devices disposed within the housing, and a heat exchanger disposed within the housing. The heat exchanger can be faced with an oxidant-containing gas outlet surface of at least one of the plurality of electrochemical devices. The electrochemical devices can include a stack of solid oxide fuel cells, a battery, or a solid oxide electrolyzer cell.

Abstract: An apparatus can include a housing, a plurality of electrochemical devices disposed within the housing, and a heat exchanger disposed within the housing. The heat exchanger can be faced with an oxidant-containing gas outlet surface of at least one of the plurality of electrochemical devices. The electrochemical devices can include a stack of solid oxide fuel cells, a battery, or a solid oxide electrolyzer cell.

Abstract: An electrochemical device can include a cathode layer including an ionic conductor material and an electronic conductor material. The cathode layer can include a ratio of (Vi/Ve) of a volume of the ionic conductor material (Vi) to a volume of the electronic conductor material (Ve) of at least 1.3. In an embodiment, the cathode layer can include a median surface diffusion length (Ls) greater than 0.33 microns. In an embodiment, the cathode layer can include a cathode functional layer.

Abstract: An apparatus can include a housing, a plurality of electrochemical devices disposed within the housing, and a heat exchanger disposed within the housing. The heat exchanger can be faced with an oxidant-containing gas outlet surface of at least one of the plurality of electrochemical devices. The electrochemical devices can include a stack of solid oxide fuel cells, a battery, or a solid oxide electrolyzer cell.

Abstract: An electrochemical assembly can include an electrochemical device and a heat exchanger disposed within a housing. In an embodiment, the heat exchanger can be disposed in a gas outlet chamber. In another embodiment, the heat exchanger can be at least partially embedded in a wall of the gas outlet chamber. The heat exchanger can be configured to transfer a heat from an outlet gas to an inlet gas.

Abstract: An electrochemical device can include a cathode layer including an ionic conductor material and an electronic conductor material. The cathode layer can include a ratio of (Vi/Ve) of a volume of the ionic conductor material (Vi) to a volume of the electronic conductor material (Ve) of at least 1.3. In an embodiment, the cathode layer can include a median surface diffusion length (Ls) greater than 0.33 microns. In an embodiment, the cathode layer can include a cathode functional layer.

Abstract: A high temperature system can include a high temperature device having a plurality of opposite surfaces and a compression device that exerts a biaxial compression against the opposite surfaces. The high temperature system can include a high temperature insulation disposed between the compression device and the high temperature device, and a low temperature insulation disposed external to the compression device such that the compression device is disposed between the high temperature insulation and the low temperature insulation.

Abstract: Embodiments of the present disclosure relate to a hot press and methods of using the hot press. In an embodiment, the hot press can include a pressing element including a flared body. In another embodiment, the hot press can include a compression surface. The compression surface can include a first layer including a monocrystalline material and a second layer including a polycrystalline material, wherein the monocrystalline material and the polycrystalline material include a same primary compound. In a further embodiment, a sample including more than one layer of ceramic oxide material can be hot pressed without a die.

Abstract: A method includes placing a material including a glass precursor material in contact with a second material and annealing the glass precursor material to form a glass composition in contact with the second material. In an embodiment, annealing is performed at a single temperature. In another embodiment, annealing is performed at a temperature in a range of 750° C. to 1000° C. In a particular embodiment, the glass composition includes a crystalline fraction of at least 30%.

Abstract: Embodiments of the present disclosure relate to a hot press and methods of using the hot press. In an embodiment, the hot press can include a pressing element including a flared body. In another embodiment, the hot press can include a compression surface. The compression surface can include a first layer including a monocrystalline material and a second layer including a polycrystalline material, wherein the monocrystalline material and the polycrystalline material include a same primary compound. In a further embodiment, a sample including more than one layer of ceramic oxide material can be hot pressed without a die.

Abstract: A bonding layer, disposed between an interconnect layer and an electrode layer of a solid oxide fuel cell article, may be formed from a yttria stabilized zirconia (YSZ) powder having a monomodal particle size distribution (PSD) with a d50 that is greater than about 1 ?m and a d90 that is greater than about 2 ?m.

Abstract: A mold for forming a porous article can include a first material having a first thermal conductivity and a second material having a second thermal conductivity different from the first thermal conductivity. The first material may be at least partially embedded within the second material and configured to create regions of different thermal conductivity in the body, such as configured to create distinct nucleation regions within a material formed within the mold. A method for forming a porous article can include providing a slurry within a mold and freeze-casting the slurry to form a porous article having a burst-like distribution of porosity. A porous article according to embodiments herein can include a burst-like distribution of porosity.

Abstract: A bonding layer, disposed between an interconnect layer and an electrode layer of a solid oxide fuel cell article, may be formed from a yttria stabilized zirconia (YSZ) powder having a monomodal particle size distribution (PSD) with a d50 that is greater than about 1 ?m and a d90 that is greater than about 2 ?m.

Abstract: The present disclosure is directed to an integrated SOFC stack including, a first cell having a cathode layer, an electrolyte layer overlying the cathode layer, and an anode layer overlying the electrolyte layer. The SOFC stack also includes a second cell having a cathode layer, an electrolyte layer overlying the cathode layer, and an anode overlying the electrolyte layer. The SOFC stack further includes a ceramic interconnect layer between the first cell and the second cell, the ceramic interconnect layer having a first high temperature bonding region along the interfacial region between the first cell and the ceramic interconnect layer. The ceramic interconnect layer also includes a second high temperature bonding region along the interfacial region between the second cell and the ceramic interconnect layer.

Abstract: A raw material powder for forming a layer of a solid oxide fuel cell (SOFC) article includes a broad particle size distribution (BPSD) defined by plotted curve of frequency versus diameter of the raw material powder may be characterized as having a first standard deviation including at least about 78% to at least about 99% of a total content of particles of the raw material powder. The plotted curve of the BPSD may also be characterized as having a first maximum value and a first minimum value, wherein the difference between the first maximum value and first minimum value is not greater than about 8%.

Abstract: The present disclosure relates to solid oxide fuel cells, and particularly raw powder materials which form a layer in a solid oxide fuel. The raw powder materials include an ionic conductor powder material; and an electronic conductor powder material. The ratio of an average particle diameter of the ionic conductor powder material to an average particle diameter of the electronic conductor powder material is greater than about 1:1, and an average particle diameter of at least one of the electronic conductor powder material or the ionic conductor powder material is coarse.

Abstract: An SOFC component includes a first electrode, an electrolyte overlying the first electrode, and a second electrode overlying the electrolyte. The second electrode includes a bulk layer portion and a functional layer portion, the functional layer portion being an interfacial layer extending between the electrolyte and the bulk layer portion of the second electrode, wherein the bulk layer portion has a bimodal pore size distribution.

Abstract: A bonding layer, disposed between an interconnect layer and an electrode layer of a solid oxide fuel cell article, may be formed from a yttria stabilized zirconia (YSZ) powder having a monomodal particle size distribution (PSD) with a d50 that is greater than about 1 ?m and a d90 that is greater than about 2 ?m.

Abstract: Robust ceramic igniters are provided that include an improved sealing system which can significantly enhance operational life of the igniter. Preferred igniters comprise a conductive cold zone and hot zone with higher resisitivity. A hermetic sealant material covers one or more electrical connections on the of each cold zone, thus shielding the electrical connections from environmental exposure, and thereby avoiding igniter failure resulting from electrical shorts and/or undesired oxidation.

Abstract: Robust ceramic igniters are provided that include an improved sealing system which can significantly enhance operational life of the igniter. Preferred igniters comprise a conductive cold zone and hot zone with higher resisitivity. A hermetic sealant material covers one or more electrical connections on the of each cold zone, thus shielding the electrical connections from environmental exposure, and thereby avoiding igniter failure resulting from electrical shorts and/or undesired oxidation.