Patents by Inventor John G. Papalos
John G. Papalos has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 6303672Abstract: A self-dispersing curable epoxy composition is prepared upon contacting an epoxy resin with a polyoxyalkylenemonoamine having a molecular weight of from about 3,000 to about 15,000 in a ratio of about 0.001 to 0.060 reactive equivalents of polyoxyalkylenemonoamine to about 1.0 reactive equivalents of epoxy resin. The self-dispersing curable epoxy resin forms an aqueous dispersion upon mixing with water. When cured, the dispersion is useful as a coating composition.Type: GrantFiled: June 7, 1995Date of Patent: October 16, 2001Assignee: Henkel CorporationInventors: John G. Papalos, Shailesh Shah, Reuben H. Grinstein, Joseph L. Mulvey, Brian G. Jewell
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Patent number: 6294596Abstract: A self-dispersing curable epoxy composition is prepared upon contacting an epoxy resin with a polyoxyalkyleneamine having a molecular weight of from about 3,000 to about 15,000 in a ratio of about 0.001 to 0.060 reactive equivalents of polyoxyalkyleneamine to about 1.0 reactive equivalents of epoxy resin. The self-dispersing curable epoxy resin forms an aqueous dispersion upon mixing with water. When cured, the dispersion is useful as a coating composition.Type: GrantFiled: September 15, 1995Date of Patent: September 25, 2001Assignee: Henkel CorporationInventors: John G. Papalos, Shailesh Shah, Reuben H. Grinstein, Joseph L. Mulvey, Brian G. Jewell
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Patent number: 5874490Abstract: There is disclosed a self-dispersing curable epoxy resin composition comprising the addition product of reactants comprising (a) 1.0 reactive equivalent of an epoxy resin, (b) from about 0.40 to 0.95 reactive equivalents of a polyhydric phenol, and (c) from about 0.005 to 0.5 reactive equivalents of an amine-epoxy adduct comprising the addition product of reactants comprising 1.0 reactive equivalent of a polyepoxide and from about 0.3 to 0.9 reactive equivalents of a polyoxyalkyleneamine with the structural formulaH.sub.2 N--CH(R.sub.2)CH.sub.2 --O--R.sub.1 --CH.sub.2 CH(R.sub.2)--NH.sub. 2wherein:R.sub.1 represents a polyoxyalkylene chain having the structural formula:(CH.sub.2 --CH.sub.2 --O).sub.a --(CH.sub.2 --CH(R.sub.3)--O).sub.bwherein:R.sub.3 is a monovalent organic radical selected from the group consisting of C.sub.1 to C.sub.4 aliphatic hydrocarbons,`a` designates a number of ethoxy groups (CH.sub.2 --CH.sub.2 --O),`b` designates a number of monosubstituted ethoxy groups (CH.sub.2 --CH(R.sub.Type: GrantFiled: October 30, 1996Date of Patent: February 23, 1999Assignee: Henkel CorporationInventors: Kartar S. Arora, John G. Papalos, Grannis S. Johnson
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Patent number: 5763506Abstract: A self-dispersing curable epoxy composition is prepared upon contacting (a) 1.0 reactive equivalents of an epoxy resin, (b) from about 0.01 to 1.0 reactive equivalents of a polyhydric phenol, and (c) between 0.005 and 0.025 reactive equivalents of an amine-epoxy adduct, wherein the amine-epoxy adduct is formed upon contacting 1.0 equivalents of an aliphatic polyepoxide and between 0.3 and 0.9 reactive equivalents of a polyoxyalkyleneamine. The self-dispersing curable epoxy resin forms an aqueous dispersion upon mixing with water. When cured, the dispersion is useful as a coating composition.Type: GrantFiled: September 26, 1996Date of Patent: June 9, 1998Assignee: Henkel CorporationInventors: John G. Papalos, Reuben H. Grinstein, Shailesh Shah, Joseph L. Mulvey, Brian G. Jewell
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Patent number: 5652323Abstract: A self-dispersing curable epoxy composition is prepared upon contacting (a) 1.0 reactive equivalents of an epoxy resin, (b) from about 0.01 to 1.0 reactive equivalents of a polyhydric phenol, and (c) between 0.005 and 0.025 reactive equivalents of an amine-epoxy adduct, wherein the amine-epoxy adduct is formed upon contacting 1.0 equivalents of an aliphatic polyepoxide and between 0.3 and 0.9 reactive equivalents of a polyoxyalkyleneamine. The self-dispersing curable epoxy resin forms an aqueous dispersion upon mixing with water. When cured, the dispersion is useful as a coating composition.Type: GrantFiled: June 6, 1995Date of Patent: July 29, 1997Assignee: Henkel CorporationInventors: John G. Papalos, Reuben H. Grinstein, Shailesh Shah, Joseph L. Mulvey, Brian G. Jewell
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Patent number: 5648409Abstract: There is disclosed a self-disbursing curable epoxy resin composition comprising the addition product of reactants comprising (a) 1.0 reactive equivalent of an epoxy resin, (b) from about 0.40 to 0.95 reactive equivalents of a polyhydric phenol, and (c) from about 0.005 to 0.5 reactive equivalents of an amine-epoxy adduct comprising the addition product of reactants comprising 1.0 reactive equivalent of an aromatic polyepoxide and from about 0.3 to 0.9 reactive equivalents of a polyoxyalkyleneamine.Type: GrantFiled: December 29, 1994Date of Patent: July 15, 1997Assignee: Henkel CorporationInventors: Kartar S. Arora, David I. Devore, Reuben H. Grinstein, Grannis S. Johnson, John G. Papalos, Shailesh Shah
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Patent number: 5623046Abstract: A self-dispersing curable epoxy composition is prepared upon contacting (a) 1.0 reactive equivalents of an epoxy resin, (b) between 0.005 and 0.5 reactive equivalents of an amine-epoxy adduct, and optionally (c) from about 0.01 to 1.0 reactive equivalents of a polyhydric phenol, wherein the amine-epoxy adduct is formed upon contacting 1.0 equivalents of an aliphatic polyepoxide and greater than 1.0 but no more than about 2.5 reactive equivalents of a polyoxyalkyleneamine. The self-dispersing curable epoxy resin forms an aqueous dispersion upon mixing with water. When cured, the dispersion is useful as a coating composition.Type: GrantFiled: June 7, 1995Date of Patent: April 22, 1997Assignee: Henkel CorporationInventors: John G. Papalos, Shailesh Shah, Reuben H. Grinstein, Joseph L. Mulvey, Brian G. Jewell
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Patent number: 5604269Abstract: A self-dispersing curable epoxy composition is prepared upon contacting (a) 1.0 reactive equivalents of an epoxy resin, (b) between 0.005 and 0.5 reactive equivalents of an amine-epoxy adduct, and optionally (c) from about 0.01 to 1.0 reactive equivalents of a polyhydric phenol, wherein the amine-epoxy adduct is formed upon contacting 1.0 equivalents of an aliphatic polyepoxide and greater than 1.0 but no more than about 2.5 reactive equivalents of a polyoxyalkyleneamine. The self-dispersing curable epoxy resin forms an aqueous dispersion upon mixing with water. When cured, the dispersion is useful as a coating composition.Type: GrantFiled: August 25, 1994Date of Patent: February 18, 1997Assignee: Henkel CorporationInventors: John G. Papalos, Shailesh Shah, Reuben H. Grinstein, Joseph L. Mulvey, Brian G. Jewell
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Patent number: 5565506Abstract: A self-dispersing curable epoxy composition is prepared upon contacting (a) 1.0 reactive equivalents of an epoxy resin, (b) from about 0.65 to 0.95 reactive equivalents of a polyhydric phenol, and (c) between 0.005 and 0.5 reactive equivalents of an amine-epoxy adduct, wherein the amine-epoxy adduct is formed upon contacting 1.0 equivalents of an aliphatic polyepoxide and between 0.3 and 0.9 reactive equivalents of a polyoxyalkyleneamine. The self-dispersing curable epoxy resin forms an aqueous dispersion upon mixing with water. When cured, the dispersion is useful as a coating composition.Type: GrantFiled: August 25, 1994Date of Patent: October 15, 1996Assignee: Henkel CorporationInventors: John G. Papalos, Reuben H. Grinstein, Shailesh Shah, Joseph L. Mulvey, Brian G. Jewell
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Patent number: 5565505Abstract: A self-dispersing curable epoxy composition is prepared upon contacting (a) 1.0 reactive equivalents of an epoxy resin, (b) from about 0.01 to 1.0 reactive equivalents of a polyhydric phenol, and (c) between 0.005 and 0.025 reactive equivalents of an amine-epoxy adduct, wherein the amine-epoxy adduct is formed upon contacting 1.0 equivalents of an aliphatic polyepoxide and between 0.3 and 0.9 reactive equivalents of a polyoxyalkyleneamine. The self-dispersing curable epoxy resin forms an aqueous dispersion upon mixing with water. When cured, the dispersion is useful as a coating composition.Type: GrantFiled: June 14, 1994Date of Patent: October 15, 1996Assignee: Henkel CorporationInventors: John G. Papalos, Reuben H. Grinstein, Shailesh Shah, Joseph L. Mulvey, Brian G. Jewell
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Patent number: 4800229Abstract: Reactive dispersants for magnetic recording media are prepared by sequentially phosphating and esterifying or esterifying and phosphating alkoxylated alcohols having at least two carbon atoms and at least two hydroxyl groups. The phosphating agent can be phosphorus oxychloride while the esterifying agent can be acrylic acid.Type: GrantFiled: January 12, 1988Date of Patent: January 24, 1989Assignee: Diamond Shamrock Chemical CompanyInventor: John G. Papalos
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Patent number: 4770952Abstract: Reactive dispersants for magnetic recording media are prepared by sequentially phosphating and esterifying or esterifying and phosphating alkoxylated alcohols having at least two carbon atoms and at least two hydroxyl groups. The phosphating agent can be phosphorus oxychloride while the esterifying agent can be acrylic acid.Type: GrantFiled: July 10, 1987Date of Patent: September 13, 1988Assignee: Diamond Shamrock Chemicals CompanyInventor: John G. Papalos
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Patent number: 4514189Abstract: Particulate carbonaceous materials water mixtures are prepared by adding a condensate which is a condensation product of(a) an aldehyde having from about 1 to about 7 carbon atoms,(b) a benzene derivative such as benzene sulfonic acid, an alkyl benzene sulfonic acid having at least one alkyl group of from about 1 to about 20 carbon atoms and mixtures thereof, and optionally,(c) a naphthalene derivative such as naphthalene sulfonic acid, an alkyl naphthalene sulfonic acid having at least one alkyl group of from about 1 to about 12 carbon atoms and mixtures thereof.The condensate is added in an amount sufficient to reduce viscosity of the water mixture of carbonaceous materials, to stabilize carbonaceous materials in the water network and to improve pumpability. An acid form of the condensate or a salt may be added.Type: GrantFiled: February 24, 1983Date of Patent: April 30, 1985Assignee: Diamond Shamrock Chemicals CompanyInventors: John G. Papalos, Joseph V. Sinka
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Patent number: 4479826Abstract: A dispersing agent which is(a) a condensation product of a substituted phenol sulfonic acid which is an arylphenol sulfonic acid or an aralkylphenol sulfonic acid with from about 0.5 to about 4 moles of formaldehyde per mole of substituted phenol sulfonic acid, or(b) a condensation product of (i) a substituted phenol sulfonic acid which is an arylphenol sulfonic acid or an aralkylphenol sulfonic acid and (ii) an aryl sulfonic acid with from about 0.5 to about 4 moles of formaldehyde per mole of substituted phenol sulfonic acid and aryl sulfonic acid wherein the weight ratio of substituted phenol sulfonic acid to aryl sulfonic acid is from about 0.95:0.05 to about 0.05:0.95.The dispersing agent may be used directly or reacted with a salt forming cation to obtain a salt. The condensation product is useful as a dispersing agent in hydraulic cement, mortar, concrete or the like.Type: GrantFiled: March 23, 1984Date of Patent: October 30, 1984Assignee: Diamond Shamrock Chemicals CompanyInventors: John G. Papalos, Arpad Savoly
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Patent number: 4457762Abstract: Improved stabilized water slurries of carbonaceous materials are obtained by having present a condensation product or a salt thereof of a substituted phenol sulfonic acid which is(a) an arylphenol sulfonic acid,(b) an aralkylphenol sulfonic acid,(c) an arylphenol sulfonic acid and arylsulfonic acid mixture, or(d) an aralkylphenol sulfonic acid and arylsulfonic acid mixture,condensed with from about 0.5 to about 4.0 moles of formaldehyde per mole of sulfonic acid with the proviso that the weight ratio if substituted phenol sulfonic acid to arylsulfonic acid is from about 0.95:0.05 to about 0.05:0.95 in the mixtures, the condensation product being present in an amount sufficient to reduce viscosity of the water slurry of carbonaceous materials, to stabilize carbonaceous materials in the water network and to improve its pumpability. If desired, an acid form or a salt of the condensation product may be used.Type: GrantFiled: January 7, 1983Date of Patent: July 3, 1984Assignee: Diamond Shamrock Chemicals CompanyInventors: John G. Papalos, Jose L. Villa, Kathy A. Knitter, Arpad Savoly
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Patent number: 4457874Abstract: A dispersing agent which is(a) a condensation product of a substituted phenol sulfonic acid which is an arylphenol sulfonic acid or an aralkylphenol sulfonic acid with from about 0.5 to about 4 moles of formaldehyde per mole of substituted phenol sulfonic acid, or(b) a condensation product of (i) a substituted phenol sulfonic acid which is an arylphenol sulfonic acid or an aralkylphenol sulfonic acid and (ii) an aryl sulfonic acid with from about 0.5 to about 4 moles of formaldehyde per mole of substituted phenol sulfonic acid and aryl sulfonic acid wherein the weight ratio of substituted phenol sulfonic acid to aryl sulfonic acid is from about 0.95:0.05 to about 0.05:0.95.The dispersing agent may be used directly or reacted with a salt forming cation to obtain a salt. The condensation product is useful as a dispersing agent in hydraulic cement, mortar, concrete or the like.Type: GrantFiled: July 9, 1982Date of Patent: July 3, 1984Assignee: Diamond Shamrock Chemicals CompanyInventors: John G. Papalos, Arpad Savoly
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Patent number: 4297259Abstract: A condensation product of naphthalenesulfonic acid and linear alkylbenzenesulfonic acid having an alkyl moiety of from about 4 to about 20 carbon atoms with formaldehyde or salt thereof is useful as a secondary emulsifier and co-emulsifier in synthetic polymer latex processes. From about 0.05 to about 5 parts by weight of the condensation product per 100 parts by weight of latex monomer is used as a secondary emulsifier and from about 0.5 to about 5 parts by weight of the condensation product per 100 parts by-weight of latex monomer is used as a co-emulsifier. Additionally, products can be prepared which have been found to be biodegradable. Use of these condensation products eliminates pollution caused by a secondary emulsifier or co-emulsifier in polymer manufacture effluent.Type: GrantFiled: May 7, 1980Date of Patent: October 27, 1981Assignee: Diamond Shamrock CorporationInventors: John G. Papalos, Ronald W. Kavchok
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Patent number: 4256871Abstract: A condensation product of naphthalenesulfonic acid and linear alkyl benzenesulfonic acid having an alkyl moiety of from about 4 to about 20 carbon atoms with formaldehyde or salt thereof is useful as a secondary emulsifier and co-emulsifier in synthetic polymer latex processes. From about 0.05 to about 5 parts by weight of the condensation product per 100 parts by weight of latex monomer is used as a secondary emulsifier and from about 0.5 to about 5 parts by weight of the condensation product per 100 parts by weight of latex monomer is used as a co-emulsifier. Additionally, products can be prepared which have been found to be biodegradable. Use of these condensation products eliminates pollution caused by a secondary emulsifier or co-emulsifier in polymer manufacture effluent.Type: GrantFiled: April 18, 1979Date of Patent: March 17, 1981Assignee: Diamond Shamrock CorporationInventors: John G. Papalos, Ronald W. Kavchok
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Patent number: 4110367Abstract: The novel compounds, sulfonated alkylphenoxy acetones. In dyeing nylon textiles, with acid dyes, barre' is reduced by using these novel compounds as a dye leveler.Type: GrantFiled: February 2, 1976Date of Patent: August 29, 1978Assignee: Diamond Shamrock CorporationInventor: John G. Papalos
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Patent number: H1712Abstract: Radiation-curable compositions containing monoalkyl or mono-aralkyl ether di-acrylates or di-methacrylates of particular ethoxylated and/or propoxylated polyols of formulae I and II have been developed. These polyol derivatives substituted with hydrophobic ether functionalities constitute UV-curable diluents that can be isolated in excellent yields with minimal losses during the manufacturing process.Type: GrantFiled: June 8, 1994Date of Patent: February 3, 1998Assignee: Henkel CorporationInventors: John G. Papalos, Joseph V. Sinka