Abstract: A catalytically active surface is provided on the clean, combustion-exposed parts of an internal combustion engine that is green, has low operating hours, or is of modern, low emission design. A substrate or thermal barrier coat of high surface area and preferably capable of maintaining a surface temperature of at least 450° C. is deposited in the combustion chamber. Zirconia, silica, or lube oil ash are suitable. A catalytically active moiety such as platinum or iron is dispersed in, on, or with the combustion facing surface of the substrate. Nanophase iron from ferrocene or nanophase platinum are suitable. Catalytic action is maintained by continuously providing a low level of catalytic precursor to the engine in the combustion charge.

Abstract: A catalytically active surface is provided on the clean, combustion-exposed parts of an internal combustion engine that is green, has low operating hours, or is of modern, low emission design. A substrate or thermal barrier coat of high surface area and preferably capable of maintaining a surface temperature of at least 450° C. is deposited in the combustion chamber. Zirconia, silica, or lube oil ash are suitable. A catalytically active moiety such as platinum or iron is dispersed in, on, or with the combustion facing surface of the substrate. Nanophase iron from ferrocene or nanophase platinum are suitable. Catalytic action is maintained by continuously providing a low level of catalytic precursor to the engine in the combustion charge.

Abstract: A passive ferrocene injection system provides a container that defines an internal reservoir holding a quantity of solid phase ferrocene. A means is provided for maintaining an elevated reservoir temperature sufficient to produce a vapor of ferrocene. The reservoir is connected to the air inlet system of a combustion device in such a manner that the ferrocene vapor is metered into the air inlet stream. One portion of this connection is a flow orifice metering ferrocene vapor from the reservoir at least by diffusion, and more normally, by diffusive and convective transport mechanisms.

Abstract: A method of conditioning diesel engines is described. In accordance with the method, a diesel engine is operated on a diesel fuel containing from about 20-30 ppm of dicyclopentadienyl iron or an equivalent amount of a derivative thereof for a period of time sufficient to eliminate carbon deposits from the combustion surfaces of the engine and to deposit a layer of iron oxide on the combustion surfaces, which layer is effective to prevent further buildup of carbon deposits, and subsequently the diesel engine is operated on a maintenance concentration of from about 10-15 ppm of dicyclopentadienyl iron or an equivalent amount of a derivative thereof on a continuous basis. The maintenance concentration is effective to maintain the catalytic iron oxide layer on the combustion surfaces but insufficient to decrease timing delay in the engine.

Abstract: Flexible polyvinyl chloride having improved flame retardancy and reduced smoke generating properties. The plastics are characterized in that they contain about from 0.01 to 0.2 parts, by wt., based on the iron content, of a high molecular weight ferrocene derivative and about 0.1 to 20 parts, by wt., of antimony oxide per 100 parts of polyvinyl chloride resin. A composition comprising the ferrocene derivative and antimony oxide useful for preparing the improved plastic is also disclosed.

Abstract: Polyurethane plastics having improved smoke supression properties due to the incorporation therein of small amount of dicyclopentadienyl iron, or derivatives thereof, in chemically uncombined form. The improved polyurethane plastics are prepared by simple physical admixture of the dicyclopentadienyl iron, or derivatives thereof, in the plastic.

Abstract: The use of dicyclopentadienyl iron, or derivatives thereof, in physical mixture with polyvinyl chloride plastics to produce polyvinyl chloride plastic having reduced smoke generating properties.