Patents by Inventor Jorg Gitzel
Jorg Gitzel has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 5693867Abstract: Tetraphenylborates are obtained in an industrially advantageous grade by spray drying an organic, aqueous or organic-aqueous extract of the tetraphenylborates obtainable in the tetraphenylborates synthesis. It is advantageous to treat the specified extract prior to spray drying with pH-controlling auxiliaries and adsorbents to remove byproducts or to limit their formation. The process gives tetraphenylborates in a homogeneous technical grade, i.e. in a narrow particle size distribution and in a particular particle shape, which improves the dispersibility in the medium to be used.Type: GrantFiled: August 29, 1996Date of Patent: December 2, 1997Assignee: Hoechst AktiengesellschaftInventors: Rudiger Baur, Hermann Fuchs, Hans-Tobias Macholdt, Jorg Gitzel, Wilfried Theiss
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Patent number: 5401809Abstract: Polymer ammonium borates having a molecular weight from about 5000 to about 500,000 and obtained by homopolymerization of monomers, such as, for example, diallyldialkylammonium chloride, and by copolymerization of mixtures of two monomers, such as, for example, diallyldimethylammonium chloride and diallylmethyloctylammonium chloride, having molar monomer ratios of about 0.5:0.5 to about 0.95:0.05 in the copolymer, followed, if desired, by anion exchange, and mixtures of these compounds. Polymer ammonium borates according to the invention are suitable as colorless charge-control agents in toners and developers for electrophotographic recording processes and as charge-improving agents in powders and coatings for surface coating.Type: GrantFiled: December 3, 1993Date of Patent: March 28, 1995Assignee: Hoechst AktiengesellschaftInventors: Jorg Gitzel, Detlef Wehle, Hans-Tobias Macholdt
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Patent number: 5342723Abstract: Use of biscationic acid imide and acid imide derivatives whose anion is the stoichiometric equivalent of one or more organic or inorganic, mixed or non-mixed anions, the compounds also being able to exist as mixed crystals with different cations, individually or in combination, as charge controllers for toners and developers employed for electrophotographic copying or multicopying of originals and for printing electronically, optically or magnetically stored data or in color proofing, and as charge controllers for powders and powder paints.Type: GrantFiled: June 25, 1992Date of Patent: August 30, 1994Assignee: Hoechst AktiengesellschaftInventors: Hans-Tobias Macholdt, Siegfried Schiebler, Jorg Gitzel, Erwin Dietz
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Patent number: 5329046Abstract: The invention relates to biscationic acid amide and acid imide derivatives with an anion of formula (BR.sub.9 R.sub.10 R.sub.11 R.sub.12)--, where R.sub.9 to R.sub.12 are aliphatic, iso- or heterocyclic aromatic residues or aralkyl residues, which may be substituted by C.sub.1 -C.sub.4 -alkyl residues, C.sub.1 -C.sub.4 -alkoxy residues, aryl residues or halogen atoms (e.g. fluorine atoms), and mixtures of these compounds and mixed crystals with mixed anions and/or cations. The invention also relates to a process for preparing them. The new compounds are excellent colorless charge controllers in toners and developers for electrophotographic recording and as charge-enhancers in powders and paints for surface coating, in particular in triboelectrically or electrokinetically sprayed powder paints.Type: GrantFiled: June 25, 1992Date of Patent: July 12, 1994Assignee: Hoechst AktiengesellschaftInventors: Hans-Tobias Macholdt, Siegfried Schiessler, Jorg Gitzel, Erwin Dietz
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Patent number: 5187038Abstract: Use of polymeric ammonium salts which have a molecular weight of about 5000 to about 500,000, and are obtained by homopolymerization of monomers, such as, for example, diallyldialkylammonium chloride, or by copolymerization of mixtures of two monomers, such as, for example, diethyldimethylammonium chloride and diallylmethyloctylammonium chloride, with molar monomer ratios of about 0.5:0.5 to about 0.95:0.05 in the copolymer, and if appropriate subsequent anion exchange, individually or in combination as charge control agents in electrophotographic toners and developers which are employed for copying or duplicating masters and for printing electronically, magnetically or optically stored information or in colorproofing, and as charge control agents in powders and powder coatings.Type: GrantFiled: September 17, 1991Date of Patent: February 16, 1993Assignee: Hoechst AktiengesellschaftInventors: Jorg Gitzel, Detlef Wehle, Hans-Tobias Macholdt
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Patent number: 5147748Abstract: Use of colorless highly fluorine-substituted phosphonium compounds as charge control agents for electrophotographic recording processesUse of highly fluorine-substituted phosphonium compounds of the formula (I) ##STR1## in which R.sub.1 to R.sub.4 are hydrogen atoms or organic radicals, at least one of the radicals R.sub.1 to R.sub.4 being a fluorine-substituted, unsaturated and/or saturated alkyl radical having 1 to 30 carbon atoms and 3 to 50 fluorine atoms, which can contain further substituents, or a fluorine-substituted aryl radical or an aralkyl radical which is fluorine-substituted on the aromatic ring, it being possible for the aryl or aralkyl radical to be additionally substituted on the aromatic ring, and in the case of an aralkyl radical the alkyl bridge between the phosphorus atom and the aromatic ring contains 1 to 30 carbon atoms, and not more than three of the radicals R.sub.1 and R.sub.Type: GrantFiled: April 12, 1990Date of Patent: September 15, 1992Assignee: Hoechst AktiengesellschaftInventors: Jorg Gitzel, Hans-Tobias Macholdt, Wolfgang Knaup
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Patent number: 5069994Abstract: The use of intensely fluorinated ammonium compounds of the general formula (I) ##STR1## in which R.sub.1 to R.sub.4 denote hydrogen atoms or organic radicals, at least one of the radicals R.sub.1 to R.sub.4 denoting a straight-chain or branched fluorine-containing alkyl radical or fluorine-containing alkenyl radical which contains 1 to 69 carbon atoms and 3 to 66 fluorine atoms and which may be substituted, and at most three of the radicals R.sub.1 to R.sub.4 are, independently of one another, hydrogen atoms, straight-chain or branched alkyl radicals or alkenyl radicals containing 1 to 30 carbon atoms, aryl radicals or aralkyl radicals, and X.sup.- denotes an organic or inorganic anion, and of intensely fluorinated iminium compounds of the general formula (II) ##STR2## in which R.sub.9 to R.sub.12 denote hydrogen atoms or organic radicals, at least one of the radicals R.sub.9 to R.sub.Type: GrantFiled: November 2, 1989Date of Patent: December 3, 1991Assignee: Hoechst AktiengesellschaftInventors: Jorg Gitzel, Hans-Tobias Macholdt, Alexander Sieber, Frank Wehowsky, Gunther Prossel
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Patent number: 5055619Abstract: Phosphonium compounds of formula (I): ##STR1## in which at least one of the radicals R.sub.1 to R.sub.4 is a fluorine-substituted, saturated alkyl radical having 1 to 30 carbon atoms and 3 to 50 fluorine atoms, which can contain further substituents, or at least one of the radicals R.sub.1 to R.sub.4 is a fluorine-substituted aryl radical or an aralkyl radical substituted by fluorine on the aromatic ring, it being possible for the aryl or aralkyl radical to be further substituted on the aromatic ring, and the alkyl bridge between the phosphorus atom and the aromatic ring, in the case of an aralkyl radical, containing 1 to 30 carbon atoms, and at most three of the radicals R.sub.1 to R.sub.4 independently of the others are hydrogen atoms, unsaturated or saturated, substituted or unsubstituted C.sub.1 -C.sub.30 alkyl radicals or aryl or aralkyl radicals which can be substituted on the aromatic ring, and R.sub.5 to R.sub.Type: GrantFiled: April 12, 1990Date of Patent: October 8, 1991Assignee: Hoechst AktiengesellschaftInventors: Jorg Gitzel, Hans-Tobias Macholdt, Wolfgang Knaup
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Patent number: 5053537Abstract: Ammonium compounds of the formula (I) ##STR1## in which at least one of the radicals R.sub.1 to R.sub.4 denotes a fluorine-containing alkyl radical having 4 to 30 carbon atoms and not more than three of the radicals R.sub.1 to R.sub.4 independently of one another denote hydrogen atoms or alkyl or hydroxyalkyl radicals having 1 to 30 carbon atoms, and R.sub.5 to R.sub.8 denote aryl, alkylaryl or halogenoaryl radicals or fluorine atoms, and iminium compounds of the formula (II) ##STR2## in which Q, together with the constituent ##STR3## forms a ring system having 4 to 17 carbon atoms, which can be interrupted by 1 to 4 hetero atoms and contain 2 to 9 double bonds, and which can be substituted by fluorine, chlorine, bromine or iodine atoms or alkyl (C.sub.1 -C.sub.6), alkoxy (C.sub.1 -C.sub.6), nitro or amino groups, R.sub.9 denotes a fluorine-containing alkyl (C.sub.1 -C.sub.30) radical, R.sub.10 denotes a hydrogen, fluorine, chlorine, bromine or iodine atom or an alkyl(C.sub.1 -C.sub.6), alkoxy (C.sub.1 -C.Type: GrantFiled: November 2, 1989Date of Patent: October 1, 1991Assignee: Hoechst AktiengesellschaftInventors: Jorg Gitzel, Hans-Tobias Macholdt, Frank Wehowsky, Gunther Prossel