Patents by Inventor José Luis Garcia Fierro

José Luis Garcia Fierro has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 11253847
    Abstract: The invention relates to a method for producing catalysts by the method of combustion in solution, to the catalysts produced by said method, and to the particular use thereof in the reverse water-gas shift reaction and in the partial oxidation of the methane into synthesis gas. Therefore, it is understood that the present invention pertains to the area of the green industry aimed at the reduction of CO2 on the planet.
    Type: Grant
    Filed: December 28, 2017
    Date of Patent: February 22, 2022
    Assignees: CONSEJO SUPERIOR DE INVESTIGACIONES CIENTIFICAS (CSIC), CONSEJO NATIONAL DE INVESTIGACIONES CIENTICAS Y TECNICAS (CONICET)
    Inventors: María Consuelo Álvarez Galván, Martín Dapena Ospina, José Antonio Alonso Alonso, Loreto Troncoso Aguilera, Vanesa Cascos Jiménez, José Miguel Campos Martín, José Luis García Fierro, Horacio Falcón Richeni
  • Publication number: 20200406246
    Abstract: The invention relates to a method for producing catalysts by the method of combustion in solution, to the catalysts produced by said method, and to the particular use thereof in the reverse water-gas shift reaction and in the partial oxidation of the methane into synthesis gas. Therefore, it is understood that the present invention pertains to the area of the green industry aimed at the reduction of CO2 on the planet.
    Type: Application
    Filed: December 28, 2017
    Publication date: December 31, 2020
    Inventors: María Consuelo ÁLVAREZ GALVÁN, Martín DAPENA OSPINA, José Antonio ALONSO ALONSO, Loreto TRONCOSO AGUILERA, Vanesa CASCOS JIMÉNEZ, José Miguel CAMPOS MARTÍN, José Luis GARCÍA FIERRO, Horacio FALCÓN RICHENI
  • Patent number: 9610573
    Abstract: A catalyst support comprising a material functionalized with at least one acid group and at least one halogen atom; and a supported catalyst comprising (i) a catalyst and (ii) the catalyst support comprising the functionalized material, as well as their uses in production of hydrogen peroxide. A process for producing hydrogen peroxide, comprising reacting hydrogen and oxygen in the presence of the supported catalyst comprising the functionalized material, optionally with the addition of an inert gas, in a reactor.
    Type: Grant
    Filed: July 9, 2012
    Date of Patent: April 4, 2017
    Assignee: SOLVAY SA
    Inventors: Gema Blanco Brieva, Jose Miguel Campos Martin, Jose Luis Garcia Fierro, Manuel Montiel Argaiz, Roberto Garaffa, Francine Janssens
  • Publication number: 20140154168
    Abstract: A catalyst support comprising a material functionalized with at least one acid group and at least one halogen atom; and a supported catalyst comprising (i) a catalyst and (ii) the catalyst support comprising the functionalized material, as well as their uses in production of hydrogen peroxide. A process for producing hydrogen peroxide, comprising reacting hydrogen and oxygen in the presence of the supported catalyst comprising the functionalized material, optionally with the addition of an inert gas, in a reactor.
    Type: Application
    Filed: July 9, 2012
    Publication date: June 5, 2014
    Applicant: SOLVAY SA
    Inventors: Gema Blanco Brieva, Jose Miguel Campos Martin, Jose Luis Garcia Fierro, Manuel Montiel Argaiz, Roberto Garaffa, Francine Janssens
  • Patent number: 8575387
    Abstract: The present invention relates to a method for preparing carboxylic acids comprising the step of contacting an aromatic hydrocarbon comprising at least one group including an ? C-atom that is oxidizable to a carboxylic group in liquid phase with an oxygen containing gas in the presence of a heterogeneous catalyst with perovskite structure ABO3 with A being selected from at least one element of groups 1 to 3 of the Periodic Table, lanthanides or actinides, and B being selected from at least one element of the groups 4 to 15 of the periodic table or an oxygen-defective derivative of that catalyst having the formula ABO3?? with 0<?<1.
    Type: Grant
    Filed: May 25, 2012
    Date of Patent: November 5, 2013
    Assignee: King Saud University
    Inventors: Saeed Mohammed Al-Zahrani, Horacio Falcon Richeni, Ainara Aguadero Garin, Jose Antonio Alonso Alonso, Jose Miguel Campos Martin, Jose Luis Garcia Fierro
  • Publication number: 20130144084
    Abstract: The present invention relates to a method for preparing carboxylic acids comprising the step of contacting an aromatic hydrocarbon comprising at least one group including an ? C-atom that is oxidizable to a carboxylic group in liquid phase with an oxygen containing gas in the presence of a heterogeneous catalyst with perovskite structure ABO3 with A being selected from at least one element of groups 1 to 3 of the Periodic Table, lanthanides or actinides, and B being selected from at least one element of the groups 4 to 15 of the periodic table or an oxygen-defective derivative of that catalyst having the formula ABO3?? with 0<?<1.
    Type: Application
    Filed: May 25, 2012
    Publication date: June 6, 2013
    Applicant: KING SAUD UNIVERSITY
    Inventors: Saeed Mohammed AI-Zahrani, Horacio Falcon Richeni, Ainara Aguadero Garin, Jose Antonio Alonso Alonso, Jose Miguel Campos Martin, Jose Luis Garcia Fierro
  • Publication number: 20100213075
    Abstract: The invention relates to a reactor for the electrochemical treatment of biomass, including at least two flat surface electrodes positioned equidistantly over the entire surface and separated by less than 1 mm, the space between said electrodes being occupied by a electrolytic solution. Preferably, at least one of the electrodes is an anode and at least one of the electrodes is a cathode. The anode is preferably made from a material selected from among vanadium, selenium, gold, silver, nickel, graphite, graphite galvanised with platinum and graphite galvanised with palladium. The invention also relates to the use of said reactor in electrooxidation reactions involving biomass, particularly polysaccharides, in the production of organic compounds, water electrolysis, hydrogen production or the production of electrochemical cells.
    Type: Application
    Filed: November 8, 2007
    Publication date: August 26, 2010
    Inventors: Domingo Guinea Díaz, José Luis Garcia Fierro, Rufino Manuel Navarro Yerga, José Ramón Jurado Egea, Heli Ricardo Rodríguez Rodríguez
  • Publication number: 20080299034
    Abstract: The present invention relates to a process for preparing hydrogen peroxide by reacting hydrogen and oxygen in the presence of a solvent and of a catalyst, wherein the catalyst comprises at least one noble or semi-noble metal supported on an inorganic material functionalized with acid groups. The invention also refers to the catalyst used in this process.
    Type: Application
    Filed: May 30, 2008
    Publication date: December 4, 2008
    Applicant: Repsol YPF, S.A.
    Inventors: Pilar De Frutos Escrig, Jose Manuel Riesco Garcia, Jose Miguel Campos Martin, Jose Luis Garcia Fierro, Encarnacion Cano Serrano, Gema Blanco Brieva
  • Patent number: 7179440
    Abstract: In this invention, a process to obtain hydrogen peroxide solutions by means of the direct reaction of hydrogen and oxygen in the presence of a solvent and of catalysts constituted from noble or semi-noble metals, or combinations of several of these metals, supported on a halogen-free acid resin, is described.
    Type: Grant
    Filed: March 13, 2003
    Date of Patent: February 20, 2007
    Assignee: Repsol Quimica, S.A.
    Inventors: Pilar De Frutos Escrig, Jose Miguel Campos Martin, Jose Luis Garcia Fierro, Encapnacion Cano Serrano, Gema Blanco Brieva
  • Patent number: 7105137
    Abstract: The invention relates to a novel catalyst having excellent activity, selectivity and stability for reducing nitric oxide to gas nitrogen, with hydrogen being used as a reducing agent, in the low temperature range 100–200° C. and in the presence of an excess of oxygen (e.g. 5% vol), H2O (5% vol) and/or SO2 (20 ppm) in the supply. The inventive catalyst consists of platinum crystals which are in contact with the phases of a mixed MgO and CeO2 medium or in the form of platinum supported on the mixed MgO—CeO2 medium which has already been sulphated in a selective manner. The Pt/MgO—CeO2 catalyst can be used to obtain NO conversion levels which are greater than 40% and nitrogen selectivity values of greater than 80% under NOx oxidation conditions in the 100–400° C. temperature range and for a surface contact time of 0.045 s. In particular, full NO conversion is obtained as well as N2 selectivity levels of 83% at 150° C. with a reaction mixture of 0.25% NO/1% H2/5% O2/5% H2O/He.
    Type: Grant
    Filed: August 11, 2004
    Date of Patent: September 12, 2006
    Assignees: Consejo Superior de Investigaciones Cientificas, Universidad de Chipre
    Inventors: Angelos M. Efstathiou, Costas N. Costa, José Luis Garcia Fierro
  • Patent number: 7038089
    Abstract: The invention relates to a process for preparing hydroperoxides from their corresponding hydrocarbons which comprises oxidizing said hydrocarbons, particularly ethylbenzene, with an oxygen containing gas in the presence of a catalyst comprising a cyclic imide compound and a compound selected from the group consisting of an alkali metal compound or mixture thereof.
    Type: Grant
    Filed: January 22, 2004
    Date of Patent: May 2, 2006
    Assignee: Respol Quimica, S.A.
    Inventors: Pilar De Frutos Escrig, Pedro Pablo Toribio Temprado, Raul Martos Calvente, Jose Miguel Campos Martin, Jose Luis Garcia Fierro
  • Patent number: 6822103
    Abstract: Oxidized compounds are produced in a continuous integrated process in liquid phase, which comprises: Step I, synthesis of non acidic hydrogen peroxide solutions by direct reaction between hydrogen and oxygen by catalytic reaction utilizing a noble metal catalyst. Step II, this hydrogen peroxide solution is directly mixed with an organic substrate, a suitable catalyst and optionally a solvent. The integrated process requires no treatment step and is particularly well adapted to the production of propylene oxide.
    Type: Grant
    Filed: June 3, 2003
    Date of Patent: November 23, 2004
    Assignee: Repsol Quimica, S.A.
    Inventors: Pilar De Frutos Escrig, Ana Padilla Polo, Jose Manuel Riesco Garcia, Jose Miguel Campos Martin, Gema Blanco Brieva, Encarnacion Cano Serrano, MaDel Carmen Capel Sanchez, Jose Luis Garcia Fierro
  • Publication number: 20040151658
    Abstract: Oxidized compounds are produced in a continuous integrated process in liquid phase, which comprises: Step I, synthesis of non acidic hydrogen peroxide solutions by direct reaction between hydrogen and oxygen by catalytic reaction utilizing a noble metal catalyst. Step II, this hydrogen peroxide solution is directly mixed with an organic substrate, a suitable catalyst and optionally a solvent. The integrated process requires no treatment step and is particularly well adapted to the production of propylene oxide.
    Type: Application
    Filed: June 3, 2003
    Publication date: August 5, 2004
    Applicant: REPSOL QUIMICA, S.A.
    Inventors: Pilar De Frutos Escrig, Ana Padilla Polo, Jose Manuel Riesco Garcia, Jose Miguel Campos Martin, Gema Blanco Brieva, Encarnacion Cano Serrano, Ma Del Carmen Capel Sanchez, Jose Luis Garcia Fierro
  • Publication number: 20030216255
    Abstract: The method consists of placing in contact methanol, oxygen and optionally water with a catalyst consisting of copper (II) oxide, zinc (II) oxide, aluminium (III) oxide and copper (II) and aluminium (III) spinel, with the following molar percentages of the metals with respect to the total: Cu (15-75%). Zn (5-60%) and Al (3-50%). The catalyst is obtained by adding urea to a solution of water-soluble salts of copper (II), zinc (II) and aluminium (III) by co-precipitation of the components.
    Type: Application
    Filed: December 19, 2002
    Publication date: November 20, 2003
    Inventors: Sonia Murcia Mascaros, Luisa-Maria Gomez Sainero, Jose-Luis Garcia Fierro, Miguel-Antonio Pena Jimenez, Umberto-Michele Costantino, Morena Nocchetti
  • Publication number: 20030215383
    Abstract: In this invention, a process to obtain hydrogen peroxide solutions by means of the direct reaction of hydrogen and oxygen in the presence of a solvent and of catalysts constituted from noble or semi-noble metals, or combinations of several of these metals, supported on a halogen-free acid resin, is described.
    Type: Application
    Filed: March 13, 2003
    Publication date: November 20, 2003
    Inventors: Pilar De Frutos Escrig, Jose Miguel Campos Martin, Jose Luis Garcia Fierro, Encapnacion Cano Serrano, Gema Blanco Brieva