Abstract: A marking composition for forming marks or indicia on a substrate is provided for laser marking applications. The composition includes a glass frit, a carrier, and absorber particles. The glass frit includes alkali metal oxides, glass forming oxides, and one or more transition metal oxides. The glass frit is devoid of at least one of bismuth and zinc.

Abstract: A compounded polymer material that can be laser marked is provided. The compounded polymer material includes an enhancer of nitrides, carbides, silicides, or combinations thereof. Upon forming the compounded polymer material into an article and exposing it to laser radiation, the irradiated portion of the compounded polymer material absorbs the laser radiation, increases in temperature, and forms a mark in the article. A lightness value difference (?L) between the mark and the non-irradiated portion of the article has an absolute value of at least 5, and the lightness value difference between the mark and the non-irradiated portion is greater than if the polymer material did not include the enhancer.

Abstract: A universal or all-purpose laser marking composition for forming satisfactorily dark laser marks on a wide variety of substrates is provided. The marking composition comprises an enhancer of nitrides, carbides, silicides, and combinations thereof. The enhancer may be selected one or more of ferromanganese, ferrosilicon, FexSi(1-x) where X can range from about 0.005 to 0.995, Fe5Si2, MgFeSi, SiC, CaSi, (Co)Mo, MoSi2, TiSi2, ZrSi2, WSi2, MnSi2, YSi, Cu5Si, Ni2Si, Fe3C, Fe7C3 and Fe2C, MoC, Mo2C, Mo3C2, YC2, WC, Al4C3, Mg2C, Mg2C3, CaC2, LaC2, Ta4C3, Fe2N, Fe3N, Fe4N, Fe7N3, Fe16N2, MoN, Mo2N, W2N, WN, WN2, and combinations thereof and combinations thereof.

Abstract: A universal or all-purpose laser marking composition for forming satisfactorily dark laser marks on a wide variety of substrates is provided. The marking composition comprises an enhancer of nitrides, carbides, silicides, and combinations thereof. The enhancer may be selected one or more of ferromanganese, ferrosilicon, FexSi(1-x) where X can range from about 0.005 to 0.995, Fe5Si2, MgFeSi, SiC, CaSi, (Co)Mo, MoSi2, TiSi2, ZrSi2, WSi2, MnSi2, YSi, Cu5Si, Ni2Si, Fe3C, Fe7C3 and Fe2C, MoC, Mo2C, Mo3C2, YC2, WC, Al4C3, Mg2C, Mg2C3, CaC2, LaC2, Ta4C3, Fe2N, Fe3N, Fe4N, Fe7N3, Fe16N2, MoN, Mo2N, W2N, WN, WN2, and combinations thereof and combinations thereof.

Abstract: A compounded polymer material that can be laser marked is provided. The compounded polymer material includes an enhancer of nitrides, carbides, silicides, or combinations thereof. Upon forming the compounded polymer material into an article and exposing it to laser radiation, the irradiated portion of the compounded polymer material absorbs the laser radiation, increases in temperature, and forms a mark in the article. A lightness value difference (?L) between the mark and the non-irradiated portion of the article has an absolute value of at least 5, and the lightness value difference between the mark and the non-irradiated portion is greater than if the polymer material did not include the enhancer.

Abstract: Various laser marking compositions and related methods are described. The laser marking compositions include a molybdenum metal complex, a tungsten metal complex, or combinations thereof. Marks or other indicia formed on a substrate using the compositions and methods exhibit increased contrast and improved substrate bonding.

Abstract: Various laser marking compositions and related methods are described. The laser marking compositions utilize one or more populations of particles having certain average particle sizes or a range of sizes. Marks or other indicia formed using the compositions and methods exhibit increased contrast, improved substrates bonding, and greater dispersability.

Abstract: Various laser marking compositions and related methods are described. The laser marking compositions include a molybdenum metal complex, a tungsten metal complex, or combinations thereof. Marks or other indicia formed on a substrate using the compositions and methods exhibit increased contrast and improved substrate bonding.

Abstract: Various laser marking compositions and related methods are described. The laser marking compositions include a molybdenum metal complex, a tungsten metal complex, or combinations thereof. Marks or other indicia formed on a substrate using the compositions and methods exhibit increased contrast and improved substrate bonding.

Abstract: Various laser marking compositions and related methods are described. The laser marking compositions utilize one or more populations of particles having certain average particle sizes or a range of sizes. Marks or other indicia formed using the compositions and methods exhibit increased contrast, improved substrates bonding, and greater dispersability.

Abstract: Various laser marking compositions and related methods are described. The laser marking compositions include a molybdenum metal complex, a tungsten metal complex, or combinations thereof. Marks or other indicia formed on a substrate using the compositions and methods exhibit increased contrast and improved substrate bonding.

Abstract: Polymer substrates are marked by a method in which certain graphite nanoplatelets are incorporated into the polymer composition, such as a coating or plastic article, prior to marking the composition by exposing selected portions of the substrate to a heat source, typically a laser. Additional pigments may also be present allowing for the production of a variety of different types of markings.

Abstract: An aqueous marking composition is described which upon application to a polymeric surface and laser irradiation, produces one or more marks or other indicia having high contrast in the polymeric surface.

Abstract: A method for laser marking a substrate which method comprises exposing a composition comprising a tetrabenzodiazadiketoperylene pigment to laser radiation to produce a fluorescent marking readily apparent under UV light is disclosed. Many of the tetrabenzodiazadiketoperylenes herein are novel. This method can yield fluorescent markings which are not readily apparent under ambient light. A method for producing non-fluorescent laser marked substrates containing tetrabenzodiazadiketoperylene dyes is also disclosed.

Abstract: A method for producing fluorescent markings on a substrate which method comprises exposing a composition comprising a polymer and an organic pigment to a heat source, such as laser radiation, to produce a fluorescent markings which are not discernable when viewed under ambient visible light but readily apparent under UV light is disclosed. The method produces novel compositions wherein a fluorescent form of a pigment is present at a higher concentration in defined domains relative to the remainder of the composition. The novel polymer composition is particularly useful in security marking applications.

Abstract: The present invention relates to additive, pigment or colorant materials which may be used for laser marking. The materials comprise oxides of bismuth and at least one additional metal. Preferred laser-markable bismuth-containing oxide compounds are of the formula BixMyOz, where M is at least one metal selected from Zn, Ti, Fe, Cu, Al, Zr, P, Sn, Sr, Si, Y, Nb, La, Ta, Pr, Ca, Mg, Mo, W, Sb, Cr, Ba and Ce, x is from about 0.3 to about 70, y is from about 0.05 to about 8, and z is from about 1 to about 100. The bismuth-containing material may be dispersed in a substrate which is subsequently irradiated by a laser to provide a contrasting mark in the irradiated region.

Abstract: The present invention relates to additive, pigment or colorant materials which may be used for laser marking. The materials comprise oxides of bismuth and at least one additional metal. Preferred laser-markable bismuth-containing oxide compounds are of the formula BixMyOz, where M is at least one metal selected from Zn, Ti, Fe, Cu, Al, Zr, P, Sn, Sr, Si, Y, Nb, La, Ta, Pr, Ca, Mg, Mo, W, Sb, Cr, Ba and Ce, x is from about 0.3 to about 70, y is from about 0.05 to about 8, and z is from about 1 to about 100. The bismuth-containing material may be dispersed in a substrate which is subsequently irradiated by a laser to provide a contrasting mark in the irradiated region.

Abstract: The present invention relates to additive, pigment or colorant materials which may be used for laser marking. The materials comprise oxides of bismuth and at least one additional metal. Preferred laser-markable bismuth-containing oxide compounds are of the formula BixMyOz, where M is at least one metal selected from Zn, Ti, Fe, Cu, Al, Zr, P, Sn, Sr, Si, Y, Nb, La, Ta, Pr, Ca, Mg, Mo, W, Sb, Cr, Ba and Ce, x is from about 0.3 to about 70, y is from about 0.05 to about 8, and z is from about 1 to about 100. The bismuth-containing material may be dispersed in a substrate which is subsequently irradiated by a laser to provide a contrasting mark in the irradiated region.

Abstract: Bismuth manganese oxide pigments are used as additives to various materials such as plastics, plastic or organic coating compositions, glass and ceramic coating compositions, and the like. The bismuth manganese oxide pigments preferably comprise Bi2Mn4O10 crystallized in the orthorhombic crystal structure. The pigments possess improved reflectance characteristics, particularly in the IR region, and may reduce IR-induced heat buildup.

Abstract: Bismuth manganese oxide green pigments are used as additives to various materials such as plastics, plastic or organic coating compositions, glass and ceramic coating compositions, and the like. The green bismuth manganese oxide pigments preferably comprise Bi12MnO20 crystallized in the cubic crystal structure. The pigments possess improved reflectance characteristics, particularly in the IR region, and may reduce IR-induced heat buildup.