Abstract: A method of making a multi-ply wiper/towel product with cellulosic microfibers. The method includes compactively dewatering a nascent web that includes at least about 10% fibrillated cellulosic microfibers and has an apparently random distribution of fibers. The dewatered web having the apparently random distribution of fibers is applied to a transfer surface. The web is belt-creped from the transfer surface utilizing a generally planar polymeric creping belt provided with a plurality of perforations through the belt. The belt-creping step occurs under pressure in a belt creping nip defined between the transfer surface and the creping belt. The web is dried to form a dried web that includes a plurality of fiber-enriched hollow domed regions protruding from an upper side of the dried web. The hollow domed regions have a sidewall of a relatively high local basis weight formed along at least a leading edge thereof.

Abstract: A multi-ply wiper/towel product includes at least one wet laid web including at least 10% fibrillated cellulosic microfiber, and at least about 40% wood pulp derived papermaking fibers. The at least one wet laid web has formed therein (i) a plurality of fiber-enriched hollow domed regions on the upper side of the at least one wet laid web having a relatively high local basis weight, and (ii) connecting regions of a relatively lower local basis weight forming a network interconnecting the relatively high local basis weight domed regions of the one wet laid web. Transition areas are provided in the at least one wet laid web with upwardly and inwardly inflected consolidated fibrous regions transitioning from the connecting regions into the domed regions, and the at least one wet laid web exhibits a differential pore volume for pores under 5 microns in a diameter of at least about 75 mm3/g/micron.

Abstract: A multi-ply absorbent towel made from papermaking fiber comprising at least a first ply and a second ply bonded together, the towel having a basis weight of greater than 30 lbs per 3000 ft2 ream (48.8 gsm) and less than 50 lbs per 3000 ft2 ream (81.4 gsm), wherein the plies are selected and adhered together such that the towel typically exhibits (i) a GM TEA, mm-g/mm2 of greater than [0.00125 (GM Tensile, g/3?)?0.75] and (ii) a GM Tensile Modulus, g/in/%, less than [0.0083 (GM Tensile Strength, g/3?)+15.4] {(i) a GM TEA, mm g/mm2, of greater than [0.00952 (GM Tensile, g/cm)?0.75] and (ii) a GM Tensile Modulus, g/cm/%, less than [0.0249 (GM Tensile Strength, g/cm)+6.06}.

Abstract: A soft and resilient, cold-water dispersible polyurethane foam suitable for disposable personal care products is produced by the combination of corn syrup, glycerin, polyether diamine, PEG, a diisocyanate, water and a catalyst. The formulation and reaction conditions for forming the inventive foam are judiciously selected and carefully controlled to achieve water dispersibility and the desired mechanical properties. The characteristic resiliency, or percent rebound for the foams was generally over 75% and the foams are readily produced as soft foams, exhibiting a relative compression value of from 20% to 150% of that of a commercial polyurethane foam cosmetic pad which is not water dispersible. The foam may be incorporated into webs or stackable products or nestable three-dimensional products.

Abstract: This invention relates to methods for producing cycloheptatriene from at least 7,7-dichloronorcarane and a liquid component comprising a C8 to C30 succinic anhydride, a carboxylic acid, or a C8 to C30 alkyldimethylamine at about 205 deg. C. to about 230 deg. C.

Abstract: A multi-ply bath tissue having no more than three plies and no fewer than two plies. The multi-ply tissue has a basis weight of from about 20 to about 35 lbs per 3000 sq foot ream and includes from about 3% to about 50% cellulosic microfiber, from about 50% to about 97% wood pulp fibers, has a geometric mean (GM) dry tensile of from about 17 to 80 g/3 in. per pound of basis weight, a cross-machine direction (CD) dry tensile of between about 30 to about 60 g/3 in. per pound of basis weight, and sufficient temporary wet strength resin to provide an initial Finch Cup CD wet tensile of from about 2.5 to about 20 g/3 in. per pound of basis weight. The initial Finch Cup CD wet tensile decays to less than 65% of the initial value in less than fifteen minutes after immersion in water. The product has a caliper of at least 5 mils per 8 sheets per pound of basis weight.

Abstract: An absorbent sheet of cellulosic fibers with upper and lower sides includes (i) a plurality of fiber-enriched hollow domed regions on the upper side of the sheet having a relatively high local basis weight, (ii) connecting regions of relatively lower local basis weight forming a network interconnecting the relatively high local basis weight domed regions of the sheet, and (iii) transition areas with upwardly and inwardly inflected consolidated fibrous regions transitioning from the connecting regions into the domed regions.

Abstract: A method of making a belt-creped absorbent cellulosic sheet. A paper making furnish is compactively dewatered to form a dewatered web having an apparently random distribution of papermaking fiber orientation. The dewatered web is applied to a translating transfer surface that is moving at a transfer surface speed. The web is belt-creped from the transfer surface at a consistency of from about 30% to about 60% utilizing a generally planar polymeric creping belt having a plurality of perforations, under pressure, in a belt creping nip defined between the transfer surface and the creping belt. The belt travels at a belt speed that is slower than the speed of the transfer surface. The web is creped from the transfer surface and redistributed on the creping belt to form a web having a plurality of interconnected regions of different local basis weights. The web is then dried.

Abstract: A soft and resilient, cold-water dispersible polyurethane foam suitable for disposable personal care products is produced by the combination of corn syrup, glycerin, polyether diamine, PEG, a diisocyanate, water and a catalyst. The formulation and reaction conditions for forming the inventive foam are judiciously selected and carefully controlled to achieve water dispersibility and the desired mechanical properties. The characteristic resiliency, or percent rebound for the foams was generally over 75% and the foams are readily produced as soft foams, exhibiting a relative compression value of from 20% to 150% of that of a commercial polyurethane foam cosmetic pad which is not water dispersible. The foam may be incorporated into webs or stackable products or nestable three-dimensional products.

Abstract: A high efficiency disposable cellulosic wiper includes (a) pulp-derived papermaking fiber; (b) up to 75% by weight regenerated cellulosic microfiber having a characteristic CSF value of less than 175 ml, the microfiber being selected and present in amounts such that the wiper exhibits a Laplace pore volume fraction at pore sizes less than 15 microns of at least 1.5 times that of a like wiper prepared without regenerated cellulose microfiber. The wipers of the invention exhibit remarkable residue removal efficiency.

Abstract: An absorbent paper sheet includes cellulosic papermaking fiber and up to about 75 percent by weight fibrillated regenerated cellulose microfiber which may be regenerated from a cellulosic dope utilizing a tertiary amine N-oxide solvent or selected ionic liquids.

Abstract: A high efficiency disposable cellulosic wiper includes (a) pulp-derived papermaking fiber; (b) up to 75% by weight regenerated cellulosic microfiber having a characteristic CSF value of less than 175 ml, the microfiber being selected and present in amounts such that the wiper exhibits a Laplace pore volume fraction at pore sizes less than 15 microns of at least 1.5 times that of a like wiper prepared without regenerated cellulose microfiber. The wipers of the invention exhibit remarkable residue removal efficiency.

Abstract: A soft and resilient, cold-water dispersible polyurethane foam suitable for disposable personal care products is produced by the combination of corn syrup, glycerin, polyether diamine, PEG, a diisocyanate, water and a catalyst. The formulation and reaction conditions for forming the inventive foam are judiciously selected and carefully controlled to achieve water dispersibility and the desired mechanical properties. The characteristic resiliency, or percent rebound for the foams was generally over 75% and the foams are readily produced as soft foams, exhibiting a relative compression value of from 20% to 150% of that of a commercial polyurethane foam cosmetic pad which is not water dispersible. The foam may be incorporated into webs or stackable products or nestable three-dimensional products.

Abstract: Certain substituted phenolic compounds when used with or without 1,2-epoxides as the sole stabilizer components are very effective in stabilizing n-propyl bromide (NPB). In a standard commercially important 60° C. stability test, representative substituted phenolic compounds used pursuant to this invention, can enable NPB to pass the test even though present at levels of about 50 ppm (wt/wt) or less in NPB containing no other stabilizer additive component. In fact, amounts as low as 1 ppm have been found effective with various substituted phenolic compounds. In addition, it has been found that one of the preferred stabilizers of this invention—2,6-di-tert-butyl-p-cresol—even though higher boiling than NPB, left inconsequential amounts of residue at least throughout the range of 1 to 30 ppm (wt/wt). Also, it has been found that certain other preferred stabilizers of this invention can provide synergistically improved stability in passing the 60° C.

Abstract: A multi-ply absorbent sheet includes at least a first and second ply bonded together. In one construction, the first and second ply are provided with from about 90% by weight to about 25% by weight pulp-derived papermaking fiber and from about 10% to about 75% by weight fibrillated regenerated cellulosic microfiber having a characteristic CSF value of less than 175 ml; the sheet having a caliper of from 180-250 mils/8 sheets and exhibiting a wipe-dry time of less than 20 seconds, an SAT capacity in the range of 350-500 g/m2, an SAT rate in the range of 0.05-0.25 g/s0.5, a CD wet tensile in the range of 400-2500 g/3? and a wet/dry CD tensile ratio of from 35% to 60%. The multi-ply sheets are efficient, high capacity wipers and have enough absorbent capacity to be used as ordinary paper towels. Preferred wiper towel products exhibit a differential pore volume for pores under 5 microns in diameter of at least about 75 mm3/g/micron.

Abstract: A multi-ply absorbent towel made from papermaking fiber comprising at least a first ply and a second ply bonded together, the towel having a basis weight of greater than 30 lbs per 3000 ft2 ream (48.8 gsm) and less than 50 lbs per 3000 ft2 ream (81.4 gsm), wherein the plies are selected and adhered together such that the towel typically exhibits (i) a GM TEA, mm-g/mm2 of greater than [0.00125 (GM Tensile, g/3?)?0.75] and (ii) a GM Tensile Modulus, g/in/%, less than [0.0083 (GM Tensile Strength, g/3?)+15.4] {(i) a GM TEA, mm g/mm2, of greater than [0.00952 (GM Tensile, g/cm)?0.75] and (ii) a GM Tensile Modulus, g/cm/%, less than [0.0249 (GM Tensile Strength, g/cm)+6.06}.

Abstract: An absorbent cellulosic sheet is formed by belt creping a nascent web at a consistency of 30% to 60% utilizing a generally planar perforated polymeric creping belt to form a sheet with fiber-enriched higher basis weight hollow domed regions on one side of the sheet joined by a network of lower local basis weight connecting regions forming a network where upwardly and inwardly inflected consolidated fibrous regions exhibiting CD fiber orientation bias form transition areas between the connecting regions and the domed regions. When formed into roll products, the cellulosic sheets exhibit a surprising combination of bulk, roll firmness, absorbency and softness. The consolidated fibrous regions are preferably saddle shaped and exhibit a matted structure on both their outer and inner surfaces.

Abstract: Certain substituted phenolic compounds when used with or without 1,2-epoxides as the sole stabilizer components are very effective in stabilizing n-propyl bromide (NPB). In a standard commercially important 60° C. stability test, representative substituted phenolic compounds used pursuant to this invention, can enable NPB to pass the test even though present at levels of about 50 ppm (wt/wt) or less in NPB containing no other stabilizer additive component. In fact, amounts as low as 1 ppm have been found effective with various substituted phenolic compounds. In addition, it has been found that one of the preferred stabilizers of this invention—2,6-di-tert-butyl-p-cresol—even though higher boiling than NPB, left inconsequential amounts of residue at least throughout the range of 1 to 30 ppm (wt/wt). Also, it has been found that certain other preferred stabilizers of this invention can provide synergistically improved stability in passing the 60° C.

Abstract: A soft and resilient, cold-water dispersible polyurethane foam suitable for disposable personal care products is produced by the combination of corn syrup, glycerin, polyether diamine, PEG, a diisocyanate, water and a catalyst. The formulation and reaction conditions for forming the inventive foam are judiciously selected and carefully controlled to achieve water dispersibility and the desired mechanical properties. The characteristic resiliency, or percent rebound for the foams was generally over 75% and the foams are readily produced as soft foams, exhibiting a relative compression value of from 20% to 150% of that of a commercial polyurethane foam cosmetic pad which is not water dispersible. The foam may be incorporated into webs or stackable products or nestable three-dimensional products.

Abstract: A high efficiency disposable cellulosic wiper includes (a) pulp-derived papermaking fiber; (b) up to 75% by weight regenerated cellulosic microfiber having a characteristic CSF value of less than 175 ml, the microfiber being selected and present in amounts such that the wiper exhibits a Laplace pore volume fraction at pore sizes less than 15 microns of at least 1.5 times that of a like wiper prepared without regenerated cellulose microfiber. The wipers of the invention exhibit remarkable residue removal efficiency.