Patents by Inventor Junichi Kugimoto
Junichi Kugimoto has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 10392334Abstract: A method and a system for inexpensively producing a corresponding target ketone and/or alcohol by decomposing hydroperoxide rapidly and with high selectivity using an aqueous alkaline solution and by recovering and recycling alkali. The method includes neutralizing at least a part of a carboxylic acid in the oxidation reaction solution by contacting the oxidation reaction solution with a first alkaline solution including a carbonate of an alkali metal, and separating the reaction mixture into a first oil phase and a first water phase; decomposing the hydroperoxide and the ester compound in the first oil phase by contacting the first oil phase with a second alkaline solution having a higher pH value than the first alkaline solution, and separating the reaction mixture into a second oil phase and a second water phase; and recovering the carbonate of an alkali metal from the first water phase and recycling the carbonate of an alkali metal to the first alkaline solution.Type: GrantFiled: December 6, 2016Date of Patent: August 27, 2019Assignee: UBE INDUSTRIES, LTD.Inventors: Yoshinori Sugimura, Kazunori Kurosawa, Kazuo Yamato, Junichi Kugimoto, Joji Kawai, Wanna Sirisuksukon, Nantariya Ngamsup
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Publication number: 20180346399Abstract: A method and a system for inexpensively producing a corresponding target ketone and/or alcohol by decomposing hydroperoxide rapidly and with high selectivity using an aqueous alkaline solution and by recovering and recycling alkali. The method includes neutralizing at least a part of a carboxylic acid in the oxidation reaction solution by contacting the oxidation reaction solution with a first alkaline solution including a carbonate of an alkali metal, and separating the reaction mixture into a first oil phase and a first water phase; decomposing the hydroperoxide and the ester compound in the first oil phase by contacting the first oil phase with a second alkaline solution having a higher pH value than the first alkaline solution, and separating the reaction mixture into a second oil phase and a second water phase; and recovering the carbonate of an alkali metal from the first water phase and recycling the carbonate of an alkali metal to the first alkaline solution.Type: ApplicationFiled: December 6, 2016Publication date: December 6, 2018Inventors: Yoshinori SUGIMURA, Kazunori KUROSAWA, Kazuo YAMATO, Junichi KUGIMOTO, Joji KAWAI, Wanna SIRISUKSUKON, Nantariya NGAMSUP
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Patent number: 10099985Abstract: This invention provides producing having an objective ketone and/or alcohol by decomposing of a hydrocarbon compound rapidly and selectively having a same number of carbon atoms as a hydrocarbon compound by decomposing a hydroperoxide in a reaction solution obtained from oxidizing the hydrocarbon compound using molecular oxygen of this invention involves, a hydroperoxide decomposition step for decomposing the hydroperoxide into the ketone and/or alcohol by contacting the reaction solution with an aqueous solution containing a carbonate of an alkaline earth metal or a carbonate of an alkali metal and a transition metal compound, a separation step for separating into an oil phase comprising the ketone and/or alcohol, and a water phase comprising the carbonate of an alkaline earth metal or carbonate of an alkali metal and the transition metal compound, a recovery step for recovering the carbonate of an alkali metal or carbonate of an alkaline earth metal and the transition metal compound by combusting the waterType: GrantFiled: October 5, 2015Date of Patent: October 16, 2018Assignee: UBE INDUSTRIES, LTD.Inventors: Kazunori Kurosawa, Yoshinori Sugimura, Hideo Shimomura, Kazuo Yamato, Joji Funatsu, Naoya Katagiri, Junichi Kugimoto, Joji Kawai
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Publication number: 20170313641Abstract: This invention provides producing having an objective ketone and/or alcohol by decomposing of a hydrocarbon compound rapidly and selectively having a same number of carbon atoms as a hydrocarbon compound by decomposing a hydroperoxide in a reaction solution obtained from oxidizing the hydrocarbon compound using molecular oxygen of this invention involves, a hydroperoxide decomposition step for decomposing the hydroperoxide into the ketone and/or alcohol by contacting the reaction solution with an aqueous solution containing a carbonate of an alkaline earth metal or a carbonate of an alkali metal and a transition metal compound, a separation step for separating into an oil phase comprising the ketone and/or alcohol, and a water phase comprising the carbonate of an alkaline earth metal or carbonate of an alkali metal and the transition metal compound, a recovery step for recovering the carbonate of an alkali metal or carbonate of an alkaline earth metal and the transition metal compound by combusting the waterType: ApplicationFiled: October 5, 2015Publication date: November 2, 2017Applicant: Ube Industries, Ltd.Inventors: Kazunori Kurosawa, Yoshinori Sugimura, Hideo Shimomura, Kazuo Yamato, Joji Funatsu, Naoya Katagiri, Junichi Kugimoto, Joji Kawai
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Patent number: 9376375Abstract: This invention relates to a process for producing an oxime comprising reacting a ketone and hydroxylamine in the presence of a carboxylic acid and/or its salt in a system consisting of an aqueous phase and a hydrophobic solvent phase.Type: GrantFiled: March 23, 2011Date of Patent: June 28, 2016Assignee: UBE INDUSTRIES, LTD.Inventors: Masahide Okada, Junichi Kugimoto, Kazunori Kurosawa, Joji Funatsu, Katsuyoshi Kudo
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Patent number: 9242931Abstract: A method for producing a high purity, high quality amide compound, particularly a lactam. An amount of each of a halide, an aldehyde compound, an alcohol compound and a nitrile compound contained in a solution recycled into an oxime-forming step is controlled to an amount of 0.4 mol % or less based on the ketone as a starting material. One or more of a ketone, an oxime and an amide compound are purified by hydrogenation and/or crystallization for eliminating impurities containing a double bond. A content of impurities having a cyclic bridge structure is controlled using a cycloalkanone purified by recrystallization.Type: GrantFiled: December 27, 2013Date of Patent: January 26, 2016Assignee: UBE INDUSTRIES, LTD.Inventors: Junichi Kugimoto, Joji Kawai
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Patent number: 8962826Abstract: A method for producing a high purity, high quality amide compound, particularly a lactam. An amount of each of a halide, an aldehyde compound, an alcohol compound and a nitrile compound contained in a solution recycled into an oxime-forming step is controlled to an amount of 0.4 mol% or less based on the ketone as a starting material. One or more of a ketone, an oxime and an amide compound are purified by hydrogenation and/or crystallization for eliminating impurities containing a double bond. A content of impurities having a cyclic bridge structure is controlled using a cycloalkanone purified by recrystallization.Type: GrantFiled: December 27, 2013Date of Patent: February 24, 2015Assignee: Ube Industries, Ltd.Inventors: Junichi Kugimoto, Joji Kawai, Kazuo Yamato, Masahide Okada, Tsunemi Sugimoto, Hiroshi Matsumoto
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Patent number: 8816069Abstract: The present invention relates to a method for producing a high purity, high quality amide compound, particularly, lactam. A first embodiment of the present invention is characterized in that an amount of each of a halide, an aldehyde compound, an alcohol compound and a nitrile compound contained in a solution recycled into an oxime-forming step is controlled to an amount of 0.4 mol % or less based on the ketone as a starting material. A second embodiment of the present invention is characterized in that one or more compounds selected from the group consisting of a ketone, an oxime and an amide compound are purified by hydrogenation and/or crystallization for eliminating impurities containing a double bond. A third embodiment of the present invention is characterized in that a content of impurities having a cyclic bridge structure is controlled by using a cycloalkanone purified by recrystallization.Type: GrantFiled: March 15, 2011Date of Patent: August 26, 2014Assignee: Ube Industries, Ltd.Inventors: Junichi Kugimoto, Joji Kawai, Hiroshi Matsumoto
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Publication number: 20140114061Abstract: A method for producing a high purity, high quality amide compound, particularly a lactam. An amount of each of a halide, an aldehyde compound, an alcohol compound and a nitrile compound contained in a solution recycled into an oxime-forming step is controlled to an amount of 0.4 mol % or less based on the ketone as a starting material. One or more of a ketone, an oxime and an amide compound are purified by hydrogenation and/or crystallization for eliminating impurities containing a double bond. A content of impurities having a cyclic bridge structure is controlled using a cycloalkanone purified by recrystallization.Type: ApplicationFiled: December 27, 2013Publication date: April 24, 2014Applicant: Ube Industries, Ltd.Inventors: Junichi Kugimoto, Joji Kawai, Kazuo Yamato, Masahide Okada, Tsunemi Sugimoto, Hiroshi Matsumoto
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Publication number: 20140114062Abstract: A method for producing a high purity, high quality amide compound, particularly a lactam. An amount of each of a halide, an aldehyde compound, an alcohol compound and a nitrile compound contained in a solution recycled into an oxime-forming step is controlled to an amount of 0.4 mol % or less based on the ketone as a starting material. One or more of a ketone, an oxime and an amide compound are purified by hydrogenation and/or crystallization for eliminating impurities containing a double bond. A content of impurities having a cyclic bridge structure is controlled using a cycloalkanone purified by recrystallization.Type: ApplicationFiled: December 27, 2013Publication date: April 24, 2014Applicant: Ube Industries, Ltd.Inventors: Junichi Kugimoto, Joji Kawai, Kazuo Yamato, Masahide Okada, Tsunemi Sugimoto, Hiroshi Matsumoto
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Patent number: 8624021Abstract: The present invention provides novel cyclododecanone-O-azacyclotridecen-2-yloxime and cyclododecanone-O-azacyclotridecen-2-yloxime hydrochloride. The invention also provides a process for producing an amide compound wherein cyclododecanone-O-azacyclotridecen-2-yloxime, hydrogen chloride and/or Lewis acid or cyclododecanone-O-azacyclotridecen-2-yloxime hydrochloride are used as a rearrangement catalyst and/or a reaction starting material in a reaction step.Type: GrantFiled: September 24, 2010Date of Patent: January 7, 2014Assignee: Ube Industries, Ltd.Inventors: Tsunemi Sugimoto, Mitsuru Kishishita, Junichi Kugimoto, Kazunori Kurosawa, Hideo Shimomura, Ryouta Yasumatsu
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Patent number: 8530645Abstract: This invention relates to a process for producing an amide compound by Beckmann rearrangement of an oxime compound using a compound having at least two electron-withdrawing leaving groups as a rearrangement catalyst, the process comprising a pre-preparation step in which the rearrangement catalyst and at least a part of the oxime compound are mixed and reacted; and a rearrangement reaction step in which the oxime compound is rearranged at a temperature higher than that in the pre-preparation step.Type: GrantFiled: March 4, 2010Date of Patent: September 10, 2013Assignee: Ube Industries, Ltd.Inventors: Junichi Kugimoto, Tsunemi Sugimoto
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Publication number: 20130184494Abstract: According to the first embodiment of the present invention, an oxide of a hydrocarbon compound can be produced with high yield and high productivity by oxidizing the hydrocarbon compound with molecular oxygen in the co-presence of an N-hydroxy compound, such as methyl ethyl ketone or N-hydroxysuccinimide, and a phosphate ester, such as dibutyl phosphate. According to another embodiment of the present invention, an oxide of a hydrocarbon compound can be produced with high yield by using an oxidation catalyst that comprises an oxime compound, such as methyl ethyl ketone. According to another embodiment of the present invention, an alcohol and/or a ketone can be produced with high yield by oxidizing the hydrocarbon compound at a temperature of 160° C. or less, and by decomposing the resulting hydroperoxide, for example, in a unit having an inner surface formed by a material from which no transition metal ion is generated.Type: ApplicationFiled: September 26, 2011Publication date: July 18, 2013Applicant: USE Industries, Ltd.Inventors: Kazunori Kurosawa, Joji Funatsu, Naoya Katagiri, Junichi Kugimoto
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Publication number: 20130023697Abstract: This invention relates to a process for producing an oxime comprising reacting a ketone and hydroxylamine in the presence of a carboxylic acid and/or its salt in a system consisting of an aqueous phase and a hydrophobic solvent phase.Type: ApplicationFiled: March 23, 2011Publication date: January 24, 2013Applicant: UBE INDUSTRIES, LTD.Inventors: Masahide Okada, Junichi Kugimoto, Kazunori Kurosawa, Joji Funatsu, Katsuyoshi Kudo
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Patent number: 8354527Abstract: The present invention relates to a process for producing an amide or lactam, particularly laurolactam, wherein catalytic amounts of an acidic chloride and a Lewis acid are used in Beckmann rearrangement of an oxime compound. In accordance with the process, side reactions during Beckmann rearrangement can be so controlled that selectivity can be improved and strong coloring in the reaction can be prevented, giving a high-quality amide or lactam.Type: GrantFiled: April 22, 2009Date of Patent: January 15, 2013Assignee: Ube Industries, Ltd.Inventors: Yasuhisa Fukuda, Junichi Kugimoto, Nobuhiro Il
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Publication number: 20130005961Abstract: The present invention provides novel cyclododecanone-O-azacyclotridecen-2-yloxime and cyclododecanone-O-azacyclotridecen-2-yloxime hydrochloride. The invention also provides a process for producing an amide compound wherein cyclododecanone-O-azacyclotridecen-2-yloxime, hydrogen chloride and/or Lewis acid or cyclododecanone-O-azacyclotridecen-2-yloxime hydrochloride are used as a rearrangement catalyst and/or a reaction starting material in a reaction step.Type: ApplicationFiled: September 24, 2010Publication date: January 3, 2013Applicant: UBE INDUSTRIES, LTD.Inventors: Tsunemi Sugimoto, Mitsuru Kishishita, Junichi Kugimoto, Kazunori Kurosawa, Hideo Shimomura, Ryouta Yasumatsu
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Publication number: 20130005960Abstract: The present invention relates to a method for producing a high purity, high quality amide compound, particularly, lactam. A first embodiment of the present invention is characterized in that an amount of each of a halide, an aldehyde compound, an alcohol compound and a nitrile compound contained in a solution recycled into an oxime-forming step is controlled to an amount of 0.4 mol % or less based on the ketone as a starting material. A second embodiment of the present invention is characterized in that one or more compounds selected from the group consisting of a ketone, an oxime and an amide compound are purified by hydrogenation and/or crystallization for eliminating impurities containing a double bond. A third embodiment of the present invention is characterized in that a content of impurities having a cyclic bridge structure is controlled by using a cycloalkanone purified by recrystallization.Type: ApplicationFiled: March 15, 2011Publication date: January 3, 2013Applicant: UBE INDUSTRIES, LTD.Inventors: Junichi Kugimoto, Joji Kawai, Kazuo Yamato, Masahide Okada, Tsunemi Sugimoto, Hiroshi Matsumoto
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Patent number: 8338589Abstract: The present invention relates to a process for producing laurolactam from cyclododecanone oxime by liquid-phase rearrangement reaction using trichlorotriazine as a rearrangement catalyst. The present invention can provide a process which can solve the problem of termination of the reaction at a certain conversion, can prevent an inactive precipitate generated from trichlorotriazine from precipitating in the course of the reaction process, and can remove an inactive precipitate, an active intermediate and a residual catalyst.Type: GrantFiled: May 19, 2009Date of Patent: December 25, 2012Assignee: UBE Industries, Ltd.Inventors: Junichi Kugimoto, Nobuhiro Ii, Takashi Doi, Satoru Fujitsu, Tadashi Gotou, Hideo Shimomura, Ryouta Yasumatsu, Joji Kawai
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Patent number: 8309714Abstract: Provided is a process for efficiently producing laurolactam by simple steps from cyclododecanone and hydroxylamine.Type: GrantFiled: November 19, 2008Date of Patent: November 13, 2012Assignee: Ube Industries, Ltd.Inventors: Junichi Kugimoto, Joji Kawai, Hideo Shimomura, Ryouta Yasumatsu, Nobuhiro Ii
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Patent number: 8163899Abstract: Disclosed is a method for producing laurolactam from cyclododecanone and hydroxylamine in a simple process and with high efficiency. The method comprises the following steps (a) to (e): (a) reacting cyclododecanone with hydroxylamine in an aqueous solution in the presence of an excess amount of cyclododecanone or a solvent to produce cyclododecanone oxime; (b) separating the reaction mixture obtained after the oxime-forming step into an oil and an aqueous phases and collecting a solution of cyclododecanone oxime of the oil phase as; (c) removing dissolved water from the solution of cyclododecanone oxime which is collected as an oily phase in the oil/aqueous phase separation step; (d) producing laurolactam from cyclododecanone oxime by rearrangement reaction using an aromatic-ring containing compound as a rearrangement catalyst; and (e) separating the produced laurolactam from the reaction mixture after the rearrangement step and purifying the laurolactam.Type: GrantFiled: February 8, 2008Date of Patent: April 24, 2012Assignees: National University Corporation Nagoya University, UBE Industries, Ltd.Inventors: Kazuaki Ishihara, Junichi Kugimoto, Joji Kawai