Patents by Inventor Junji Arika
Junji Arika has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 4687653Abstract: Disclosed is a zeolite having a composition of the following formula: xM.sub.2/n O.Al.sub.2 O.sub.3.(5-10)SiO.sub.2.yH.sub.2 O wherein M is at least one cation having a valency of n, and x is 0.8-2 and y is 0-10, and exhibiting an X-ray powder diffraction pattern shown in Table 1. This zeolite is prepared by a process wherein a reaction mixture comprising a silica source, an alumina source, an alkali source, a potassium source and water and having a composition satisfying the following molar ratios: SiO.sub.2 /Al.sub.2 O.sub.3 =6-40, OH/SiO.sub.2 =0.3-1, K.sub.2 O/M.sub.2 O=0.1-0.9 (M: the total of alkali metals), and H.sub.2 O/SiO.sub.2 =10-70, is crystallized at 120.degree. to 200.degree. C. with stirring. The zeolite is also prepared by a process wherein a granular amorphous aluminosilicate containing aluminum in an amount of 4 to 22 wt. % as Al.sub.2 O.sub.Type: GrantFiled: November 7, 1985Date of Patent: August 18, 1987Assignee: Toyo Soda Manufacturing Co., Ltd.Inventors: Junji Arika, Kazushige Igawa, Keiji Itabashi
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Patent number: 4678651Abstract: A faujasite zeolite of a high purity and a desired silica/alumina ratio is prepared by crystallizing at an elevated temperature a reaction mixture comprising a silica source, an alumina source, and an alkali metal source, wherein a transparent faujasite germ solution obtained by mixing and aging aqueous alkali metal silicate solution, an aqueous alkali metal aluminate solution and an aqueous alkali metal hydroxide solution is made present in the reaction mixture. The faujasite germ solution has an oxide molar composition represented by the following molar ratios:SiO.sub.2 /Al.sub.2 O.sub.3 =8 to 14,M.sub.2 O/Al.sub.2 O.sub.3 =7 to 30,andH.sub.2 O/M.sub.2 O=10 to 14,wherein M represents an alkali metal.The amount of the faujasite germ solution is 1 to 30 wt. % as Al.sub.2 O.sub.3 based on the faujasite zeolite.Type: GrantFiled: July 11, 1985Date of Patent: July 7, 1987Assignee: Toyo Soda Manufacturing Co., Ltd.Inventors: Hiroshi Miyazaki, Junji Arika, Michiyuki Aimoto
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Patent number: 4664898Abstract: A mordenite type zeolite having a high purity and a high SiO.sub.2 /Al.sub.2 O.sub.3 molar ratio is prepared without using an organic or inorganic mineralizer, by a process wherein a homogeneous aluminosilicate containing 3 to 14% by weight, expressed in terms of Al.sub.2 O.sub.3 (calculated as the anhydride), of aluminum is crystallized in an aqueous solution of an alkali metal hydroxide.Type: GrantFiled: September 23, 1985Date of Patent: May 12, 1987Assignee: Toyo Soda Manufacturing Co., Ltd.Inventors: Junji Arika, Hiroshi Miyazaki, Keiji Itabashi, Michiyuki Aimoto
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Patent number: 4650654Abstract: A ferrierite type zeolite having a high purity and a high SiO.sub.2 /Al.sub.2 O.sub.3 molar ratio is prepared by reacting simultaneously and continuously an aqueous sodium and/or potassium silicate solution with an aluminum-containing solution to obtain a homogeneous phase compound of a granular amorphous aluminosilicate containing Al in an amount of 3 to 14 wt. % as calculated as anhydrous Al.sub.2 O.sub.3 and Na and/or K in an amount of 1 to 17 wt. % as calculated as anhydrous Na.sub.2 O and/or K.sub.2 O; and then, crystallizing the homogeneous phase compound in the form of a slurry in water or in an aqueous sodium hydroxide and/or potassium hydroxide solution. The molar ratio of K.sup.+ to the total of (K.sup.+ +Na.sup.+) in the slurry is 0.1 to 0.9.Type: GrantFiled: December 26, 1984Date of Patent: March 17, 1987Assignee: Toyo Soda Manufacturing Co., Ltd.Inventors: Junji Arika, Hiroshi Miyazaki, Kazushige Igawa, Keiji Itabashi
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Patent number: 4587115Abstract: A faujasite type zeolite having a high SiO.sub.2 /Al.sub.2 O.sub.3 ratio is prepared by simultaneously and continuously supplying an aqueous solution of an alkali metal silicate and an aqueous solution of an aluminum-containing compound whereby the alkali metal silicate is continuously reacted with the aluminum-containing compound to prepare a homogeneous phase compound of a granular amorphous aluminosilicate containing aluminum in an amount of 10 to 16% by weight, as Al.sub.2 O.sub.3 and based on the anhydride; and then, crystallizing the granular homogeneous phase amorphous aluminosilicate in an aqueous alkali metal hydroxide solution having a concentration of 4 to 10% by weight.Type: GrantFiled: June 8, 1984Date of Patent: May 6, 1986Assignee: Toyo Soda Manufacturing Co., Ltd.Inventors: Junji Arika, Michiyuki Aimoto, Hiroshi Miyazaki
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Patent number: 4562055Abstract: A zeolite similar to ZSM-5, having lattice spacings (d-values), shown in Table 1, of the X-ray powder diffraction pattern, and a ferrierite zeolite are prepared by crystallizing a homogeneous phase compound of a granular amorphous aluminosilicate in water or in an aqueous solution of an alkali metal hydroxide and/or an alkali metal silicate.Type: GrantFiled: September 20, 1983Date of Patent: December 31, 1985Assignee: Toyo Soda Manufacturing Co., Ltd.Inventors: Junji Arika, Hiroshi Miyazaki, Kazushige Igawa, Keiji Itabashi
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Patent number: 4554211Abstract: A spherical micro-porous silica gel, which is characterized by having a mean diameter of 3-20 .mu.m, a bulk density of 0.28-0.41 g/cm.sup.3, a pore size of 18,000-100,000 and a specific surface area of 1,000-1,400 m.sup.2 /g and a production process therefor is characterized by employing (a) an aqueous solution containing SiO.sub.2 in which the primary particle diameter is not larger than 6 nm and the molar ratio of SiO.sub.2 to Na.sub.2 O is not larger than 5.5, (b) either stearic acid or a mixture of stearic acid and a non-ionic surface active agent of which HLB ranges from 3.5 to 6.0 as an emulsifier and (c) an organic acid as a gelling agent.Type: GrantFiled: August 2, 1983Date of Patent: November 19, 1985Assignee: Toyo Soda Manufacturing Co. Ltd.Inventors: Junji Arika, Eiji Shiota, Kazuaki Yamamoto
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Patent number: 4530824Abstract: An L type zeolite of a high purity is prepared by crystallizing an amorphous sodium alminosilicate compound containing a silicon component in an amount of 67 to 91 wt. % as SiO.sub.2 on the anhydrous basis in an aqueous potassium hydroxide solution.Type: GrantFiled: October 18, 1983Date of Patent: July 23, 1985Assignee: Toyo Soda Manufacturing Co., Ltd.Inventors: Junji Arika, Keiji Itabashi, Yoshio Tamura
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Patent number: 4405484Abstract: A finely divided zeolite powder of high flowability is provided. This zeolite powder is represented by the formula: Na.sub.2 O.Al.sub.2 O.sub.3.nSiO.sub.2.wH.sub.2 O (n=1.8.about.3.0 and w=1.about.6) and comprises at least 99 weight % of particles having a particle size of 1-5 microns and has an aerated bulk density of from 0.3 to about 0.5 g/cc, a degree of cohesiveness of not larger than 56%, and a general flow index (expressed as the sum of indexes of the repose angle, spatula angle, compressibility and degree of cohesiveness) of from 30 to about 50. The zeolite powder is prepared by adding an alkali metal aluminate to an aqueous zeolite slurry containing 3052 wt. % of zeolite (an anhydride) and having pH of not higher than 12.8; adjusting the pH of the slurry to a value not higher than 11; and then, drying the slurry. The zeolite powder is useful as a builder for detergent.Type: GrantFiled: August 7, 1981Date of Patent: September 20, 1983Assignee: Toyo Soda Manufacturing Co., Ltd.Inventors: Hiroshi Miyazaki, Junji Arika
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Patent number: 4247529Abstract: Titanium carbonitride of a high purity and in a fine powder form can be produced by maintaining a mixture of titanium halide and carbon at a temperature of from 700.degree. C. to 1,800.degree. C. in the presence of a reducing substance, such as aluminum or an aluminum-titanium alloy, in a nitrogen-containing gaseous atmosphere.Type: GrantFiled: March 13, 1979Date of Patent: January 27, 1981Assignee: Toyo Soda Manufacturing Co., Ltd.Inventors: Tadaaki Mori, Takaaki Tsukidate, Junji Arika
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Patent number: 4157379Abstract: Chain structured corpuscular calcium carbonate is produced by a carbonation of calcium hydroxide suspended in water in the presence of a chelating agent and a water soluble metal salt.Type: GrantFiled: November 30, 1977Date of Patent: June 5, 1979Assignee: Toyo Soda Manufacturing Co., Ltd.Inventors: Junji Arika, Masaru Takitani, Keiji Mitarai, Kazuaki Yamamoto
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Patent number: 3980754Abstract: An alkali carbonate containing a fluorine compound is purified by dissolving the crude alkali carbonate in an aqueous solution or suspension of magnesium bicarbonate in order to transfer the fluorine impurity into the resulting colloidal flocculated precipitate whereby the fluorine is substantially separated from the aqueous solution of the alkali carbonate.Type: GrantFiled: August 8, 1975Date of Patent: September 14, 1976Assignee: Toyo Soda Manufacturing Co., Ltd.Inventors: Susumo Otsuki, Junji Arika, Mitsunobu Kashibe, Kosuke Takeshige