Abstract: A low-VOC coating composition, a coating film, a substrate with a coating film, or a method its production, may include a low-VOC coating composition substantially free of benzyl alcohol. The low-VOC coating composition may include: a bisphenol epoxy compound (A) having an epoxy equivalent of 200 or less; a liquid amine curing agent (B); and a dioxolane derivative (C) of formula (1): wherein R1 and R2 are each independently H, an alkyl group, an alkenyl group, or a phenyl group, and n is 1, 2, 3, 4, or 5.

Abstract: The present invention relates to a coating composition, a primer coating film, a layered antifouling coating film, a method of producing a substrate with a primer coating film, and a method of producing a substrate with a layered antifouling coating film. The coating composition includes an epoxy resin (A), an amine curing agent (B), a silane coupling agent (C), water (D), and a pigment (E). In the coating composition, the content of the water (D) is 3.5 to 11 parts by weight with respect to 100 parts by weight of non-volatile content in the coating composition, and a pigment volume concentration of the coating composition is 37 to 47%.

Abstract: An object of the present invention is to provide an antifouling coating composition capable of forming an antifouling coating film that retains a high antifouling performance for a prolonged period of time and has an excellent damage resistance. Another object of the present invention is to provide an antifouling coating film formed with the antifouling coating composition, a substrate with an antifouling coating film and a method for producing the same, and an antifouling method using the antifouling coating film. The antifouling coating composition of the present invention contains a hydrolyzable polymer (A) containing a metal ester group, zinc oxide (B), and medetomidine (C), and has a content of the zinc oxide (B) in a solid content of the antifouling composition of 27 to 60% by mass.

Abstract: The present invention is to provide an antifouling coating composition capable of forming an antifouling coating film that exhibits a high antifouling performance even in a marine area having a heavy fouling load by animal species such as barnacles, has excellent slime resistance, and is prevented from cracking. Further, the present invention is also to provide an antifouling coating film, a substrate with an antifouling coating film and a method of producing the substrate, and an antifouling method, each using the composition. The antifouling coating composition of the present invention contains a polyorganosiloxane block-containing hydrolyzable copolymer (A) and medetomidine (B), wherein the polyorganosiloxane block-containing hydrolyzable copolymer (A) contains (i) a constituent unit derived from a hydrolyzable group-containing monomer (a1) and (ii) a constituent unit derived from a polyorganosiloxane block-containing monomer (a2).

Abstract: The present invention is to provide an antifouling coating composition capable of forming an antifouling coating film that exhibits a high antifouling performance even in a marine area having a heavy fouling load by animal species such as barnacles, has excellent slime resistance, and is prevented from cracking. Further, the present invention is also to provide an antifouling coating film, a substrate with an antifouling coating film and a method of producing the substrate, and an antifouling method, each using the composition. The antifouling coating composition of the present invention contains a polyorganosiloxane block-containing hydrolyzable copolymer (A) and medetomidine (B), wherein the polyorganosiloxane block-containing hydrolyzable copolymer (A) contains (i) a constituent unit derived from a hydrolyzable group-containing monomer (a1) and (ii) a constituent unit derived from a polyorganosiloxane block-containing monomer (a2).

Abstract: An object of the present invention is to provide an antifouling coating composition capable of forming an antifouling coating film that retains a high antifouling performance for a prolonged period of time and has an excellent damage resistance. Another object of the present invention is to provide an antifouling coating film formed with the antifouling coating composition, a substrate with an antifouling coating film and a method for producing the same, and an antifouling method using the antifouling coating film. The antifouling coating composition of the present invention contains a hydrolyzable polymer (A) containing a metal ester group, zinc oxide (B), and medetomidine (C), and has a content of the zinc oxide (B) in a solid content of the antifouling composition of 27 to 60% by mass.

Abstract: The present invention relates to a coating composition, a primer coating film, a layered antifouling coating film, a method of producing a substrate with a primer coating film, and a method of producing a substrate with a layered antifouling coating film. The coating composition includes an epoxy resin (A), an amine curing agent (B), a silane coupling agent (C), water (D), and a pigment (E). In the coating composition, the content of the water (D) is 3.5 to 11 parts by weight with respect to 100 parts by weight of non-volatile content in the coating composition, and a pigment volume concentration of the coating composition is 37 to 47%.

Abstract: Provided is a two-component-type primer having good adhesive property with a base material, particularly a nonferrous metal, and excellent curability, without containing any chromium compound. The two-component-type primer comprises an epoxy resin, an MXDA (meta-xylenediamine) Mannich modified curing agent, a gypsum (excluding crystal gypsum), and a pigment (excluding gypsum), wherein the volume concentration of a gypsum and a pigment in a dry coating film formed with the primer is 40 to 50%.

Abstract: The antifouling coating composition according to the present invention includes a silylacrylic copolymer including a structural unit (1) derived from triisopropylsilyl methacrylate (i), a structural unit (2) derived from triisopropylsilyl acrylate (ii) and a structural unit (3) derived from a polymerizable monomer having a polymerizable double bond (iii), which excludes the above (i) and (ii), the silylacrylic copolymer satisfies specific requirements. Thus, an antifouling coating composition that is excellent in long-term storage stability and gives a coating film excellent in long-term antifouling properties and long-term water resistance can be provided.

Abstract: Provided is a two-component-type primer having good adhesive property with a base material, particularly a nonferrous metal, and excellent curability, without containing any chromium compound. The two-component-type primer comprises an epoxy resin, an MXDA (meta-xylenediamine) Mannich modified curing agent, a gypsum (excluding crystal gypsum), and a pigment (excluding gypsum), wherein the volume concentration of a gypsum and a pigment in a dry coating film formed with the primer is 40 to 50%.

Abstract: To provide a polyester resin for an antifouling coating material that has improved storage stability while maintaining low VOC, thereby allowing preparation in a one-pack form, and that allows increased curability to be achieved and can provide a satisfactory antifouling property and coating property for prolonged periods, as well as a method for producing it, and an antifouling coating material composition. The polyester resin for an antifouling coating material is obtained by reacting a (a) trihydric or greater alcohol, a (b) dibasic acid or its anhydride and a (c) divalent alcohol, and then further reacting with an (d) alicyclic dibasic acid or its anhydride.

Abstract: The antifouling coating composition according to the present invention includes a silylacrylic copolymer including a structural unit (1) derived from triisopropylsilyl methacrylate (i), a structural unit (2) derived from triisopropylsilyl acrylate (ii) and a structural unit (3) derived from a polymerizable monomer having a polymerizable double bond (iii), which excludes the above (i) and (ii), the silylacrylic copolymer satisfies specific requirements. Thus, an antifouling coating composition that is excellent in long-term storage stability and gives a coating film excellent in long-term antifouling properties and long-term water resistance can be provided.

Abstract: To provide an antifouling coating composition which does not contain copper or any copper compound (e.g., cupric oxide) and therefore enables the production of an antifouling coating film that does not undergo discoloration or cracking caused by ultraviolet ray or moisture, can have a low VOC and long-term antifouling properties at high levels simultaneously, and has excellent mechanical strength. A two-part hydrolysable antifouling coating composition of the present invention comprises two liquids, i.e., a first component containing a polyester resin having a solid content acid value and a hydroxyl value of 50-200 mgKOH/g and 100 mgKOH/g or less, respectively, and having a viscosity of 500 mPa·s or less at 25° C.; and a second component in paste form containing a zinc oxide, and based on the total amount of the first and second components, the content of volatile organic compound is 400 g/L or less, and copper or any copper compound is not contained.

Abstract: A high-solids anticorrosive coating composition which comprises a main ingredient (A) comprising an epoxy resin (a1) and a hardener ingredient (B) comprising an alicyclic amine hardener (b1) and/or a Mannich type hardener (b2), the ingredient (A) and/or the ingredient (B) containing at least either of an additive (a2) selected among epoxidized reactive diluents and modified epoxy resins and a coating film modifier (ab) selected among petroleum resins, xylene resins, coumarone resins, terpene phenol resins and vinyl chloride copolymers. The high-solids anticorrosive coating composition especially of the rapidly curable type is characterized by containing a high-boiling organic solvent having a boiling point exceeding 150° C. and containing substantially no organic solvent having a boiling point of 150° C. or lower.

Abstract: The present invention provides an antifouling paint composition comprising a hydrolyzable copolymer (A) and an antifouling agent (B), wherein (A) is at least one kind of hydrolyzable copolymer selected from the group consisting of (a1) a copolymer containing a bond of metal salt, which is an acrylic polymer or a polyester resin, and has a side chain terminal group represented by the formula (I): —COO-M-O—COR1 [where M represents zinc or copper and R1 represents an organic group]; (a2) a copolymer containing a bond of metal salt composed of a component unit (a21) represented by the formula (II): CH2?C(R2)—COO-M-O—CO—C(R2)?CH2 [where M is the same as above and R2 represents H or CH3] and the other unsaturated monomer component unit (a22) which is copolymerizable with the monomer (II); and (a3) a silyl ester based copolymer composed of a component unit (a31) represented by the general formula (III): R7—CH?C(R3)—COO—SiR4R5R6 [where R3 is the same as R2, R4 to R6 represents a hydrocarbon group, R7 represents H or