Abstract: The polymerization of cycloalkenamer is stopped by adding an alkyl vinyl derivative. Subsequently compound A is added, wherein compound A has at least one of the features i) or ii): i) at least one functional group or ii) at least one saturated or unsaturated aliphatic or aromatic heterocyclic ring having 3 to 14 ring atoms, wherein the ring atoms contain at least one carbon atom and at least one atom selected from oxygen, nitrogen and sulfur. A membrane filtration is subsequently carried out. This type of production produces polyalkenamers which are temperature-stable at 180° C.

Abstract: A method is useful for the continuous production of ketones from a compound with at least one epoxide group in at least one fixed bed reactor. A catalyst composition is used with at least one noble metal and at least one metal oxide. To reduce the proportions of high-boilers which form in the reaction, an inert gas is introduced so that a carbon monoxide partial pressure of 50 mbar or less is set in the reactor.

Abstract: A method is useful for the continuous production of ketones from a compound with at least one epoxide group in at least one fixed bed reactor. A catalyst composition is used with at least one noble metal and at least one metal oxide. To reduce the proportions of high-boilers which form in the reaction, an inert gas is introduced so that a carbon monoxide partial pressure of 50 mbar or less is set in the reactor.

Abstract: The polymerization of cycloalkenamer is stopped by adding an alkyl vinyl derivative. Subsequently compound A is added, wherein compound A has at least one of the features i) or ii): i) at least one functional group or ii) at least one saturated or unsaturated aliphatic or aromatic heterocyclic ring having 3 to 14 ring atoms, wherein the ring atoms contain at least one carbon atom and at least one atom selected from oxygen, nitrogen and sulfur. A membrane filtration is subsequently carried out. This type of production produces polyalkenamers which are temperature-stable at 180° C.

Abstract: The present invention relates to a process for producing cycloalkenamer-containing compositions. The polymerization of cycloalkenamer is stopped by addition of alkyl vinyl ethers. This is followed by a membrane filtration. This type of production affords polyalkenamers that are thermally stable at 180° C.

Abstract: Polymers can be prepared from monomers comprising laurolactam, by a process including a. Beckmann rearrangement of cyclododecanone oxime to give laurolactam in the presence of a Beckmann rearrangement catalyst, b. removal of impurities from the laurolactam to obtain purified laurolactam, and c. polymerization of monomers comprising purified laurolactam. For avoidance of discolouration or yellowing under ageing conditions, prior to the polymerization, polycyclic substances containing 24 carbon atoms and at least one heteroatom selected from oxygen and nitrogen and having a molar mass between 300 and 380 g/mol are limited to 500 ppm, based on laurolactam.

Abstract: A homogeneous catalyst system is removed from a reaction mixture of two liquid phases by separating the two liquid phases with a membrane having at least one separation-active layer in such a way that the homogeneous catalyst system is at least partially concentrated in a membrane retentate; wherein the reaction mixture contains at least one partially epoxidized cyclic unsaturated compound having twelve carbon atoms; and wherein the membrane separation-active layer contains crosslinked a silicone acrylate and/or polydimethylsiloxane and/or polyimide.

Abstract: A catalyst composition is useful for producing a ketone from a compound containing at least one epoxide group, and the catalyst composition contains at least one precious metal; and at least one mixed oxide; wherein the mixed oxide contains zirconium dioxide and silicon dioxide; wherein the precious metal is supported and the support is not entirely made of the mixed oxide; and wherein a mass ratio of zirconium dioxide to silicon dioxide in the mixed oxide is 86:14 to 99.9:0.1.

Abstract: An apparatus for the epoxidation of a cyclic unsaturated C12 compound with hydrogen peroxide is provided. The apparatus includes a reactor for carrying out the reaction, wherein the walls of the reactor are at least partially furnished with a separation-active layer of crosslinked silicone acrylates and/or polydimethylsiloxane.

Abstract: The invention relates to a method for the purification of poly(arylene ethers) of formula (I) in which m=0 to 1.0, n=1.0-m, and Ar1, Ar2, Ar3 and Ar4 independently represent divalent arylene groups. The compound of formula (I) is produced in a first step 1, with a raw product being obtained by bringing a metal or ammonium salt of divalent dihydroxy derivatives of Ar1 or Ar3 into contact with one or more dihalogenated derivatives of Ar2 and/or Ar4, in the presence of a solvent LM1. A precipitate that is present, if appropriate, is separated (step B) so as to obtain a solution L which then undergoes a membrane filtration (step C).

Abstract: Cyclododecanone (CDON) is prepared by epoxidizing cyclododecene (CDEN) to epoxycyclododecane (CDAN epoxide), and rearranging the CDAN epoxide to CDON to obtain a mixture comprising said CDON and cyclododecane (CDAN), wherein CDAN is separated from the CDON-containing mixture and oxidized to CDON.

Abstract: Cyclododecanone (CDON) is prepared by epoxidizing cyclododecene (CDEN) to epoxycyclododecane (CDAN epoxide), and rearranging the CDAN epoxide to CDON to obtain a mixture comprising said CDON and CDEN, wherein CDEN is separated from the CDON-containing mixture and sent to the epoxidation to CDAN epoxide in step a.

Abstract: A catalyst composition is useful for producing a ketone from a compound containing at least one epoxide group, and the catalyst composition contains at least one precious metal; and at least one mixed oxide; wherein the mixed oxide contains zirconium dioxide and silicon dioxide; wherein the precious metal is supported and the support is not entirely made of the mixed oxide; and wherein a mass ratio of zirconium dioxide to silicon dioxide in the mixed oxide is 86:14 to 99.9:0.1.

Abstract: The invention relates to a method for the purification of poly(arylene ethers) of formula (I) in which m=0 to 1.0, n=1.0-m, and Ar1, Ar2, Ar3 and Ar4 independently represent divalent arylene groups. The compound of formula (I) is produced in a first step 1, with a raw product being obtained by bringing a metal or ammonium salt of divalent dihydroxy derivatives of Ar1 or Ar3 into contact with one or more dihalogenated derivatives of Ar2 and/or Ar4, in the presence of a solvent LM1. A precipitate that is present, if appropriate, is separated (step B) so as to obtain a solution L which then undergoes a membrane filtration (step C).

Abstract: Cyclododecanone (CDON) is prepared by epoxidizing cyclododecene (CDEN) to epoxycyclododecane (CDAN epoxide), and rearranging the CDAN epoxide to CDON to obtain a mixture comprising said CDON and CDEN, wherein CDEN is separated from the CDON-containing mixture and sent to the epoxidation to CDAN epoxide in step a.

Abstract: Cyclododecanone (CDON) is prepared by epoxidizing cyclododecene (CDEN) to epoxycyclododecane (CDAN epoxide), and rearranging the CDAN epoxide to CDON to obtain a mixture comprising said CDON and cyclododecane (CDAN), wherein CDAN is separated from the CDON-containing mixture and oxidized to CDON.

Abstract: A homogeneous catalyst system is removed from a reaction mixture of two liquid phases by separating the two liquid phases with a membrane having at least one separation-active layer in such a way that the homogeneous catalyst system is at least partially concentrated in a membrane retentate; wherein the reaction mixture contains at least one partially epoxidized cyclic unsaturated compound having twelve carbon atoms; and wherein the membrane separation-active layer contains crosslinked a silicone acrylate and/or polydimethylsiloxane and/or polyimide.

Abstract: A process for preparing a ketone by conversion of a compound E which contains an epoxy group to the ketone in the presence of a mixture comprising at least one noble metal and at least one metal oxide as a catalyst system, wherein the metal oxide in the catalyst system is at least one of titanium dioxide and zirconium dioxide, and the process is conducted at 0 to 0.9 bar of hydrogen.

Abstract: A process for preparing a ketone by conversion of a compound E which contains an epoxy group to the ketone in the presence of a mixture comprising at least one noble metal and at least one metal oxide as a catalyst system, wherein the metal oxide in the catalyst system is at least one of titanium dioxide and zirconium dioxide, and the process is conducted at 0 to 0.9 bar of hydrogen.