Patents by Inventor Kae Yamamura
Kae Yamamura has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 9556023Abstract: A porous composite metal oxide, including a mixture of first ultrafine particles containing alumina and second ultrafine particles containing zirconia, wherein the first ultrafine particles and the second ultrafine particles are uniformly dispersed in such a way as to satisfy a condition that standard deviations of content ratios (% by mass) of all metal elements contained in the porous composite metal oxide at 0.1% by mass or more are each 10 or less, the standard deviations being obtained by measuring content ratios of the metal elements at 100 measurement points within a minute analysis region of 20 nm square by energy dispersive X-ray spectroscopy using a scanning transmission electron microscope equipped with a spherical aberration correction function.Type: GrantFiled: September 10, 2010Date of Patent: January 31, 2017Assignee: KABUSHIKI KAISHA TOYOTA CHUO KENKYUSHOInventors: Kimitoshi Sato, Kae Yamamura, Akira Morikawa, Akihiko Suda
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Patent number: 9376327Abstract: A ceria-zirconia base composite oxide contains a composite oxide of ceria and zirconia. In the ceria-zirconia base composite oxide, a content ratio between cerium and zirconium in the composite oxide is in a range from 43:57 to 48:52 in terms of molar ratio ([cerium]:[zirconium]). An intensity ratio of a diffraction line at 2?=14.5° to a diffraction line at 2?=29° {I(14/29) value} and an intensity ratio of a diffraction line at 2?=28.5° to the diffraction line at 2?=29° {I(28/29) value}, which are calculated from an X-ray diffraction pattern obtained by an X-ray diffraction measurement using CuKa after heating under a temperature condition of 1100° C. in air for 5 hours, respectively satisfy the following conditions: I(14/29) value?0.015, and I(28/29) value?0.08.Type: GrantFiled: April 12, 2011Date of Patent: June 28, 2016Assignees: KABUSHIKI KAISHA TOYOTA CHUO KENKYUSHO, TOYOTA JIDOSHA KABUSHIKI KAISHA, CATALER CORPORATIONInventors: Akira Morikawa, Kae Yamamura, Akihiko Suda, Naoki Takahashi, Oji Kuno, Takeshi Nobukawa, Akiya Chiba, Ryuta Fujii
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Patent number: 9126846Abstract: A method of synthesizing metal composite oxide, the method including: a step of separately introducing into a high-speed stirring apparatus a ceria composite oxide microparticle colloid having a mean particle diameter of 10 nm or less after adding a dispersant and an alumina microparticle colloid having a mean particle diameter of 10 nm or less after adding a dispersant; a step of synthesizing alumina-ceria composite oxide microparticles by allowing the ceria composite oxide microparticles and the alumina microparticles that have been introduced into the high-speed stirring apparatus to react in a microscopic space; and a step of applying a shearing force of 17000 sec?1 or more to the alumina-ceria composite oxide microparticles.Type: GrantFiled: December 6, 2010Date of Patent: September 8, 2015Assignee: TOYOTA JIDOSHA KABUSHIKI KAISHAInventors: Satoshi Nagao, Kimiyasu Ono, Hirohito Hirata, Akihiko Suda, Kimitoshi Sato, Kae Yamamura, Akira Morikawa
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Patent number: 8697600Abstract: An exhaust gas purifying catalyst that contains a first oxygen storage material on which no noble metal is supported and which has a pyrochlore phase type regular array structure, and a second oxygen storage material which has a higher oxygen storage rate and a lower oxygen storage capacity than the first oxygen storage material and on which a platinum group noble metal is supported.Type: GrantFiled: July 22, 2011Date of Patent: April 15, 2014Assignee: Toyota Jidosha Kabushiki KaishaInventors: Takeshi Nobukawa, Oji Kuno, Akira Morikawa, Kae Yamamura, Naoki Takahashi, Akihiko Suda
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Publication number: 20130029840Abstract: A ceria-zirconia base composite oxide contains a composite oxide of ceria and zirconia. In the ceria-zirconia base composite oxide, a content ratio between cerium and zirconium in the composite oxide is in a range from 43:57 to 48:52 in terms of molar ratio ([cerium]: [zirconium]). An intensity ratio of a diffraction line at 2?=14.5° to a diffraction line at 2?=29° {I(14/29) value} and an intensity ratio of a diffraction line at 2?=28.5° to the diffraction line at 2?=29° {I(28/29) value}, which are calculated from an X-ray diffraction pattern obtained by an X-ray diffraction measurement using CuKa after heating under a temperature condition of 1100° C. in air for 5 hours, respectively satisfy the following conditions: I(14/29)value?0.015, and I(28/29)value?0.08.Type: ApplicationFiled: April 12, 2011Publication date: January 31, 2013Applicants: KABUSHIKI KAISHA TOYOTA CHUO KENKYUSHO, CATALER CORPORATION, TOYOTA JIDOSHA KABUSHIKI KAISHAInventors: Akira Morikawa, Kae Yamamura, Akihiko Suda, Naoki Takahashi, Oji Kuno, Takeshi Nobukawa, Akiya Chiba, Ryuta Fujii
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Publication number: 20120244056Abstract: A method of synthesizing metal composite oxide, the method including: a step of separately introducing into a high-speed stirring apparatus a ceria composite oxide microparticle colloid having a mean particle diameter of 10 nm or less after adding a dispersant and an alumina microparticle colloid having a mean particle diameter of 10 nm or less after adding a dispersant; a step of synthesizing alumina-ceria composite oxide microparticles by allowing the ceria composite oxide microparticles and the alumina microparticles that have been introduced into the high-speed stirring apparatus to react in a microscopic space; and a step of applying a shearing force of 17000 sec?1 or more to the alumina-ceria composite oxide microparticles.Type: ApplicationFiled: December 6, 2010Publication date: September 27, 2012Applicant: TOYOTA JIDOSHA KABUSHIKI KAISHAInventors: Satoshi Nagao, Kimiyasu Ono, Hirohito Hirata, Akihiko Suda, Kimitoshi Sato, Kae Yamamura, Akira Morikiawa
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Patent number: 8242046Abstract: A particulate inorganic oxide containing aluminum oxide, a metal oxide forming no composite oxide with aluminum oxide, and an additional element including at least one of a rare-earth element and an alkali earth element, the inorganic oxide containing a secondary particle formed by aggregating primary particles; wherein at least a part of the secondary particle includes a plurality of first primary particles, each having a particle size of 100 nm or less, containing aluminum oxide and the additional element, and a plurality of second primary particles, each having a particle size of 100 nm or less, containing the metal oxide and the additional element; wherein at least a part of the first and second primary particles has a surface concentrated region where the additional element has a locally increased content in a surface layer part thereof.Type: GrantFiled: July 22, 2005Date of Patent: August 14, 2012Assignees: Toyota Jidosha Kabushiki Kaisha, Kabushiki Kaisha Toyota ChuoInventors: Akira Morikawa, Toshitaka Tanabe, Kae Yamamura, Naoki Takahashi, Hiromasa Suzuki, Akemi Sato, Mamoru Ishikiriyama, Takaaki Kanazawa, Oji Kuno
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Publication number: 20120142523Abstract: A porous composite metal oxide, including a mixture of first ultrafine particles containing alumina and second ultrafine particles containing zirconia, wherein the first ultrafine particles and the second ultrafine particles are uniformly dispersed in such a way as to satisfy a condition that standard deviations of content ratios (% by mass) of all metal elements contained in the porous composite metal oxide at 0.1% by mass or more are each 10 or less, the standard deviations being obtained by measuring content ratios of the metal elements at 100 measurement points within a minute analysis region of 20 nm square by energy dispersive X-ray spectroscopy using a scanning transmission electron microscope equipped with a spherical aberration correction function.Type: ApplicationFiled: September 10, 2010Publication date: June 7, 2012Applicant: KABUSHIKI KAISHA TOYOTA CHUO KENKYUSHOInventors: Kimitoshi Sato, Kae Yamamura, Akira Morikawa, Akihiko Suda
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Publication number: 20120021899Abstract: An exhaust gas purifying catalyst that contains a first oxygen storage material on which no noble metal is supported and which has a pyrochlore phase type regular array structure, and a second oxygen storage material which has a higher oxygen storage rate and a lower oxygen storage capacity than the first oxygen storage material and on which a platinum group noble metal is supported.Type: ApplicationFiled: July 22, 2011Publication date: January 26, 2012Applicant: TOYOTA JIDOSHA KABUSHIKI KAISHAInventors: Takeshi NOBUKAWA, Oji KUNO, Akira MORIKAWA, Kae YAMAMURA, Naoki TAKAHASHI, Akihiko SUDA
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Patent number: 7713908Abstract: A method of producing a porous composite metal oxide comprising the steps of: dispersing first metal oxide powder, which is an aggregate of primary particles each with a diameter of not larger than 50 nm, in a dispersion medium by use of microbeads each with a diameter of not larger than 150 ?m, thus obtaining first metal oxide particles, which are 1 nm to 50 nm in average particle diameter, and not less than 80% by mass of which are not larger than 75 nm in diameter; dispersing and mixing up, in a dispersion medium, the first metal oxide particles and second metal oxide powder, which is an aggregate of primary particles each with a diameter of not larger than 50 nm, and which is not larger than 200 nm in average particle diameter, thus obtaining a homogeneously-dispersed solution in which the first metal oxide particles and second metal oxide particles are homogeneously dispersed; and drying the homogeneously-dispersed solution, thus obtaining a porous composite metal oxide.Type: GrantFiled: August 29, 2005Date of Patent: May 11, 2010Assignee: Kabushiki Kaisha Toyota Chuo KenkyushoInventors: Toshio Yamamoto, Akihiko Suda, Akira Morikawa, Kae Yamamura, Hirotaka Yonekura
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Publication number: 20090149321Abstract: A particulate inorganic oxide contains an aluminum oxide, a metal oxide forming no composite oxide with an aluminum oxide, and at least one additional element selected from the group consisting of rare earth elements and alkaline earth elements. In the inorganic oxide, a percentage content of the aluminum oxide to a total amount of aluminum in the aluminum oxide, a metal element in the metal oxide, and the additional element is in a range from 48 at % to 92 at % in terms of element content. At least 80% of primary particles in the inorganic oxide have a particle diameter of 100 nm or smaller. At least a part of the primary particles have a surface concentrated region where a percentage content of the additional element is locally increased in a surface layer part thereof. The content of the additional element in the surface concentrated region to a whole amount of the inorganic oxide is in a range from 0.06% by mass to 0.98% by mass in terms of oxide amount.Type: ApplicationFiled: June 8, 2007Publication date: June 11, 2009Inventors: Akira Morikawa, Toshitaka Tanabe, Naoki Takahashi, Kae Yamamura, Takeru Yoshida, Akemi Sato
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Publication number: 20090099013Abstract: A particulate inorganic oxide contains an aluminum oxide, a metal oxide forming no composite oxide with an aluminum oxide, and at least one additional element selected from the group consisting of rare earth elements and alkaline earth elements. In the inorganic oxide, a percentage content of the additional element to a total amount of aluminum in the aluminum oxide, a metal element in the metal oxide, and the additional element is in a range from 1.1 at % to 8.0 at % in terms of element content. At least 80% of primary particles in the inorganic oxide have a particle diameter of 100 nm or smaller. At least a part of the primary particles have a surface concentrated region where a percentage content of the additional element is locally increased in a surface layer part thereof. The content of the additional element in the surface concentrated region to a whole amount of the inorganic oxide is in a range from 0.06% by mass to 0.98% by mass in terms of oxide amount.Type: ApplicationFiled: June 8, 2007Publication date: April 16, 2009Inventors: Akira Morikawa, Toshitaka Tanabe, Naoki Takahashi, Kae Yamamura, Takeru Yoshida, Akemi Sato
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Publication number: 20070104950Abstract: A particulate inorganic oxide containing aluminum oxide, a metal oxide forming no composite oxide with aluminum oxide, and an additional element including at least one of a rare-earth element and an alkali earth element, the inorganic oxide containing a secondary particle formed by aggregating primary particles; wherein at least a part of the secondary particle includes a plurality of first primary particles, each having a particle size of 100 nm or less, containing aluminum oxide and the additional element, and a plurality of second primary particles, each having a particle size of 100 nm or less, containing the metal oxide and the additional element; wherein at least a part of the first and second primary particles has a surface concentrated region where the additional element has a locally increased content in a surface layer part thereof.Type: ApplicationFiled: July 22, 2005Publication date: May 10, 2007Inventors: Akira Morikawa, Toshitaka Tanabe, Kae Yamamura, Naoki Takahashi, Hiromasa Suzuki, Akemi Sato, Mamoru Ishikiriyama, Takaaki Kanazawa, Oji Kuno
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Patent number: 7214643Abstract: A metal oxide which has a large pore volume, and is very useful as a catalyst support. An alkaline material is added to an aqueous solution in which a compound of a metal element for composing an oxide is dissolved, a resultant mixture is co-precipitated, an obtained precipitate is washed, a washed precipitate is stirred in water along with a surfactant, and is calcined. By adding the surfactant after washing, the pH is not changed so that the adding effect of the surfactant is achieved to its upper most limit, thereby obtaining a metal oxide which has a large pore volume and a large mean diameter of secondary particles, and exhibits excellent gas diffusion properties.Type: GrantFiled: March 21, 2003Date of Patent: May 8, 2007Assignee: Kabushiki Kaisha Toyota Chuo KenkyushoInventors: Toshio Yamamoto, Akihiko Suda, Kae Yamamura, Hideo Sobukawa
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Publication number: 20060043651Abstract: A method of producing a porous composite metal oxide comprising the steps of: dispersing first metal oxide powder, which is an aggregate of primary particles each with a diameter of not larger than 50 nm, in a dispersion medium by use of microbeads each with a diameter of not larger than 150 ?m, thus obtaining first metal oxide particles, which are 1 nm to 50 nm in average particle diameter, and not less than 80% by mass of which are not larger than 75 nm in diameter; dispersing and mixing up, in a dispersion medium, the first metal oxide particles and second metal oxide powder, which is an aggregate of primary particles each with a diameter of not larger than 50 nm, and which is not larger than 200 nm in average particle diameter, thus obtaining a homogeneously-dispersed solution in which the first metal oxide particles and second metal oxide particles are homogeneously dispersed; and drying the homogeneously-dispersed solution, thus obtaining a porous composite metal oxide.Type: ApplicationFiled: August 29, 2005Publication date: March 2, 2006Applicant: KABUSHIKI KAISHA TOYOTA CHUO KENKYUSHOInventors: Toshio Yamamoto, Akihiko Suda, Akira Morikawa, Kae Yamamura, Hirotaka Yonekura
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Publication number: 20030224931Abstract: A metal oxide which has a large pore volume, and is very useful as a catalyst support. An alkaline material is added to an aqueous solution in which a compound of a metal element for composing an oxide is dissolved, a resultant mixture is co-precipitated, an obtained precipitate is washed, a washed precipitate is stirred in water along with a surfactant, and is calcined. By adding the surfactant after washing, the pH is not changed so that the adding effect of the surfactant is achieved to its upper most limit, thereby obtaining a metal oxide which has a large pore volume and a large mean diameter of secondary particles, and exhibits excellent gas diffusion properties.Type: ApplicationFiled: March 21, 2003Publication date: December 4, 2003Applicant: KABUSHIKI KAISHA TOYOTA CHUO KENKYUSHOInventors: Toshio Yamamoto, Akihiko Suda, Kae Yamamura, Hideo Sobukawa