Abstract: Improved superconducting oxides are provided having the general formula (Hg.sub.1-x Tl.sub.x)Ba.sub.2 Ca.sub.n-1 Cu.sub.n O.sub.2n+2+.alpha. where x is from about 0.05-0.5 and n is 1, 2, 3 or 4, and .alpha. is an oxygen enrichment factor. The Tl-doped oxides exhibit very high T.sub.c and J.sub.c values.

Abstract: Composite bulk superconducting materials having desirable physical, measured transport current density and high T.sub.c superconducting characteristics are provided which comprise a first matrix of superconducting ceramic oxide crystalline grains with a second matrix of elemental metal (gold, silver, palladium and tin) situated within the interstices between the crystalline grains. Preferably, each matrix is a continuous phase within the composite material, with the ceramic oxide preferably being present at a level of at least about 80% by weight, whereas the elemental metal is present at a level of up to about 20% by weight. In fabrication procedures, a precursor superconducting ceramic oxide is first prepared and reduced to a fine powder size; this is mixed with powdered elemental metal, and the mixture is compressed using high compaction pressures on the order of 14 tons/cm.sup.2 or greater to form a body, which is then sintered to yield the composite.

Abstract: A selectively controllable, direction-, amplitude- and/or frequency-specific superconducting shield (10) is provided which includes a multiply-connected superconducting shield (12) adapted to shield a zone (13) from external magnetic, electric and/or electromagnetic fields and signals. Controlled gating of the shield (12) is provided by means (16) serving to selectively lower the critical shielding current density of a portion (26) of the shield (12) to a level permitting entrance of external fields through the portion (26), while leaving the critical shielding current densities of other portions of the shield (12) at higher, field-shielding levels. The means (16) preferably includes respective, selectively energizable coil pairs (CP.sub.1, CP.sub.2 . . . CP.sub.n) disposed about the shield (12). A highly sensitive magnetic detector (30) would include the shielding device (10) as well as a SQUID assembly (18) situated within the zone (13) defined by shield (12).

Abstract: Complex superconducting oxides are fabricated through appropriate selection and use of fundamental superconducting "building blocks." In this fashion, the invention provides a rationalized method of fabricating complex oxides having desirably high T.sub.c values. In another aspect of the invention, novel, 112 and 12 superconducting oxides are described.

Abstract: Vanadium-containing superconducting oxides are disclosed having critical temperature (T.sub.c) values of above about 100.degree. K. and preferably about 110.degree.-150.degree. K., together with predicted current density (J.sub.c) values on the order of 10.sup.4 -10.sup.5 amperes/cm.sup.2. The oxides hereof are moreover relatively ductile and easily bulk sintered to give end products having desirable superconductivity characteristics. Certain preferred oxides of the invention are defined by the general formula:(V.sub.1-x M.sub.x).sub.i (A.sub.1-y M.sub.y).sub.j Q.sub.k Cu.sub.m O.sub.r.+-.t I.