Patents by Inventor Kaname MITSUYOSHI
Kaname MITSUYOSHI has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 11535765Abstract: The present invention relates to [1] a water-based ink containing an azomethine metal complex pigment (A), an aromatic group-containing polymer (B), an organic solvent (D) and water, in which a mass ratio of the azomethine metal complex pigment (A) to the aromatic group-containing polymer (B) [(A)/(B)] is not less than 1.4 and not more than 4, and the aromatic group-containing polymer (B) is a crosslinked polymer obtained by crosslinking an aromatic group-containing polymer (b) having an acid value of not less than 80 mgKOH/g and not more than 400 mgKOH/g with a water-insoluble polyfunctional epoxy compound (c), said water-based ink being excellent in storage stability and maintenanceability, and [2] a process for producing a pigment water dispersion liquid of particles of the aromatic group-containing polymer (B) containing the azomethine metal complex pigment (A).Type: GrantFiled: October 15, 2018Date of Patent: December 27, 2022Assignee: KAO CORPORATIONInventors: Tsuyoshi Egawa, Kaname Mitsuyoshi, Shimpei Nishimura
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Patent number: 11459476Abstract: The present invention relates to [1] a process for producing a pigment water dispersion liquid of polymer particles containing an azomethine metal complex pigment (A), said process including the step of subjecting a mixture containing the azomethine metal complex pigment (A), an uncrosslinked aromatic group-containing polymer (b) and water to dispersion treatment using a medialess disperser at an accumulated input energy of not more than 5.0 kWh/kg, [2] a pigment water dispersion liquid containing an azomethine metal complex pigment (A) and a polymer dispersant (B), in which in an optical absorption spectrum of the pigment water dispersion liquid, a ratio of a maximum absorbance (A1max) in a wavelength range of not less than 440 nm and less than 465 nm to a maximum absorbance (A2max) in a wavelength range of not less than 420 nm and less than 440 nm [(A1max)/(A2max)] is not less than 1.000, and [3] a water-based ink for ink-jet printing, containing the aforementioned pigment water dispersion liquid.Type: GrantFiled: December 20, 2018Date of Patent: October 4, 2022Assignee: KAO CORPORATIONInventors: Kaname Mitsuyoshi, Tsuyoshi Egawa, Tomohiko Nagano, Yusuke Shimizu
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Patent number: 11242466Abstract: The present invention relates to an ink set for ink-jet printing which contains at least a water-based ink (I) and a water-based ink (II) in which the water-based ink (I) contains a pigment (A1) having a barbituric acid-derived structure, and the water-based ink (II) contains a diketopyrrolopyrrole pigment (A2), an ink-jet printing method using the ink set, and an ink-jet printed material.Type: GrantFiled: October 15, 2018Date of Patent: February 8, 2022Assignee: KAO CORPORATIONInventors: Tsuyoshi Egawa, Kaname Mitsuyoshi, Tomohiko Nagano
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Patent number: 11220611Abstract: The present invention relates to [1] a water-based ink for ink-jet printing which can be prevented from suffering from increased viscosity and flocculation of the ink upon storage thereof even when used in the form of a system containing a large amount of a solvent, said water-based ink for ink-jet printing containing crosslinked polymer particles containing a pigment having an indanthrone skeleton, an organic solvent and water, in which a crosslinking rate of the crosslinked polymer is not less than 10 mol % and not more than 90 mol %, and a content of the organic solvent in the water-based ink is not less than 30% by mass and not more than 65% by mass, and [2] an ink-jet printing method including the steps of loading the water-based ink as described in the above [1] to an ink-jet printing apparatus, and ejecting the water-based ink in the form of droplets of the ink onto a printing medium to form characters or images on the printing medium.Type: GrantFiled: July 9, 2018Date of Patent: January 11, 2022Assignee: KAO CORPORATIONInventors: Tomohiko Nagano, Kaname Mitsuyoshi, Tsuyoshi Egawa
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Publication number: 20200392361Abstract: The present invention relates to [1] a process for producing a pigment water dispersion liquid of polymer particles containing an azomethine metal complex pigment (A), said process including the step of subjecting a mixture containing the azomethine metal complex pigment (A), an uncrosslinked aromatic group-containing polymer (b) and water to dispersion treatment using a medialess disperser at an accumulated input energy of not more than 5.0 kWh/kg, [2] a pigment water dispersion liquid containing an azomethine metal complex pigment (A) and a polymer dispersant (B), in which in an optical absorption spectrum of the pigment water dispersion liquid, a ratio of a maximum absorbance (A1max) in a wavelength range of not less than 440 nm and less than 465 nm to a maximum absorbance (A2max) in a wavelength range of not less than 420 nm and less than 440 nm [(A1max)/(A2max)] is not less than 1.000, and [3] a water-based ink for ink-jet printing, containing the aforementioned pigment water dispersion liquid.Type: ApplicationFiled: December 20, 2018Publication date: December 17, 2020Applicant: KAO CORPORATIONInventors: Kaname MITSUYOSHI, Tsuyoshi EGAWA, Tomohiko NAGANO, Yusuke SHIMIZU
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Publication number: 20200255683Abstract: The present invention relates to an ink set for ink-jet printing which contains at least a water-based ink (I) and a water-based ink (II) in which the water-based ink (I) contains a pigment (A1) having a barbituric acid-derived structure, and the water-based ink (II) contains a diketopyrrolopyrrole pigment (A2), an ink-jet printing method using the ink set, and an ink-jet printed material.Type: ApplicationFiled: October 15, 2018Publication date: August 13, 2020Applicant: KAO CORPORATIONInventors: Tsuyoshi EGAWA, Kaname MITSUYOSHI, Tomohiko NAGANO
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Publication number: 20200248013Abstract: The present invention relates to [1] a water-based ink containing an azomethine metal complex pigment (A), an aromatic group-containing polymer (B), an organic solvent (D) and water, in which a mass ratio of the azomethine metal complex pigment (A) to the aromatic group-containing polymer (B) [(A)/(B)] is not less than 1.4 and not more than 4, and the aromatic group-containing polymer (B) is a crosslinked polymer obtained by crosslinking an aromatic group-containing polymer (b) having an acid value of not less than 80 mgKOH/g and not more than 400 mgKOH/g with a water-insoluble polyfunctional epoxy compound (c), said water-based ink being excellent in storage stability and maintenanceability, and [2] a process for producing a pigment water dispersion liquid of particles of the aromatic group-containing polymer (B) containing the azomethine metal complex pigment (A).Type: ApplicationFiled: October 15, 2018Publication date: August 6, 2020Applicant: KAO CORPORATIONInventors: Tsuyoshi EGAWA, Kaname MITSUYOSHI, Shimpei NISHIMURA
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Patent number: 10655030Abstract: The present invention relates to a water-based ink including a pigment, a water-insoluble polymer, an organic solvent and a surfactant, in which the organic solvent includes at least a glycol ether which has a viscosity of from 2.0 to 7.0 mPa·s and a vapor pressure from 0.01 to 7.0 hPa as measured at 20° C., and a content of a glycol ether having a viscosity of not less than 6.0 mPa·s as measured at 20° C. as a component of the glycol ether in the water-based ink is from 0 to 5% by mass; the surfactant includes a silicone-based surfactant and a content of the silicone-based surfactant in the water-based ink is from 0.005 to 0.Type: GrantFiled: June 24, 2016Date of Patent: May 19, 2020Assignee: KAO CORPORATIONInventors: Hirotaka Takeno, Yuki Wakabayashi, Kaname Mitsuyoshi, Takahiro Yoshikawa
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Publication number: 20200123402Abstract: The present invention relates to [1] a water-based ink for ink-jet printing which can be prevented from suffering from increased viscosity and flocculation of the ink upon storage thereof even when used in the form of a system containing a large amount of a solvent, said water-based ink for ink-jet printing containing crosslinked polymer particles containing a pigment having an indanthrone skeleton, an organic solvent and water, in which a crosslinking rate of the crosslinked polymer is not less than 10 mol % and not more than 90 mol %, and a content of the organic solvent in the water-based ink is not less than 30% by mass and not more than 65% by mass, and [2] an ink-jet printing method including the steps of loading the water-based ink as described in the above [1] to an ink-jet printing apparatus, and ejecting the water-based ink in the form of droplets of the ink onto a printing medium to form characters or images on the printing medium.Type: ApplicationFiled: July 9, 2018Publication date: April 23, 2020Applicant: KAO CORPORATIONInventors: Tomohiko NAGANO, Kaname MITSUYOSHI, Tsuyoshi EGAWA
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Patent number: 10316207Abstract: The present invention relates to a water-based ink that exhibits excellent ejection properties, and can be prevented from suffering from reduction in a dot size of the ink during a drying step thereof even when printed on a low-water absorbing recording medium, and is capable of obtaining printed characters or images having excellent uniformity, as well as an ink-jet printing method using the water-based ink. The water-based ink includes a pigment, a water-insoluble polymer, an acetylene glycol-based nonionic surfactant (A) having HLB of not less than 0 and not more than 5, a nonionic surfactant (B) having HLB of not less than 6 and not more than 20, a polyether-modified silicone (C) having a kinematic viscosity of not less than 30 mm2/s and not more than 190 mm2/s as measured at 25° C. and an organic solvent (D), in which a weighted mean value of a boiling point of the organic solvent (D) is not lower than 150° C. and not higher than 230° C.Type: GrantFiled: December 16, 2015Date of Patent: June 11, 2019Assignee: KAO CORPORATIONInventors: Kaname Mitsuyoshi, Hirotaka Takeno, Takayuki Suzuki, Takahiro Yoshikawa
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Patent number: 10266712Abstract: The present invention provides an ink-jet printing method using a water-based ink for ink-jet printing which is excellent in quick-drying fixing properties and long-term fixing properties when printing characters or images on a low-water absorbing recording medium, as well as ejection stability. The present invention relates to [1] an ink-jet printing method of printing characters or images on a recording medium using a water-based ink for ink-jet printing, in which the recording medium has a water absorption of not more than 10 g/m2 and not less than 0 g/m2 as measured in a pure water contact time of 100 milliseconds; the water-based ink includes a pigment (A), resin particles (B), a polypropylene glycol (X) and water; and the resin particles (B) are produced by emulsion polymerization method; and [2] the aforementioned water-based ink for ink-jet printing.Type: GrantFiled: August 18, 2015Date of Patent: April 23, 2019Assignee: Kao CorporationInventors: Yuki Wakabayashi, Kaname Mitsuyoshi, Hirotaka Takeno
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Patent number: 10179470Abstract: An inkjet recording method for printing an inkjet recording medium comprising an ink-receiving layer containing inorganic pigment, starch and copolymer latex on a surface of a base with inkjet ink as aqueous pigment ink, a content of the inorganic pigment being 10 g/m2 or more to 35 g/m2 or less in the ink-receiving layer, and a content of calcium carbonate being from 80% by weight or more to 100% by weight or less, the inkjet ink containing one or more selected from self dispersed pigment and pigment containing water-insoluble polymer particles, from 10% by weight or more to 48% by weight or less of a water-soluble organic solvent A having a boiling point of 230° C. or less, from 0% by weight or more to 5.0% by weight or less of a water-soluble organic solvent B having a boiling point of 280° C. or more, from 42% by weight or more to 70% by weight or less of water.Type: GrantFiled: June 24, 2015Date of Patent: January 15, 2019Assignees: Nippon Paper Industries Co., Ltd., Kao CorporationInventors: Koji Kutsuwa, Masaaki Nakano, Yasufumi Ueda, Teruyuki Fukuda, Kaname Mitsuyoshi, Takayuki Suzuki
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Publication number: 20180187034Abstract: The present invention relates to a water-based ink including a pigment, a water-insoluble polymer, an organic solvent and a surfactant, in which the organic solvent includes at least a glycol ether which has a viscosity of from 2.0 to 7.0 mPa·s and a vapor pressure from 0.01 to 7.0 hPa as measured at 20° C., and a content of a glycol ether having a viscosity of not less than 6.0 mPa·s as measured at 20° C. as a component of the glycol ether in the water-based ink is from 0 to 5% by mass; the surfactant includes a silicone-based surfactant and a content of the silicone-based surfactant in the water-based ink is from 0.005 to 0.Type: ApplicationFiled: June 24, 2016Publication date: July 5, 2018Applicant: KAO CORPORATIONInventors: Hirotaka TAKENO, Yuki WAKABAYASHI, Kaname MITSUYOSHI, Takahiro YOSHIKAWA
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Publication number: 20170369725Abstract: The present invention relates to a water-based ink that exhibits excellent ejection properties, and can be prevented from suffering from reduction in a dot size of the ink during a drying step thereof even when printed on a low-water absorbing recording medium, and is capable of obtaining printed characters or images having excellent uniformity, as well as an ink-jet printing method using the water-based ink. The water-based ink includes a pigment, a water-insoluble polymer, an acetylene glycol-based nonionic surfactant (A) having HLB of not less than 0 and not more than 5, a nonionic surfactant (B) having HLB of not less than 6 and not more than 20, a polyether-modified silicone (C) having a kinematic viscosity of not less than 30 mm2/s and not more than 190 mm2/s as measured at 25° C. and an organic solvent (D), in which a weighted mean value of a boiling point of the organic solvent (D) is not lower than 150° C. and not higher than 230° C.Type: ApplicationFiled: December 16, 2015Publication date: December 28, 2017Applicant: KAO CORPORATIONInventors: Kaname MITSUYOSHI, Hirotaka TAKENO, Takayuki SUZUKI, Takahiro YOSHIKAWA
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Publication number: 20170267885Abstract: The present invention provides an ink-jet printing method using a water-based ink for ink-jet printing which is excellent in quick-drying fixing properties and long-term fixing properties when printing characters or images on a low-water absorbing recording medium, as well as ejection stability. The present invention relates to [1] an ink-jet printing method of printing characters or images on a recording medium using a water-based ink for ink-jet printing, in which the recording medium has a water absorption of not more than 10 g/m2 and not less than 0 g/m2 as measured in a pure water contact time of 100 milliseconds; the water-based ink includes a pigment (A), resin particles (B), a polypropylene glycol (X) and water; and the resin particles (B) are produced by emulsion polymerization method; and [2] the aforementioned water-based ink for ink-jet printing.Type: ApplicationFiled: August 18, 2015Publication date: September 21, 2017Applicant: KAO CORPORATIONInventors: Yuki WAKABAYASHI, Kaname MITSUYOSHI, Hirotaka TAKENO
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Publication number: 20170259602Abstract: An inkjet recording method for printing an inkjet recording medium comprising an ink-receiving layer containing inorganic pigment, starch and copolymer latex on a surface of a base with inkjet ink as aqueous pigment ink, a content of the inorganic pigment being 10 g/m2 or more to 35 g/m2 or less in the ink-receiving layer,and a content of calcium carbonate being from 80% by weight or more to 100% by weight or less, the inkjet ink containing one or more selected from self dispersed pigment and pigment containing water-insoluble polymer particles, from 10% by weight or more to 48% by weight or less of a water-soluble organic solvent A having a boiling point of 230° C. or less, from 0% by weight or more to 5.0% by weight or less of a water-soluble organic solvent B having a boiling point of 280° C. or more, from 42% by weight or more to 70% by weight or less of water.Type: ApplicationFiled: June 24, 2015Publication date: September 14, 2017Inventors: Koji Kutsuwa, Masaaki Nakano, Yasufumi Ueda, Teruyuki Fukuda, Kaname Mitsuyoshi, Takayuki Suzuki
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Patent number: 9447298Abstract: The present invention relates to [1] a pigment-containing water-based ink for ink-jet printing which is free of turbidity and excellent in capability of suppressing occurrence of image unevenness (MOTTLING) when printed on a low-water absorbing recording medium, said ink including at least one acetylene glycol (A) selected from the group consisting of 2,4,7,9-tetramethyl-5-decyne-4,7-diol and the like, and a nonionic surfactant (B), a content of the component (A) in the water-based ink being not less than 1.0% by mass and not more than 3.0% by mass, and a mass ratio of the component (B) to the component (A) [(B)/(A)] being not less than 1 and not more than 3; and [2] an ink-jet printing method for printing images or characters on a low-water absorbing recording medium using said water-based ink for ink-jet printing.Type: GrantFiled: December 10, 2013Date of Patent: September 20, 2016Assignee: KAO CORPORATIONInventors: Yuki Wakabayashi, Kaname Mitsuyoshi, Hiroto Soma
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Publication number: 20150337149Abstract: The present invention relates to [1] a pigment-containing water-based ink for ink-jet printing which is free of turbidity and excellent in capability of suppressing occurrence of image unevenness (MOTTLING) when printed on a low-water absorbing recording medium, said ink including at least one acetylene glycol (A) selected from the group consisting of 2,4,7,9-tetramethyl-5-decyne-4,7-diol and the like, and a nonionic surfactant (B), a content of the component (A) in the water-based ink being not less than 1.0% by mass and not more than 3.0% by mass, and a mass ratio of the component (B) to the component (A) [(B)/(A)] being not less than 1 and not more than 3; and [2] an ink-jet printing method for printing images or characters on a low-water absorbing recording medium using said water-based ink for ink-jet printing.Type: ApplicationFiled: December 10, 2013Publication date: November 26, 2015Applicant: KAO CORPORATIONInventors: Yuki WAKABAYASHI, Kaname MITSUYOSHI, Hiroto SOMA