Abstract: The present invention is directed to polyurethane ureas which may be obtained by the reaction of a hydrophilic NCO prepolymer, which has been prepared from a polyhydroxy component based on about 9 to 100% by weight of a polyether containing about 30 to 100% by weight of ethylene oxide, or a mixture of this hydrophilic NCO prepolymer and a hydrophobic NCO prepolymer, the mixture containing .gtoreq.30% by weight of the hydrophilic prepolymer, with an aldimine or ketimine-containing hardener mixture in the presence of water and organic solvents, approximately 30 to 70% of the NCO groups of the prepolymers being reacted with the amino groups of the hardener and the remainder reacting with water.The present invention is also directed to a process for the preparation of these polyurethane ureas and to coated substrates prepared from these polyurethane ureas.

Abstract: The present invention is directed to a high-solids polyurethane reactive coating system based on blocked NCO-prepolymers, polyamines and, optionally, solvents, said coating system containing a leveller agent comprising(1) a combination of from about 1 to 10% by weight of (A) vinyl polymers and copolymers based on (meth)acrylic acid esters and, optionally, other comonomers and from about 0.1 to 2% by weight of (B) polysiloxanes and/or polyalkylene oxide/polysiloxane copolymers,(2) from about 0.2 to 2.0% by weight of (C) poly(meth)acrylic acid (hydroxy)alkyl ester graft polymers on silicones,(3) mixtures of (A), (B) and (C) in the amounts specified,(4) mixtures of (A) and (C) in the amounts specified or(5) mixtures of (B) and (C) in the amounts specified.The present invention also relates to textile substrates coated on one or both sides or surface-textured sheet-form materials, particularly velour leather, coated with the above leveller-containing, high-solids polyurethane reactive coating systems.

Abstract: The present invention is directed to a high-solids polyurethane reactive coating system based on blocked NCO-prepolymers, polyamines and, optionally, solvents, said coating system containing a leveller agent comprising(1) a combination of from about 1 to 10% by weight of (A) vinyl polymers and copolymers based on (meth)acrylic acid esters and, optionally, other comonomers and from about 0.1 to 2% by weight of (B) polysiloxanes and/or polyalkylene oxide/polysiloxane copolymers,(2) from about 0.2 to 2.0% by weight of (C) poly(meth)acrylic acid (hydroxy)alkyl ester graft polymers on silicones,(3) mixtures of (A), (B) and (C) in the amounts specified,(4) mixtures of (A) and (C) in the amounts specified or(5) mixtures of (B) and (C) in the amounts specified.The present invention also relates to textile substrates coated on one or both sides or surface-textured sheet-form materials, particularly velour leather, coated with the above leveller-containing, high-solids polyurethane reactive coating systems.

Abstract: The invention disclosed herein is concerned with a process for mixing a plurality of viscous rapidly reacting, fluid materials and an apparatus with which to perform this process. In this process the fluid materials are initially introduced into a mixing chamber and mixed with a gas, preferably in such a way that an angular momentum is imparted to the mixture. The mixture is then fed into a static mixer which has a short residence time spectrum. The apparatus comprises a cylindrical mixing chamber with a gas inlet and at least one nongaseous fluid material inlet arranged to direct flow tangentially to the interior surface of the mixing chamber. Other inlets may be provided downstream of these initial inlets but before a static mixing apparatus with which said mixing chamber communicates. An outlet is provided downstream of said static mixing apparatus which preferably has intersecting baffle plates, a low pressure loss and a short residence time spectrum.

Abstract: The invention disclosed herein is concerned with a process for mixing a plurality of viscous rapidly reacting, fluid materials and an apparatus with which to perform this process. In this process the fluid materials are initially introduced into a mixing chamber and mixed with a gas, preferably in such a way that an angular momentum is imparted to the mixture. The mixture is then fed into a static mixer which has a short residence time spectrum. The apparatus comprises a cylindrical mixing chamber with a gas inlet and at least one nongaseous fluid material inlet arranged to direct flow tangentially to the interior surface of the mixing chamber. Other inlets may be provided downstream of these initial inlets but before a static mixer with which said mixing chamber communicates. An outlet is provided downstream of said static mixer which preferably has intersecting baffle plates, a low pressure loss and a short residence time spectrum.